1. Ag nanoparticle immobilized mesoporous TiO2-cobalt ferrite nanocatalyst: A highly active, versatile, magnetically separable and reusable catalyst
- Author
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Madhurya Chandel, Debabrata Moitra, Harshita Lulla, Barun Kumar Ghosh, and Narendra Nath Ghosh
- Subjects
Materials science ,Mechanical Engineering ,Inorganic chemistry ,Nanoparticle ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,Heterogeneous catalysis ,01 natural sciences ,0104 chemical sciences ,Catalysis ,Styrene ,chemistry.chemical_compound ,chemistry ,Chemical engineering ,Mechanics of Materials ,Styrene oxide ,General Materials Science ,0210 nano-technology ,Selectivity ,Photodegradation ,Mesoporous material - Abstract
Here, a simple method for preparation of a novel nanocatalyst, composed of Ag nanoparticle, mesoporous TiO 2 and CoFe 2 O 4 nanoparticle, has been reported for three important reactions (i) epoxidation of styrene, (ii) reduction of 4-nitrophenol (4-NP) and (iii) photocatalytic degradation of Methylene Blue dye. The synthesized catalyst exhibited high catalytic activities towards all of these three reactions. For styrene epoxidation, ∼98.1% conversion of styrene with ∼94.5% selectivity of styrene oxide was observed within 10 h. This catalyst catalyzed the reduction of 4-nitrophenol within 4 min with k app = 1.08 min −1 . The catalyst also showed complete photodegradation of Methylene Blue within 60 min under visible light exposure. The catalyst was easily recovered from the reaction mixture by applying a permanent magnet externally. The recovered catalyst also showed excellent reusability. Easy synthesis methodology, versatile catalytic activity, easy separation and good reusability make this nanocatalyst attractive in the field of heterogeneous catalysis.
- Published
- 2017
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