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The large thickness COPV is designed by netting theory and the finite element simulation method, but the actual performance is low and the cylinder performance still cannot be improved after increasing the thickness of the composite winding layer. This paper analyzes the reasons for this and puts forward a feasible solution: without changing the thickness of the winding layer, the performance of COPV can be effectively increased by increasing the proportion of annular winding fiber. This method has been verified by tests and is supported by theory. [ABSTRACT FROM AUTHOR]

The nanoscale Cu-rich precipitates (CRPs) are one of the most critical microstructural features responsible for degrading the mechanical properties of reactor pressure vessel (RPV) steels. The prospect of the rapid regeneration of the service performance of degraded materials through electropulsing is attractive, and electropulsing has been proven to have the application potential to eliminate the CRPs and recover the mechanical properties of RPV materials. However, few studies have investigated the secondary service issue of electropulsing. This paper provides experimental findings from microstructural investigations and property evaluations of a FeCu RPV model alloy subjected to re-aging following recovery electropulsing and annealing treatments. The evolution behavior of CRPs and the changes in the hardness of the alloy during the re-aging process after electropulsing treatment were consistent with the initial aging process, while the re-aging process of the annealing treatment group was quite different from the initial aging. The difference between the electropulsing and annealing treatment groups was that the annealing treatment failed to eliminate the precipitates completely, leaving behind some large precipitates. This work demonstrates the potential application of EPT in this field. [ABSTRACT FROM AUTHOR]

With the development of the pressure vessel industry, high-energy wire welding has a great future. However, this means higher demands on the weldability of pressure vessel steels. Controlling inclusions via oxidative metallurgy is a reliable method of improving the weldability of pressure vessel steels. Hence, in this paper, experimental steels with different Mg element mass fractions were prepared using vacuum metallurgy. Simulated welding for high-heat input welding was carried out using the Gleeble-2000 welding thermal simulation test machine. The inclusions in the welding heat-affected zone (HAZ) in the experimental steels were observed using an optical microscope (OM) and scanning electron microscope (SEM). The compositions of the inclusions were analyzed using an energy-dispersive spectrometer (EDS). The research results indicated that the addition of Mg could increase the number density of the inclusions in the welding HAZ. With the addition of Mg from 0 to 5 wt.%, the total number density of the inclusions increased from 133 to 687 pieces/mm2, and the number density of the inclusions with a size of 0–5 μm2 increased from 122 to 579 pieces/mm2. The inclusions in the experimental steel welding HAZ with Mg elements were mainly elliptical composite inclusions composed of (Mg-Zr-O) + MnS. Moreover, MnS precipitated on the surface of the Mg-containing inclusions in the welding HAZ. Intragranular acicular ferrite (IAF) nucleation was primarily induced via the minimum lattice mismatch mechanism, supplemented with stress-strain energy and inert interface energy mechanisms. [ABSTRACT FROM AUTHOR]

The paper presents the issues related to the design and assessment of the technical condition as well as determination of the residual durability of pressure equipment. Based on a real a example, a liquid nitrogen spherical tank, we present the development and applicability of the method for assessment of the durability of the structure. In terms of the material itself, the authors analyze macroscale (structural) factors of the geometry of the real structure (by 3D scanning: material wear detection, deflections and deformations, etc.) and measured real operational loads to develop an integrated method, including material model and behavior in its operational condition, delivering a useful tool for macroscale structural analyses of the materials under complex load (mechanical, thermal, chemical, etc.). As a result, a detailed analysis of the tank is presented. The paper gives an idea of the method, its development, usefulness, and applicability of the presented approach by indication of the mutual influence of pressure vessel components (e.g., stubs, manholes) and operational loads, which may result in underestimating the strength and durability of the pressure vessels in the design process and during operation. [ABSTRACT FROM AUTHOR]

