1. Effect of acidity in the removal-degradation of benzene in water catalyzed by Co-MCM-41 in medium containing hydrogen peroxide
- Author
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Francisco L. Castro, Yldeney Silva Domingos, Antonio S. Araujo, Marco Costa, Mirna F. Farias, Valter J. Fernandes, and Glauber José Turolla Fernandes
- Subjects
Inorganic chemistry ,chemistry.chemical_element ,02 engineering and technology ,General Chemistry ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,01 natural sciences ,Decomposition ,0104 chemical sciences ,Catalysis ,Metal ,chemistry.chemical_compound ,chemistry ,MCM-41 ,Mechanics of Materials ,visual_art ,visual_art.visual_art_medium ,General Materials Science ,0210 nano-technology ,Benzene ,Hydrogen peroxide ,Mesoporous material ,Cobalt - Abstract
In this manuscript, MCM-41 and Co-MCM-41 were synthesized to evaluate the effect of the metal incorporated in the structure of the mesoporous material used in the benzene removal in aqueous medium containing hydrogen peroxide (H 2 O 2 ). The decomposition of H 2 O 2 in the medium containing MCM-41 and Co-MCM-41 was investigated. The techniques used to characterize these materials showed satisfactory results, proving that the synthesis was effective. The decomposition of hydrogen peroxide carried out in the ultraviolet/visible molecular absorption spectrophotometer revealed that the pH of the medium and the presence of cobalt influence its decomposition. In the reaction containing benzene + Co-MCM-41 + H 2 O 2 , it was possible to confirm this information, because there was practically no decomposition at pH = 1.5, 3.0 and 5.0, whereas decomposition was considerable at pH = 7.0 and 10.0 and all H 2 O 2 was decomposed at pH = 12. Tests containing benzene + H 2 O 2 + MCM-41 resulted in a higher removal of analytes in an alkaline medium. The last catalytic tests contained benzene + Co(II) + H 2 O 2 in the aqueous reaction medium; compared to benzene + Co-MCM-41 + H 2 O 2 , it was found that the influence of Co-MCM-41 can be better viewed in pH = 10.0 and 12.0, because 82.1% of benzene was removed after 5 h.
- Published
- 2018