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Start Over Author "Li, Shubai" Journal mendeleev communications
2 results on '"Li, Shubai"'

1. Nickel catalyzed hydrosilane reduction of (het)arenecarboxylic acids into aldehydes

Author

Li Shubai, Zhang Nana, Liang Wang, Yaoyao Wang, and Yu Tao

Subjects
010405 organic chemistry, Chemistry, Activator (genetics), chemistry.chemical_element, General Chemistry, 010402 general chemistry, Cleavage (embryo), 01 natural sciences, Medicinal chemistry, 0104 chemical sciences, Catalysis, Dimethyl dicarbonate, chemistry.chemical_compound, Nickel
Abstract

Nickel-catalyzed reduction of (het)arenecarboxylic acids with hydrosilanes in the presence of dimethyl dicarbonate as the activator affords the corresponding aldehydes. The role of the activator is the conversion of the acids into their anhydrides undergoing C–O cleavage. The good yields were achieved in case of substrates bearing electron-donating and electron-neutral groups.

Published
2021

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