Thick plate steel structure is widely used in the construction machinery, pressure vessels, ships, and other manufacturing fields. To obtain an acceptable welding quality and efficiency, thick plate steel is always joined by laser-arc hybrid welding technology. In this paper, Q355B steel with a thickness of 20 mm was taken as the research object, and the process of narrow-groove laser-arc hybrid welding was studied. The results showed that the laser-arc hybrid welding method could realize one-backing and two-filling welding with the single-groove angles of 8–12°. At different plate gaps of 0.5 mm, 1.0 mm, and 1.5 mm, the shapes of weld seams were satisfied with no undercut, blowhole, or other defects. The average tensile strength of welded joints was 486~493 MPa, and the fracture position was in the base metal area. Due to the high cooling rate, a large amount of lath martensite formed in heat-affected zone (HAZ) and this zone exhibited higher hardness values. The impact roughness of the welded joint was almost 66–74 J, with different groove angles. [ABSTRACT FROM AUTHOR]

For decades, it has been known that the creation of oxygenated functional groups, especially carbonyl and sulfoxide, is among the main causes of chemical aging and degradation of asphalt. However, is the oxidation of a bitumen homogeneous? The focus of this paper was to follow the oxidation phenomena through an asphalt puck during a pressure aging vessel (PAV) test. According to the literature, the asphalt oxidation process that leads to the creation of oxygenated functions can be divided into the following successive main steps: the absorption of oxygen in asphalt at the air/asphalt interface, diffusion into the matrix, and reaction with asphalt molecules. To study the PAV oxidation process, the creation of carbonyl and sulfoxide functional groups in three asphalts were investigated after various aging protocols by Fourier transform infrared spectroscopy (FTIR). From these experiments performed on different layers of asphalt puck, it was observed that PAV aging resulted in a nonhomogeneous oxidation level inside the entire matrix. Compared to the upper surface, the lower section exhibited carbonyl and sulfoxide indices 70% and 33% lower, respectively. Moreover, the difference in the oxidation level between the top and bottom surfaces increased when the thickness and viscosity of the asphalt sample increased. [ABSTRACT FROM AUTHOR]

Thickness thinning is one of the processing defects that tend to occur in traditional stamping or mechanical bending of the plate and tube. In the field of high mechanical performance requirements (such as pressure vessels), the thinning phenomenon cannot be ignored. Thermal stress forming has excellent characteristics of forming without thinning, but the forming angle of this method is small, thus limiting the promotion and application of the process in the field of the form. To solve the problem, thermal stress forming with the baffle pressure method (BPM) is proposed. The coupled thermodynamic model of BPM is established, and the bending angle and deformation mechanism of the BPM are investigated. Lastly, the grain size and microhardness are measured and discussed. Results of the bending angle show that the proposed method can increase the bending angle by 57.71 times compared with the traditional method. The bending angle of BPM is determined by both the thermal buckling and the baffle, and the baffle plays a major role. The results of grain size and microhardness analysis show that the method refines the grain size, increases the material microhardness by 1.31 times and thickens the deformation zone by about 2.75%. In addition, the analytical equation of beam bending with laser as the heat source is given in this paper; this has some significance for further enrichment and development of the basic theory of beam thermoplastic bending. [ABSTRACT FROM AUTHOR]

Fracturing pumpheads are typical pressure vessels that experience frequent fatigue failure under the effect of notches in their cross-bore. To enhance the fatigue life of fracturing pumpheads, the study of the notch effect is indispensable and important to establish a reliable mathematical model to predict their fatigue life. In the present paper, two novel fatigue life prediction models are proposed for notched specimens. In these models, two new geometric fatigue failure regions are defined to improve the weight function. Finally, the elaborated novel stress-field intensity approach was applied to three different types of notched specimens. Experiment results indicate that the new SFI approach achieves 47.82%, 39.48%, and 31.85% higher prediction accuracy than the traditional SFI approach, respectively. It was found that the modified SFI approach provided better predictions than the traditional SFI approach and the TCD method. The II-th novel SFI approach had the highest accuracy, and the I-th novel SFI approach was more suitable for sharply notched specimens. [ABSTRACT FROM AUTHOR]

