1. Reversal of global atmospheric ethane and propane trends largely due to US oil and natural gas production
- Author
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Shalini Punjabi, S. Rossabi, Martin K. Vollmer, Louisa K. Emmons, Alastair C. Lewis, K. A. Masarie, Christian Plass-Duelmer, Jacques Hueber, P. Tans, Stefan Reimann, Andrea Pozzer, Stephen A. Montzka, James W. Hannigan, Kirk Thoning, Emmanuel Mahieu, Rainer Steinbrecher, Bruno Franco, Lucy J. Carpenter, Anja Claude, Detlev Helmig, and Dan Smale
- Subjects
chemistry.chemical_classification ,010504 meteorology & atmospheric sciences ,Northern Hemisphere ,010501 environmental sciences ,Spatial distribution ,Atmospheric sciences ,01 natural sciences ,Methane ,chemistry.chemical_compound ,Hydrocarbon ,chemistry ,Propane ,Atmospheric chemistry ,General Earth and Planetary Sciences ,Environmental science ,Tropospheric ozone ,Air quality index ,0105 earth and related environmental sciences - Abstract
Atmospheric non-methane hydrocarbon concentrations began declining in the 1970s. Surface and column measurements show that Northern Hemisphere ethane concentrations are now rising, probably due to North American oil and natural gas emissions. Non-methane hydrocarbons such as ethane are important precursors to tropospheric ozone and aerosols. Using data from a global surface network and atmospheric column observations we show that the steady decline in the ethane mole fraction that began in the 1970s1,2,3 halted between 2005 and 2010 in most of the Northern Hemisphere and has since reversed. We calculate a yearly increase in ethane emissions in the Northern Hemisphere of 0.42 (±0.19) Tg yr−1 between mid-2009 and mid-2014. The largest increases in ethane and the shorter-lived propane are seen over the central and eastern USA, with a spatial distribution that suggests North American oil and natural gas development as the primary source of increasing emissions. By including other co-emitted oil and natural gas non-methane hydrocarbons, we estimate a Northern Hemisphere total non-methane hydrocarbon yearly emission increase of 1.2 (±0.8) Tg yr−1. Atmospheric chemical transport modelling suggests that these emissions could augment summertime mean surface ozone by several nanomoles per mole near oil and natural gas production regions. Methane/ethane oil and natural gas emission ratios could suggest a significant increase in associated methane emissions; however, this increase is inconsistent with observed leak rates in production regions and changes in methane’s global isotopic ratio.
- Published
- 2016