1. Low-strain heteroepitaxial nanodiamonds: fabrication and photoluminescence of silicon-vacancy colour centres
- Author
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Sergey A. Grudinkin, Valery Yu. Davydov, Valery G. Golubev, Mikhail A. Baranov, N. A. Feoktistov, and Alexander N. Smirnov
- Subjects
Photoluminescence ,Materials science ,Silicon ,Material properties of diamond ,chemistry.chemical_element ,Bioengineering ,02 engineering and technology ,Chemical vapor deposition ,engineering.material ,01 natural sciences ,symbols.namesake ,Etching (microfabrication) ,0103 physical sciences ,General Materials Science ,Electrical and Electronic Engineering ,Reactive-ion etching ,010306 general physics ,business.industry ,Mechanical Engineering ,Diamond ,General Chemistry ,021001 nanoscience & nanotechnology ,chemistry ,Mechanics of Materials ,engineering ,symbols ,Optoelectronics ,0210 nano-technology ,business ,Raman spectroscopy - Abstract
Nanodiamonds with the 'diamond' 1332.5 cm(-1) Raman line as narrow as 1.8 cm(-1) have been produced by reactive ion etching in oxygen plasma of heteroepitaxial diamond particles grown by microwave plasma enhanced chemical vapour deposition (MWPECVD) on silicon. After the etching, a doublet is recorded in the zero-phonon line photoluminescence spectra of an ensemble of silicon-vacancy (SiV) centres at 10 K. Each line of the doublet is split into two lines corresponding to the optical transitions between the split excited and ground energy levels of the SiV centres. These Raman and photoluminescent features have been observed previously only in low-strain homoepitaxial diamond films and single-crystal diamond.
- Published
- 2016