Metal cylindrical shells are widely used to store and transport highly hazardous chemicals. The impact resistance of metal cylindrical shells under an explosive load is a concern for researchers. In this paper, an innovative failure criterion considering the time effect is proposed for metal cylindrical shells under explosive loads. Firstly, based on the maximum shear stress criterion, an innovative failure criterion containing the time effect is provided. Then, a metal cylindrical shell model is established. Next, a failure pressure equation for metal shells under an explosive load is proposed based on the innovative failure criterion. Lastly, the proposed equation is verified by numerical simulation. The results indicate the failure pressure equation for a metal cylindrical shell under an explosive load uses the finite element method. Our research is of significance for fully understanding the failure mechanism of piping and pressure vessels under impact load. [ABSTRACT FROM AUTHOR]

A phenomenological model for estimating the effects of load ratio R and hydrogen pressure P H 2 on the hydrogen-assisted fatigue crack growth rate (HA–FCGR) behavior in the transient and steady-state regimes of pressure vessel steels is described. The "transient regime" is identified with crack growth within a severely embrittled zone of intense plasticity at the crack tip. The "steady-state" behavior is associated with the crack growing into a region of comparatively lower hydrogen concentration located further away from the crack tip. The model treats the effects of R and P H 2 as being functionally separable. In the transient regime, the effects of the hydrogen pressure on the HA–FCGR behavior were negligible but were significant in the steady-state regime. The hydrogen concentration in the steady-state region is modeled as being dependent on the kinetics of lattice diffusion, which is sensitive to pressure. Experimental HA–FCGR data from the literature were used to validate the model. The new model was shown to be valid over a wide range of conditions that ranged between − 1 ≤ R ≤ 0.8 and 0.02 ≤ P H 2 ≤ 103 MPa for pressure vessel steels. [ABSTRACT FROM AUTHOR]

Advanced thermoplastic composites manufacturing using laser assisted tape placement or winding (LATP/LATW) is a challenging task as monitoring and predicting nip point (bonding) temperature are difficult especially on curved surfaces. A comprehensive numerical analysis of the heat flux and temperature distribution near the nip point is carried out in this paper for helical winding of fiber reinforced thermoplastic tapes on a cylindrically shaped mandrel. An optical ray-tracing technique is coupled with a numerical heat transfer model in the process simulation tool. The developed optical-thermal model predictions were compared with experimental data available in literature to validate its effectiveness. The influences of winding/placement angle, mandrel curvature and tape width on the incident angles, the laser absorbed intensity, and the process temperature distribution are studied extensively using the validated model. Winding/placement angle has a considerable effect on the temperature distribution. Increase in winding angle results in a higher temperature for tape due to more reflections coming from the substrate. On the other hand, substrate temperature decreases as the winding angle increases due to a decrease in the laser incident angles based on the local surface curvature. An increase in mandrel curvature results in higher nip point temperatures for substrate and lower one for tape. Different mandrel sizes for 90 ° placement path do not have a strong effect on the substrate process temperature as for other winding angles because of less curvature change of the corresponding irradiated area. Tape width causes local temperature variations at the edges of the tape/substrate. In order to obtain the desired process temeprature during LATW or LATP processes, the laser intensity distribution on the tape and substrate surfaces should be regulated. [ABSTRACT FROM AUTHOR]

Glass fiber-reinforced composite cylinders, capable of withstanding internal pressure generated during service, are increasingly utilized as insulators in high voltage circuit breakers. Different testing procedures have been suggested by various standards to assess the pressure resistance of these components. Due to its simplicity and cost-effectiveness, the split-disk testing method is the most widely used for evaluating the hoop strength of pressure cylinders during the development and verification phases. However, the method presents several aspects, such as those related to the influence of specimen geometry and friction, which require further examination since they may impact the outcome of the experimental tests. The investigation, carried out by a combination of experimental testing and finite element analyses, shows that the friction between the specimen and the semi-disks has a noteworthy effect on the hoop load applied to the specimen. Almost constant load distributions along the hoop direction, representative of the real operating conditions in a pressurized cylinder, can be achieved via proper lubrication of the contact surfaces. Furthermore, FE analyses demonstrate that the notch geometry suggested by specific standards (short notch) is not capable of inducing a uniform strain distribution in the notched region. A different notch geometry (long notch) is proposed in the study to attain a more uniform strain field over the reduced area region. The experimental results indicate that the strength measured on the short notch specimens is higher than that determined on the long notch specimens, thus confirming the significant influence of strain distribution on the strength properties measured with the split-disk method. [ABSTRACT FROM AUTHOR]

