In this paper, we presented new J -oriented basis sets, pecJ- n ( n = 1, 2), for phosphorus and silicon, purposed for the high-quality correlated calculations of the NMR spin-spin coupling constants involving these nuclei. The pecJ- n basis sets were generated using the modified version of the property-energy consistent (PEC) method, which was introduced in our earlier paper. The modifications applied to the original PEC procedure increased the overall accuracy and robustness of the generated basis sets in relation to the diversity of electronic systems. Our new basis sets were successfully tested on a great number of spin-spin coupling constants, involving phosphorus or/and silicon, calculated within the SOPPA(CCSD) method. In general, it was found that our new pecJ-1 and pecJ-2 basis sets are very efficient, providing the overall accuracy that can be characterized by MAEs of about 3.80 and 1.98 Hz, respectively, against the benchmark data obtained with a large dyall.aae4z + basis set of quadruple-ζ quality.