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Start Over Author "DI CAPUA, Roberto" Journal materials chemistry and physics
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2. Synthesis and characterization of conductive copper-based metal-organic framework/graphene-like composites

Author

L. Lisi, Roberto Di Capua, Valentina Gargiulo, Michela Alfè, Michela, Alfé, Valentina, Gargiulo, Luciana, Lisi, and DI CAPUA, Roberto

Subjects
Nanostructure, Materials science, Electrical characterisation, Graphene, Microporous materials, chemistry.chemical_element, Organometallic compounds, Composite materials, Carbon black, Condensed Matter Physics, Copper, Nanostructures, law.invention, chemistry, Composite materials, Organometallic compounds, Microporous materials, Nanostructures, Electrical characterisation, Electrical resistivity and conductivity, law, General Materials Science, Metal-organic framework, Composite material, Electrical conductor, Group 2 organometallic chemistry
Abstract

Metal-organic framework (MOF) incorporating conductive graphene-like layers were synthesized and characterized. The selected MOF, HKUST-1, combines high surface area, water stability, simple preparation and low costs. Graphene-like layers incorporated into the MOF structure were obtained by a two-step oxidation/reduction wet treatment of a high surface carbon black. MOF composites were produced at different carbonaceous layers content. It was shown, through a wide characterization of the samples, that the composites preserve the main features of the parent MOF, additional exhibiting a tunable electrical conductivity. © 2014 Elsevier B.V. All rights reserved.

Published
2014
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