Usually, the design of composite structures is limited to the linear elastic analysis only. The experimental results discussed in the paper demonstrate the physical non-linear behaviour both for unidirectional and woven roving composites. It is mainly connected with the micromechanical damages in composite structures, particularly with the effects of matrix cracking modeled in the form of elastic-plastic physical relations. In the present paper, the effects of both physical and geometrical non-linearities are taken into account. Their influence on the limit states (understood in the sense of buckling or failure/damage) of composite structures is discussed. The numerical examples deal with the behaviour of composite pressure vessels components, such as a cylindrical shell and the reinforcement of the junction of shells. The optimisation method of the reinforcement thickness is also formulated and solved herein. [ABSTRACT FROM AUTHOR]

Q960 high-strength steel is widely used in pressure vessels, bridges, offshore platforms and other important steel structural components because of its high strength and good plastic toughness, but alloy elements added to this kind of steel have strong hardenability, especially after welding, so the strength and toughness cannot meet the requirements, which limits its application in a wider range. In this paper, from the point of view of the metallurgical treatment of the weld, the goal is to improve the strength and toughness of the Q960 high strength steel weld metal In order to analyze the influence of Zr on the welding process of Q960 steel and the strengthening and toughening effect of weld metal, this paper takes Fe-Mn-Mo-Cr-Ni as the main alloy system, BaF2-CaF2-Al-Mg as the basic slag system, and adopts the method of melting consumable electrode self-shielded for welding, and analyzes the welding process, microstructure, tensile property and impact toughness of the welded joint. The experimental results show that when the weld metal contains 0.0061% Zr, the minimum spatter rate is only 7%, the maximum slag removal rate is 95%, the maximum hardness is 357HV, the maximum elongation is 34%, and the impact toughness is the highest. At this time, the acicular ferrite content in the weld microstructure is the highest, and there is a certain amount of equiaxed fine-grained ferrite, and the content of proeutectoid ferrite is the least, which effectively improves the strength and toughness of the weld metal. [ABSTRACT FROM AUTHOR]

The application of flat ends in pressure boilers is inevitably associated with the presence of stress concentration, which is observed in the vicinity of the junction of the cylinder and the closing flat plate. The analyzed flat end plates with stress relief grooves fall into the group of solutions recognized by the respective Standards of Calculations of Pressure Vessels. Unfortunately, no clear evidence is given in the Standards on how to choose the best groove parameters. This opens up the problem of the optimal choice of the groove parameters providing a minimum stress level. Even for the optimal values defining the stress relief groove geometry, certain plastic deformations are observed in the groove area for materials which exhibit elastic-plastic properties. Such a situation is completely unacceptable during exploitation, and a suitable reduction of the operating pressure is necessary. This paper discusses the effectiveness of other designs for flat ends used in pressure vessels. The proposed modifications took the form of external ribs applied around the top of the endplate circumference. The dimensions of these ribs were set using parametric optimization. The results of the study encouraged the authors to perform a more general analysis with the use of topology optimization. The results of all performed studies proved that the reduction of stress concentration and the full elimination of plastic deformation are possible. All numerical calculations were made using the finite element code (FEM), Ansys. [ABSTRACT FROM AUTHOR]

