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1. Mn-mediated oxidative radical cyclization of 2-(azidomethyl)phenyl isocyanides with carbazate: access to quinazoline-2-carboxylates.

Author

Yogesh Kumar, Gujjenahalli Ramalingaiah, Begum, Noor Shahina, and Mohammed Imran, Khan

Subjects
*ISOCYANIDES, *AROMATIZATION, *ATOMS, *HETEROCYCLIC chemistry, *RADICAL anions
Abstract

Mn-TBHP mediated oxidative radical cyclization of 2-(azidomethyl)phenyl isocyanides using methyl carbazate has been described. This procedure is realized through a cascade radical addition and aromatization process with high atom economy to furnish various heterocyclic C2 diversified quinazoline-2-carboxylate derivatives. [ABSTRACT FROM AUTHOR]

Published
2020
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