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In this work, a bimetallic sulfide-coupled graphene hybrid was designed and constructed for capacitive energy storage. The hybrid structure involved decorating copper–cobalt–sulfide (CuCo2S4) nanoparticles onto graphene layers, with the nanoparticles anchored within the graphene layers, forming a hybrid energy storage system. In this hybrid structure, rGO can work as the substrate and current collector to support the uniform distribution of the nanoparticles and provides efficient transportation of electrons into and out of the electrode. In the meantime, CuCo2S4-active materials are expected to offer an evident enhancement in electrochemical activities, due to the rich valence change provided by Cu and Co. Benefiting from the integrated structure of CuCo2S4 nanoparticles and highly conductive graphene substrates, the prepared CuCo2S4@rGO electrode exhibited a favorable capacitive performance in 1 M KOH. At 1 A g−1, CuCo2S4@rGO achieved a specific capacitance of 410 F g−1. The capacitance retention at 8 A g−1 was 70% of that observed at 1 A g−1, affirming the material’s excellent rate capability. At the current density of 5 A g−1, the electrode underwent 10,000 charge–discharge cycles, retaining 98% of its initial capacity, which indicates minimal capacity decay and showcasing excellent cycling performance.

In contrast to traditional pigment colors, structural colors have developed a great potential in practical applications, thanks to their unique nonfading and color tunable properties; especially amorphous photonic structures with noniridescent structural colors have attracted considerable attention and their applications have expanded to more fields. Herein, graphene oxide (GO) and reduced graphene oxide (RGO) enhanced noniridescent structural colors with excellent mechanical robustness were established by a time-saving approach named spray coating, which allows for rapid fabrication of angular independent structural colors by spraying different photonic spray paints (PSPs) to ensure color multiplicity that was adjusted by the silica nanoparticles (SiO2 NPs) sizes onto the substrates. The incorporation of poly(methyl methacrylate-butyl acrylate) (PMB) improved the adhesion existing among SiO2 inter-nanoparticles and between SiO2 NPs and the substrates, taking advantages of the low glass transition temperature (Tg) of butyl acrylate derivative polymer and made PMB embedded PSPs coated patterns being imparted with good mechanical robustness and abrasive resistance. The peculiar light adsorption of GO and RGO across visible light spectrum facilitate higher color saturation. The improvement in color saturation of GO and RGO doped PSPs is expected to boost the promising applications in structurally colored paintings, inks and other color-related optical fields.

Structural-coloured poly(styrene-methyl methacrylate-acrylic acid) (Poly(St-MMA-AA)) deposited carbon fabrics (Poly(St-MMA-AA)/PCFs) with fascinating colours (salmon, chartreuse, springgreen, skyblue, mediumpurple) changing with the (Poly(St-MMA-AA) nanoparticle sizes can be facilely fabricated by the thermal-assisted gravity sedimentation method that facilitates the self-assembly of Poly(St-MMA-AA) colloidal nanoparticles to generate photonic crystals. The particle sizes of Poly(St-MMA-AA) copolymer with core/shell structure varying from 308.3 nm to 213.1 nm were controlled by adjusting the amount of emulsifier during emulsion polymerisation. The presence of the intrinsic chemical information of Poly(St-MMA-AA) copolymer has been ascertained by Raman and Fourier Transform Infrared (FT-IR) Spectroscopy analysis. Colour variation of the as-prepared structural-coloured carbon fabrics (Poly(St-MMA-AA)/PCFs) before and after dipping treatment were captured while using an optical microscope. The structural colours of Poly(St-MMA-AA)/PCFs were assessed by calculating the diffraction bandgap according to Bragg’s and Snell’s laws. The Poly(St-MMA-AA) photonic crystal films altered the electrical properties of carbon fabrics with the resistivity growing by five orders of magnitude. The differential electrical resistivity between Poly(St-MMA-AA)/PCFs and wet Poly(St-MMA-AA)/PCFs combined with the corresponding tunable colours can be potentially applied in several promising areas, such as smart displays, especially signal warning displays for traffic safety.

In this study, we simulated the electric field distribution of side-by-side electrospinning by using the finite element method (FEM), and studied the effects of spinneret wall thickness, spinning voltage and receiving distance on the distribution of the electrostatic field. The receiving distance was selected as a variable in the experimental, a series of PAN/PSA composite nanofiber membranes were prepared by using a self-made side by side electrospinning device. The membranes were tested by Fourier-transform infrared (FTIR), thermogravimetric analysis (TG), and scanning electron microscope (SEM). The prepared membranes were also treated by high-temperature treatment, and the change of fiber diameter and conductivity of the membrane before and after high-temperature treatment were studied. It was found that the PAN/PSA carbonized nanofibers could achieve a better performance in heat resistance and conductivity at 200 mm receiving distance.