This paper discusses how the strain gradient influences the fatigue life of carbon steel in the low-cycle and high-cycle fatigue regimes. To obtain fatigue data under different strain distributions, cyclic alternating bending tests using specimens with different thicknesses and cyclic tension–compression tests were conducted on carbon steel for pressure vessels (SPV235). The crack initiation life and total failure life were evaluated via the strain-based approach. The experimental results showed that the crack initiation life became short with decreasing strain gradient from 102 to 106 cycles in fatigue life. On the other hand, the influence of the strain gradient on the total failure life was different from that on the crack initiation life: although the total failure life of the specimen subjected to cyclic tension–compression was also the shortest, the strain gradient did not affect the total failure life of the specimen subjected to cyclic bending from 102 to 106 cycles in fatigue life. This was because the crack propagation life became longer in a thicker specimen. Hence, these experimental results implied that the fatigue crack initiation life could be characterized by not only strain but also the strain gradient in the low-cycle and high-cycle fatigue regimes. [ABSTRACT FROM AUTHOR]

With the acceleration of the construction of sponge cities in China, porous asphalt pavement (PA) is has been widely used. High-viscosity asphalt (HVA) is the core material in building PA because it has good rheology properties, which can provide good raveling and rutting resistance. However, due to the open-graded structure of PA, HVA was more susceptible to rapid aging, which significantly affects the durability of PA. To investigate the thermal aging effect on the rheological properties of self-modified HVA (SHVA), five types of asphalts were aged using a rolling thin film oven (RTFO) and pressure aging vessel (PAV). Then, rheological tests were adopted, such as temperature sweep test (TS), repeated creep and recovery test (RCR), and bending beam rheometer test (BBR). The results indicate that during the aging process, the oxidation-induced hardening effect of neat asphalt and the degradation-induced softening effect of the modifier changes the rheology properties of HVA significantly. As the aging progresses, the contribution of the modifiers of HVA to anti-aging performance is greatly reduced. At high temperatures, HVA demonstrates better anti-aging performance than conventional styrene–butadiene–styrene (SBS)-modified asphalt (Guo Chuang, GC). The change of the high-temperature rheological indices of the two HVA types (SHVA and TAFPACK-super HVA (TPS)) showed a smaller activation energy index (EAI), a more considerable viscous component of binder creep stiffness (Gv), and more minor accumulated stain (racc), indicating a more significant anti-short-term and long-term aging performance, which is beneficial to the high-temperature performance of asphalts. However, the changes in low-temperature rheological properties do not align with those in high-temperature rheological properties after long-term aging. The BBR test results reveal that TPS exhibits worse low-temperature performance than GC and SHVA. During the thermal aging process, the contribution rate of the modifiers in SHVA against RTFO and PAV aging is higher than that of the modifiers in TPS, which contributes to the superior anti-aging property. Overall, SHVA demonstrates the best anti-aging performance among the five asphalts tested. [ABSTRACT FROM AUTHOR]

The automated fiber placement (AFP) process faces a crucial challenge: the emergence of out-of-plane buckling in thermoplastic prepreg tows during steering, significantly impeding the quality of composite layup. In response, this study introduces a novel approach: the development of equations for wrinkle-free fiber placement within composite pressure vessels. The investigation encompasses a detailed analysis of prepreg trajectories in relation to shell geometry, accompanied by an in-depth understanding of the underlying causes of wrinkling on dome surfaces. Moreover, a comprehensive model for shell coverage, grounded in placement parameters, is meticulously established. To validate the approach, a simulation tool is devised to calculate press roller motions, ensuring the uniform fiber dispersion on the mandrel and achieving flawless coverage of the shell without wrinkles. This innovative strategy not only optimizes the AFP process for composite layup but also remarkably enhances the overall quality of composite shells. As such, this research carries significant implications for the advancement of composite manufacturing techniques and the concurrent improvement in material performance. [ABSTRACT FROM AUTHOR]

