1. Synthesis and Luminescent Properties of Carbon Nanodots Dispersed in Nanostructured Silicas
- Author
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Andrii Vasin, Dmytro Kysil, Andriy Rusavsky, Oksana Isaieva, Alexander Zaderko, Alexei Nazarov, and Volodymyr Lysenko
- Subjects
carbon nanodots ,porous silica ,fumed silica ,SiOC thin films ,Chemistry ,QD1-999 - Abstract
Luminescent carbon nanoparticles are a relatively new class of luminescent materials that have attracted the increasing interest of chemists, physicists, biologists and engineers. The present review has a particular focus on the synthesis and luminescent properties of carbon nanoparticles dispersed inside nanostructured silica of different natures: oxidized porous silicon, amorphous thin films, nanopowders, and nanoporous sol–gel-derived ceramics. The correlations of processing conditions with emission/excitation spectral properties, relaxation kinetics, and photoluminescence photodegradation behaviors are analyzed. Following the evolution of the photoluminescence (PL) through the “from-bottom-to-up” synthesis procedure, the transformation of molecular-like ultraviolet emission of organic precursor into visible emission of carbon nanoparticles is demonstrated. At the end of the review, a novel method for the synthesis of luminescent and transparent composites, in form of nanoporous silica filled with luminescent carbon nanodots, is presented. A prototype of white light emitting devices, constructed on the basis of such luminophores and violet light emitting diodes, is demonstrated.
- Published
- 2021
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