1. Sorption Capacity of AlOOH/FeAl 2 Composites towards As(V).
- Author
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Kazantsev SO, Suliz KV, Rodkevich NG, and Lozhkomoev AS
- Abstract
The treatment of wastewater from arsenic compounds is an important and urgent problem. Composite nanostructures consisting of boehmite and iron compounds have a high adsorption capacity towards As(V) specie. In this work, the adsorption properties of nanostructured composites prepared by the oxidation of bimetallic Al/Fe nanoparticles with different iron contents were investigated. As a result of oxidation, boehmite AlOOH nanosheets are formed, with the resultant FeAl
2 nanoparticles being distributed on the surface of boehmite nanosheets. The nanostructured composites prepared from Al/Fe nanoparticles containing 20 wt% Fe have been found to show the highest adsorption capacity towards As(V) specie, being 248 mg/g. The adsorption isotherms are most accurately described by the Freundlich model, with the arsenic adsorption process obeying pseudo second order kinetics. As a result of the study, the optimal ratio of Al and Fe in Al/Fe nanoparticles has been determined to obtain an AlOOH/FeAl2 composite adsorbent with a developed and accessible surface and a high sorption capacity towards As(V). This allows us to consider this material as a promising adsorbent for the removal of arsenic compounds from water.- Published
- 2023
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