The experimental and numerical analyses of the pressure vessels with different flat ends are presented and discussed in the paper. The main aim of the study is to propose the optimal flat head end geometry. The analyses are focused on the comparison of standardized geometries and with the proposed elliptical cut-out. The experimental tests with the application of strain-gauge measurements and numerical modeling of the pressure vessel are conducted. The behavior under low and high pressures and the influence of the residual welding stresses, material properties, and geometrical tolerances on the level of the plastic deformation in the flat end is discussed. It is presented that the rules given in the recent standard are not sufficient for optimal selection of the optimal geometry. It is observed that in certain geometries the deviations of the pipe thickness may lead to a significant increase of the equivalent stresses. The residual welding stresses have a significant influence on the stress and strain level—particularly in the stress relief groove (SRG). The performed study and comparison of the different geometries allow for the proposal of the optimal shape of the flat end. It appeared that the pressure vessels with SRG are the most optimal choice, particularly when elliptic shapes are in use. In some cases (i.e., pipe with wall-thickness equal to 40 mm and the flat end with circular SRG), the optimal configuration is reached for dimensions beyond the admissible by code range. [ABSTRACT FROM AUTHOR]

In this work, the stabilities of secondary phases, including carbides, brittle phases, and inclusions, were simulated by computational thermodynamics. Calphad strategical optimization is preferable for all steel alloys regarding energy resource consumption during manufacturing and processing. The alloy composition has been changed to enhance the strength, hardenability, and longevity of a reactor pressure vessel (RPV) steel by computing the phase equilibrium calculations and predicting mechanical properties such as yield and tensile strengths hardness and martensitic and bainitic volume fractions. The stabilities of the pro-eutectoid carbides (cementite), inclusions, and brittle phases in SA508 steel are critical to the toughness and fatigue life related to the crack initiation and expansion of this steel. Overall, the simulations presented in this paper explain the mechanisms that can affect the fatigue resistance and toughness of steel and offer a possible solution to controlling these properties at elevated temperatures by optimizing the steel composition and heat treatment process parameters. [ABSTRACT FROM AUTHOR]

The study investigated the effects of laboratory ageing on the fluxed and water-foamed asphalt binders in scope of Fourier transform infrared spectroscopic measurements of ageing indicators and changes in their chemical composition. The investigated binders included two paving grades, two polymer modified asphalt binders, and a highly modified asphalt binder. The bio-flux additive was produced from rapeseed methyl esters in an oxidation reaction in the presence of a metal catalyst and organic peroxide. The use of the bio-origin additive, in particular oil derivatives, was aimed at softening and better foaming of asphalt binders. This modification is possible due to the good mixability of vegetable oils with an asphalt binder, which gives a homogeneous product with reduced stiffness. The study involved the rolling thin film oven, short-term, and the pressure ageing vessel, long term, and ageing to induce oxidation on the evaluated asphalt binders. The addition of the bio-flux additive has significantly decreased the measured content of ketone compounds related to oxidation in both non-aged and aged asphalt binders, although this effect after ageing were far smaller in magnitude. Additionally, both ageing processes decreased significantly the absorbances in the ester spectral bands specific to the bio-flux additive. All mentioned effects were similar in magnitude in all tested asphalt binders. [ABSTRACT FROM AUTHOR]

The fatigue assessment of tube connections under cyclic pressure is discussed using four kinds of methods from ASME VIII-2 and EN 13445-3. FEA results are compared to the fatigue test, and some conclusions are obtained. Method 1 is the most widely used traditional method and can be used in both welded structures and unwelded structures. This method has simple operation, safety and reliability. Method 2 adopts the effective strain range to assess the fatigue for both the welded and the unwelded structure. This method is with high accuracy, good stability, safety and reliability, but the elastic–plastic analysis is very complicated. Method 3 adopts the equivalent structure stress to assess the fatigue of the welded, it is developed from fracture mechanics, and the procedure is also very complicated. Method 4 is a detailed assessment procedure for the welded and unwelded, and it is the most accurate, stable and reliable among the four methods. [ABSTRACT FROM AUTHOR]

