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In the framework of a quasi-molecular approach, the formation of hydrogen atom in the pre-recombination period of evolution of the Universe is analysed quantitatively. Calculations in an adiabatic multilevel representation enable estimates of probabilities of radiative transitions. The quasi-molecular mechanism of recombination allows the formation of hydrogen molecular ion, |${\mathrm{ H}_2}^+$|⁠ , in its ground state. The probability of this process is comparable with the probability of the creation of atomic hydrogen. The participation of a second proton in the recombination increases the binding energy of an electron and decreases the rate of recombination of hydrogen. [ABSTRACT FROM AUTHOR]

The rate coefficient for the formation of aluminium monochloride, AlCl, from the radiative association of aluminium and chlorine atoms is estimated as a function of temperature. The coupling of the Al and Cl atoms through the A1Π molecular electronic state, which undergoes radiative transition to the X1Σ+ ground state, is the most efficient transition to form AlCl. The rate constant was found to vary with temperature according to the expressions k(T) = 1.22 × 10-16(T/300)0.40exp (-748/T) cm3 s-1 for temperatures between 300 and 1000 K, and k(T) = 2.20 × 10-16(T/300)0.175exp (-1067/T) cm3 s-1 for temperatures between 1000 and 14 000 K. [ABSTRACT FROM AUTHOR]

The radiative lifetime measurements by the time-resolved laser-induced fluorescence technique are reported for 24 levels of Co I with the energy range of 283 45.86-55 922.3 cm-1, amongst which the lifetimes of 20 levels are reported for the first time. The branching fraction measurements by the emission spectrum of a hollow cathode lamp were performed for 11 levels of them together with other two levels reported in the literature, and branching fractions of 39 transitions were obtained. By combining them with lifetime values, the transition probabilities and absolute oscillator strengths of these lines were determined. [ABSTRACT FROM AUTHOR]

We continue a systematic study of chemical abundances of the strontium filament found in the ejecta of η Carinae. To this end we interpret the emission spectrum of Sc ii and Cr ii using multilevel non-local thermodynamic equilibrium models. Since the atomic data for these ions were previously unavailable, we carry out ab initio calculations of radiative transition rates and electron impact excitation rate coefficients. The observed spectrum is consistent with an electron density of the order of 107 cm−3 and a temperature between 6000 and 7000 K, conditions previously determined from [Ni ii], [Ti ii] and [Sr ii] diagnostics. The observed spectrum indicates an abundance of Sc relative to Ni more than 40 times the solar value, while the Cr/Ni abundance ratio is roughly solar. Various scenarios of depletion and dust destruction are suggested to explain such abnormal abundances. [ABSTRACT FROM AUTHOR]

Recent observations of thermally emitting isolated neutron stars revealed spectral features that could be interpreted as radiative transitions of He in a magnetized neutron star atmosphere. We present Hartree–Fock calculations of the polarization-dependent photoionization cross-sections of the He atom in strong magnetic fields ranging from 1012 to 1014 G. Convenient fitting formulae for the cross-sections are given along with the related oscillator strengths for various bound–bound transitions. The effects of finite nucleus mass on the radiative absorption cross-sections are examined using perturbation theory. [ABSTRACT FROM AUTHOR]

The rate coefficients for the formation of carbon monophosphide (CP) and silicon monophosphide (SiP) by radiative association are estimated for temperatures ranging from 300 to 14 100 K. In this temperature range, the radiative association rate coefficients are found to vary from to and from to for CP and SiP, respectively. In both cases, rate coefficients increase slowly with the increase in temperature. [ABSTRACT FROM AUTHOR]

A correction to the article "Radiative Association in Li+H Revisited: The Role of Quasi-Bound States," published in a 2003 issue is presented.