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A novel multifunctional material with efficient wicking and evaporative functionalities was fabricated using hierarchical surface nano-/microstructuring by femtosecond laser micromachining. The created material exhibits excellent multifunctional performance. Our experiments in a wind tunnel demonstrate its good wicking and evaporative functionalities under the conditions of high-temperature airflows. An important finding of this work is the significantly enhanced evaporation rate of the created material compared with the free water surface. The obtained results provide a platform for the practical implementation of Maisotsenko-cycle cooling technologies for substantially increasing efficiency in power generation, thermal management, and other evaporation-based technologies. The developed multifunctional material demonstrates long-lasting wicking and evaporative functionalities that are resistant to degradation under high-temperature airflows, indicating its suitability for practical applications. [ABSTRACT FROM AUTHOR]

Ultrashort pulse lasers have significant advantages over conventional continuous wave and long pulse lasers for the texturing of metallic surfaces, especially for nanoscale surface structure patterning. Furthermore, ultrafast laser beam polarization allows for the precise control of the spatial alignment of nanotextures imprinted on titanium-based implant surfaces. In this article, we report the biological effect of beam polarization on human mesenchymal stem cell differentiation. We created, on polished titanium-6aluminum-4vanadium (Ti-6Al-4V) plates, a laser-induced periodic surface structure (LIPSS) using linear or azimuthal polarization of infrared beams to generate linear or radial LIPSS, respectively. The main difference between the two surfaces was the microstructural anisotropy of the linear LIPSS and the isotropy of the radial LIPSS. At 7 d post seeding, cells on the radial LIPSS surface showed the highest extracellular fibronectin production. At 14 days, qRT-PCR showed on the same surface an increase in osteogenesis-related genes, such as alkaline phosphatase and osterix. At 21 d, mineralization clusters indicative of final osteoinduction were more abundant on the radial LIPSS. Taken together, we identified that creating more isotropic than linear surfaces enhances cell differentiation, resulting in an improved osseointegration. Thus, the fine tuning of ultrashort pulse lasers may be a promising new route for the functionalization of medical implants. [ABSTRACT FROM AUTHOR]

An advanced superwicking aluminum material based on a microgroove surface structure textured with both laser-induced periodic surface structures and fine microholes was produced by direct femtosecond laser nano/microstructuring technology. The created material demonstrates excellent wicking performance in a temperature range of 23 to 120 °C. The experiments on wicking dynamics show a record-high velocity of water spreading that achieves about 450 mm/s at 23 °C and 320 mm/s at 120 °C when the spreading water undergoes intensive boiling. The lifetime of classic Washburn capillary flow dynamics shortens as the temperature increases up to 80 °C. The effects of evaporation and boiling on water spreading become significant above 80 °C, resulting in vanishing of Washburn's dynamics. Both the inertial and visco-inertial flow regimes are insignificantly affected by evaporation at temperatures below the boiling point of water. The boiling effect on the inertial regime is small at 120 °C; however, its effect on the visco-inertial regime is essential. The created material with effective wicking performance under water boiling conditions can find applications in Maisotsenko cycle (M-cycle) high-temperature heat/mass exchangers for enhancing power generation efficiency that is an important factor in reducing CO2 emissions and mitigation of the global climate change. [ABSTRACT FROM AUTHOR]

A superwicking Ti-6Al-4V alloy material with a hierarchical capillary surface structure was fabricated using femtosecond laser. The basic capillary surface structure is an array of micropillars/microholes. For enhancing its capillary action, the surface of the micropillars/microholes is additionally structured by regular fine microgrooves using a technique of laser-induced periodic surface structures (LIPSS), providing an extremely strong capillary action in a temperature range between 23 °C and 80 °C. Due to strong capillary action, a water drop quickly spreads in the wicking surface structure and forms a thin film over a large surface area, resulting in fast evaporation. The maximum water flow velocity after the acceleration stage is found to be 225–250 mm/s. In contrast to other metallic materials with surface capillarity produced by laser processing, the wicking performance of which quickly degrades with time, the wicking functionality of the material created here is long-lasting. Strong and long-lasting wicking properties make the created material suitable for a large variety of practical applications based on liquid-vapor phase change. Potential significant energy savings in air-conditioning and cooling data centers due to application of the material created here can contribute to mitigation of global warming. [ABSTRACT FROM AUTHOR]

Capillary flow of water in an array of open nanotextured microgrooves fabricated by femtosecond laser processing of silicon is studied as a function of temperature using high-speed video recording. In a temperature range of 23–80 °C, the produced wicking material provides extremely fast liquid flow with a maximum velocity of 37 cm/s in the initial spreading stage prior to visco-inertial regime. The capillary performance of the material enhances with increasing temperature in the inertial, visco-inertial, and partially in Washburn flow regimes. The classic universal Washburn's regime is observed at all studied temperatures, giving the evidence of its universality at high temperatures as well. The obtained results are of great significance for creating capillary materials for applications in cooling of electronics, energy harvesting, enhancing the critical heat flux of industrial boilers, and Maisotsenko cycle technologies. [ABSTRACT FROM AUTHOR]

Laser-induced periodic surface structures (LIPSS) are often present when processing solid targets with linearly polarized ultrashort laser pulses. The different irradiation parameters to produce them on metals, semiconductors and dielectrics have been studied extensively, identifying suitable regimes to tailor its properties for applications in the fields of optics, medicine, fluidics and tribology, to name a few. One important parameter widely present when exposing the samples to the high intensities provided by these laser pulses in air environment, that generally is not considered, is the formation of a superficial laser-induced oxide layer. In this paper, we fabricate LIPSS on a layer of the oxidation prone hard-coating material chromium nitride in order to investigate the impact of the laser-induced oxide layer on its formation. A variety of complementary surface analytic techniques were employed, revealing morphological, chemical and structural characteristics of well-known high-spatial frequency LIPSS (HSFL) together with a new type of low-spatial frequency LIPSS (LSFL) with an anomalous orientation parallel to the laser polarization. Based on this input, we performed finite-difference time-domain calculations considering a layered system resembling the geometry of the HSFL along with the presence of a laser-induced oxide layer. The simulations support a scenario that the new type of LSFL is formed at the interface between the laser-induced oxide layer and the non-altered material underneath. These findings suggest that LSFL structures parallel to the polarization can be easily induced in materials that are prone to oxidation. [ABSTRACT FROM AUTHOR]