Search

We investigated the selective etching of Si versus Si1−xGex with various Ge concentrations (x = 0.13, 0.21, 0.30, 0.44) in tetramethyl ammonium hydroxide (TMAH) solution. Our results show that the Si1−xGex with a higher Ge concentration was etched slower due to the reduction in the Si(Ge)–OH bond. Owing to the difference in the etching rate, Si was selectively etched in the Si0.7Ge0.3/Si/Si0.7Ge0.3 multi-layer. The etching rate of Si depends on the Si surface orientation, as TMAH is an anisotropic etchant. The (111) and (010) facets were formed in TMAH, when Si was laterally etched in the <110> and <100> directions in the multi-layer, respectively. We also investigated the effect of the addition of Triton X-100 in TMAH on the wet etching process. Our results confirmed that the presence of 0.1 vol% Triton reduced the roughness of the etched Si and Si1−xGex surfaces. Moreover, the addition of Triton to TMAH could change the facet formation from (010) to (011) during Si etching in the <100>-direction. The facet change could reduce the lateral etching rate of Si and consequently reduce selectivity. The decrease in the layer thickness also reduced the lateral Si etching rate in the multi-layer. [ABSTRACT FROM AUTHOR]

Nanocomposite multi-layer TiO2/V2O5/TiO2 thin films were prepared via electron-beam evaporation using high-purity targets (TiO2 and V2O5 purity > 99.9%) at substrate temperatures of 270 °C (TiO2) and 25 °C (V2O5) under a partial pressure of oxygen of 2 × 10−4 mbar to maintain the stoichiometry. Rutherford backscattering spectrometry was used to confirm the layer structure and the optimal stoichiometry of the thin films, with a particle size of 20 to 40 nm. The thin films showed an optical transmittance of ~78% in the visible region and a reflectance of ~90% in the infrared. A decrease in transmittance was observed due to the greater cumulative thickness of the three layers and multiple reflections at the interface of the layers. The optical bandgap of the TiO2 mono-layer was ~3.49 eV, whereas that of the multi-layer TiO2/V2O5/TiO2 reached ~3.51 eV. The increase in the optical bandgap was due to the inter-diffusion of the layers at an elevated substrate temperature during the deposition. The intrinsic, structural, and morphological features of the TiO2/V2O5/TiO2 thin films suggest their efficient use as a solar water heater system. [ABSTRACT FROM AUTHOR]

In the present study, electro-explosive spraying technology was used to prepare a multi-layer composite coating with a staggered spatial structure on a 45 steel substrate, and the mechanical properties and wear behavior of the coating were studied. The composite coating was prepared by spraying Mo as the bonding layer, then spraying high-carbon steel and aluminum bronze alternately as a functional coating. The cross-sectional morphology, surface morphology and the properties of the coating were analyzed with a scanning electron microscope (SEM), energy dispersive spectrometer (EDS), electron backscattered diffraction (EBSD) and a 3D profilometer. The bonding strength, friction and wear resistance of the coating were studied by the bonding strength experiment and by the friction and wear experiment. The results showed that it is feasible to prepare a composite coating with a sponge-like spatial structure with electro-explosive technology. There was metallurgical bonding as well as mechanical bonding between the adjacent coating layers. The composite coating had the advantages of uniform thickness, high compactness, high bonding strength and good wear resistance. [ABSTRACT FROM AUTHOR]

Sub-monolayers of monodisperse Au colloids with different surface coverage have been embedded in between two different metal oxide thin films, combining sol-gel depositions and proper substrates functionalization processes. The synthetized films were TiO2, ZnO, and NiO. X-ray diffraction shows the crystallinity of all the oxides and verifies the nominal surface coverage of Au colloids. The surface plasmon resonance (SPR) of the metal nanoparticles is affected by both bottom and top oxides: in fact, the SPR peak of Au that is sandwiched between two different oxides is centered between the SPR frequencies of Au sub-monolayers covered with only one oxide, suggesting that Au colloids effectively lay in between the two oxide layers. The desired organization of Au nanoparticles and the morphological structure of the prepared multi-layered structures has been confirmed by Rutherford backscattering spectrometry (RBS), Secondary Ion Mass Spectrometry (SIMS), and Scanning Electron Microscopy (SEM) analyses that show a high quality sandwich structure. The multi-layered structures have been also tested as optical gas sensors. [ABSTRACT FROM AUTHOR]