The effect of CO2 curing on alkali-activated slag paste activated by a mixture of sodium hydroxide and sodium silicate solutions is reported in this paper. The paste samples after demolding were cured in three different curing environments as follows: (1) environmental chamber maintained at 85% relative humidity (RH) and 25 °C; (2) 3-bar CO2 pressure vessel; and (3) CO2 chamber maintained at 20% CO2 concentration, 70% RH and 25 °C. The hardened samples were then subjected to compressive strength measurement, X-ray diffraction analysis, and thermogravimetry. All curing conditions used in this study were beneficial for the strength development of the alkali-activated slag paste samples. Among the curing environments, the 20% CO2 chamber was the most effective on compressive strength development; this is attributed to the simultaneous supply of moisture and CO2 within the chamber. The results of X-ray diffraction and thermogravimetry show that the alkali-activated slag cured in the 20% CO2 chamber received a higher amount of calcium silicate hydrate (C-S-H), while calcite formed at an early age was consumed with time. C-S-H was formed by associating the calcite generated by CO2 curing with the silica gel dissolved from alkali-activated slag. [ABSTRACT FROM AUTHOR]

Specimens of 15Kh2MFAA steel used for reactor pressure vessels V-213 (VVER-440 reactor) were studied by positron annihilation techniques in terms of their radiation resistance and structural recovery after thermal treatment. The radiation load was simulated by experimental implantation of 500 keV H+ ions. The maximum radiation damage of 1 DPA was obtained across a region of 3 µm. Radiation-induced defects were investigated by coincidence Doppler broadening spectroscopy and positron lifetime spectroscopy using a conventional positron source as well as a slow positron beam. All techniques registered an accumulation of small open-volume defects (mostly mono- and di-vacancies) due to the irradiation, with an increase of the defect volume ΔVD ≈ 2.88 × 10−8 cm−3. Finally, the irradiated specimens were gradually annealed at temperatures from 200 to 550 °C and analyzed in detail. The best defect recovery was found at a temperature between 450 and 475 °C, but the final defect concentration of about ΔCD = 0.34 ppm was still higher than in the as-received specimens. [ABSTRACT FROM AUTHOR]

In order to verify the delamination damage occurring in thick-walled composite-overwrapped pressure vessels, firstly, for composite delamination damage, a composite laminate model was established. Model I and model II delamination failure processes of composite structures were simulated and verified based on a tiebreak contact algorithm for different mesh sizes, respectively, and the approximate equivalent results were achieved by correcting the inter-ply strength. Then, for in-plane damage to composite materials, the elastic–plastic process was verified by selecting a progressive damage model, with quasistatic nonlinear tensile shear of sample specimens as an example. Further, under the purpose of generality and simplicity, the location of the first occurrence of delamination failure was simulated and analyzed with the tiebreak contact algorithm and a reasonable mesh size, using quasistatic loading of a thick composite-overwrapped pressure vessel cylindrical section as an example. The results showed that delamination occurred at approximately the center, which is in general agreement with the experimentally observed phenomenon. On this basis, the locations of the first significant delamination phenomena in composite-overwrapped vessels under three different ratios of plus or minus 45-degree layup angles were predicted. Finally, the differences in structural strength between the single laying methods and the combined laying method were compared. The results showed that the ratio of 50% had a higher modulus value than a pure 0° ply, but too large a ratio was detrimental to the improvement of structural properties. [ABSTRACT FROM AUTHOR]

This study characterized the damage characteristics of carbon fiber composite pressure vessels by the modal acoustic emission (MAE) method. The study showed how to use the extracted damage modal features and established MAE parameters to determine the damage mode of composite pressure vessels. First, the A0 and S0 Lamb modes of the AE signal were split through mode separation, and the time window was selected to establish the MAE characteristic parameters. Subsequently, based on the MAE parameters and the damage mode characteristics established from single damage experiments, a damage mode discrimination method was established. A bending test of carbon fiber composite laminates proved that the modal separation method and the MAE parameters establishment are reasonable and effective. The results from the hydraulic test of the graded loading performed on 20 MPa carbon fiber composite pressure vessels showed the accuracy of the damage mode discrimination method, and the damage state of the pressure vessel could be analyzed using the fiber fracture damage threshold according to the MAE parameters. [ABSTRACT FROM AUTHOR]

