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This article reports on the relation between the surface topography and the optical reflectance, both total and diffuse, of different samples of AISI 430 ferritic stainless steel. Gaussian filters with different cutoff wavelengths were applied to the height maps of the surface topography of the samples, to separate the different scales of surface roughness involved in optical scattering in the visible range of the spectrum. Significant anisotropy, related to the rolling process, was found in the topography. An effective roughness slope parameter was defined from the dependence of the ratio between the root mean square height and the autocorrelation length on the cutoff wavelength. This roughness slope demonstrated an exceptionally good linear relationship with CIE 1931 luminance, which was calculated from the diffuse reflection spectra. The color uniformity of the samples was analyzed based on their CIE L*a*b* coordinates under daylight and LED illumination. The results confirmed the strong influence of manufacturing process on the surface characteristics of AISI 430 ferritic stainless steel sheet products with a bright finish.

Localised-in-the-edge oxidation of four AISI 430 alloys was investigated after an industrial bright annealing process. The oxidised surface of each specimen was characterised by X-ray photoelectron spectroscopy (XPS), Raman-spectroscopy and SEM. The results showed that the selective oxidation of Cr and Mn took place at the coil edges of AISI 430. This led to the formation of an oxide scale based on Cr2O3 and MnCr2O4. On the other hand, the formation of Cr(OH)3 and MnOOH in the outer part of the oxide scale was related to the effect of the H2–N2 environment on the annealing furnace. The results concluded that the composition of Cr and Mn in the alloy determined the composition of the oxidation products. However, the effect of annealing time was minor in this oxidation mechanism, which slightly contributed to an increase in the cation diffusion from the steel to the oxide. Finally, the results obtained indicate that the colouration of the coil edges displayed in each studied material varies according to the alloy chemical composition and annealing time.