1. Energetic [1,2,5]oxadiazolo [2,3- a ]pyrimidin-8-ium Perchlorates: Synthesis and Characterization.
- Author
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Strizhenko KV, Smirnova AD, Filatov SA, Sinditskii VP, Stash AI, Suponitsky KY, Monogarov KA, Kiselev VG, and Sheremetev AB
- Subjects
- Friction, Ketones, Nuclear Magnetic Resonance, Biomolecular, Perchlorates, Antithyroid Agents
- Abstract
A convenient method to access the above perchlorates has been developed, based on the cyclocondensation of 3-aminofurazans with 1,3-diketones in the presence of HClO
4 . All compounds were fully characterized by multinuclear NMR spectroscopy and X-ray crystal structure determinations. Initial safety testing (impact and friction sensitivity) and thermal stability measurements (DSC/DTA) were also carried out. Energetic performance was calculated by using the PILEM code based on calculated enthalpies of formation and experimental densities at r.t. These salts exhibit excellent burn rates and combustion behavior and are promising ingredients for energetic materials.- Published
- 2022
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