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Owing to the great development potential of porous anodic oxides (PAO) in many fields, research on their formation mechanisms, fabrication processes and applications has a history of more than ten years. Although compared with research on the fabrication processes and applications of PAO, research on their formation mechanisms started late, several mainstream theories have been formed in the academic community, including the field-assisted dissolution (FAD) theory, the field-assisted ejection (FAE) theory, the self-organization theory, the ionic and electronic current theory and the oxygen bubble mould effect. This review will focus on summarizing the core views of the mainstream mechanisms mentioned above and comparing the explanations for some of their classical experimental phenomena.

This paper shed light on the growth mechanism of ZrO2 bilayer nanotubes and explain the six stages of the current–time curve in the anodization of Zr.