Porous-silicon (PS) multi-layered structures with three stacked PS layers of different porosity were prepared on silicon (Si) substrates by successively tuning the electrochemical-etching parameters in an anodization process. The three PS layers have different optical bandgap energy and construct a triple-layered PS (TLPS) structure with multiple bandgap energy. Photovoltaic devices were fabricated by depositing aluminum electrodes of Schottky contacts on the surfaces of the developed TLPS structures. The TLPS-based devices exhibit broadband photoresponses within the spectrum of the solar irradiation and get high photocurrent for the incident light of a tungsten lamp. The improved spectral responses of devices are owing to the multi-bandgap structures of TLPS, which are designed with a layered configuration analog to a tandem cell for absorbing a wider energy range of the incidental sun light. The large photocurrent is mainly ascribed to an enhanced light-absorption ability as a result of applying nanoporous-Si thin films as the surface layers to absorb the short-wavelength light and to improve the Schottky contacts of devices. Experimental results reveal that the multi-bandgap PS structures produced from electrochemical-etching of Si wafers are potentially promising for development of highly efficient Si-based solar cells. [ABSTRACT FROM AUTHOR]

We present an approach for multi-layer preparation to perform microstructure analysis of a Li-ion cell anode active material using synchrotron tomography. All necessary steps, from the disassembly of differently-housed cells (pouch and cylindrical), via selection of interesting layer regions, to the separation of the graphite-compound and current collector, are described in detail. The proposed stacking method improves the efficiency of synchrotron tomography by measuring up to ten layers in parallel, without the loss of image resolution nor quality, resulting in a maximization of acquired data. Additionally, we perform an analysis of the obtained 3D volumes by calculating microstructural characteristics, like porosity, tortuosity and specific surface area. Due to a large amount of measurable layers within one stacked sample, differences between aged and pristine material (e.g., significant differences in tortuosity and speci?c surface area, while porosity remains constant), as well as the homogeneity of the material within one cell could be recognized. [ABSTRACT FROM AUTHOR]

Broad stopband filters are proposed, based on multilayer electromagnetically induced transparency (EIT) metamaterial structures. The single EIT metamaterial consists of a U-shaped resonator and a strip on a polyimide substrate. The EIT-like spectral feature is firstly utilized to achieve stopband filters by properly coupling two layers of EIT structure. Influences of different rotation angles on the transmission properties of the two-layer EIT structure are investigated. It is found the wider low-transmission band can be obtained for the Transverse Magnetic (TM) polarization when the two EIT metal structures are vertical to each other. Furthermore, the bandwidth of the stopband can be controlled by increasing layers of the EIT structures with the proper architectural design. The design using a coupling effect of multi EIT-like resonances in the metamaterial would provide a new method for broad stopband filters in highly integrated optical circuits. [ABSTRACT FROM AUTHOR]

Temperature and moisture can cause degradation to the impact properties of plant fiber-based composites owing to their complex chemical composition and multi-layer microstructure. This study focused on experimental characterization of the effect of important influencing factors, including manufacturing process temperature, exposure temperature, and water absorption, on the impact damage threshold and damage mechanisms of flax fiber reinforced composites. Firstly, serious reduction on the impact damage threshold and damage resistance was observed, this indicated excessive temperature can cause chemical decomposition and structural damage to flax fiber. It was also shown that a moderate high temperature resulted in lower impact damage threshold. Moreover, a small amount of water absorption could slightly improve the damage threshold load and the damage resistance. However, more water uptake caused severe degradation on the composite interface and structural damage of flax fiber, which reduced the impact performance of flax fiber reinforced composites. [ABSTRACT FROM AUTHOR]