This study investigates the effectiveness of processed oil in the modification of PG 64-22 and PG 76-22 by assessing their physical and rheological properties, and multiple comparison was conducted between the two binders. The base binders PG 64-22 and PG 76-22 were blended with processed oil at four different percentages of contents (3%, 6%, 9% and 12% by the weight of the binder) and compared with the control binder in each test. The base and modified binders were artificially short-term and long-term aged using a rolling thin film oven (RTFO) and pressure aging vessel (PAV) procedures. Superpave binder tests were performed on the modified binders by applying a rotational viscometer (RV), dynamic shear rheometer (DSR), and bending beam rheometer (BBR). The comparisons and results presented in this study indicate that (1) the processed oil has a significant effect on the binders' viscosity, which changes with respect to the increment of processed oil content. The viscosity of both modified binders decreased with the addition of 3, 6, 9 and 12% processed oil; (2) the performed DSR test showed that the addition of processed oil had a negative effect on the rutting resistance for both binders, since in PG 64-22, G*/Sin δ values decreased by 55, 65, 75 and 83% with the addition of 3, 6, 9 and 12% processed oil, respectively, while a decrement of G*/Sin δ of 24, 45, 58 and 65% with the addition of 3, 6, 9 and 12% processed oil was observed in PG 76-22; meanwhile, the fatigue cracking performance was improved and was found to be effective, while G* Sin δ in PG76-22 decreased by 9, 30, 36, and 52% and in PG 64-22 by 27, 44, 53, and 67% with the addition of 3, 6, 9 and 12% processed oil; (3) the results from the BBR test indicate significant improvement in the thermal cracking properties of the binders. The addition of 3, 6, 9 and 12% processed oil resulted in a decrease in the stiffness of both the PG 64-22 and PG 76-22 binders, with a positive effect consequently being observed on the m-values of the binders. [ABSTRACT FROM AUTHOR]

Nondestructive magnetic measurement methods can be successfully applied to determine the embrittlement of nuclear pressure vessel steel caused by neutron irradiation. It was found in previous works that reasonable correlation could be obtained between the nondestructively measured magnetic parameters and destructively determined ductile-to-brittle transition temperature. However, a large scatter of the measurement points was detected even in the cases of the non-irradiated reference samples. The reason for their scattering was attributed to the local inhomogeneity of material. This conclusion is verified in the present work by applying three different magnetic methods on two sets of Charpy samples made of two different reactor steel materials. It was found that by an optimal magnetic pre-selection of samples, a good, linear correlation can be found between magnetic parameters as well as the ductile-to-brittle transition temperature with low scattering of points. This result shows that neutron irradiation embrittlement depends very much on the local material properties. [ABSTRACT FROM AUTHOR]

The aging of bitumen is detrimental to the durability and service life of asphalt pavement. Previous studies found that bitumen was suspected to be aged by not only thermal oxidation but also solution immersion. This research aims to compare the effect of thermal-oxidative aging and salt solution aging on bitumen performance. For this purpose, a thin film oven test (TFOT) and pressure aging vessel aging (PAV) were selected as thermal-oxidative aging, and 10% NaCl aging and 10% CaCl2 aging were selected as salt solution aging. The morphology, oxygen content, physical properties, low-temperature properties, and high-temperature properties of bitumen were analysed by employing scanning electron microscopy with an energy dispersive spectrometer (SEM-EDS), physical tests, a bending beam rheometer (BBR), and a dynamic shear rheometer (DSR). Test results show that both thermal-oxidative aging and salt solution aging had similar influencing trends in the oxygen content, physical, low-temperature, and high-temperature properties of bitumen but had different changes in morphology. The aging degrees caused by four kinds of aging methods were obtained based on the summed values of the absolute aging factor of all parameters: PAV > 10% NaCl > TFOT > 10% CaCl2. The conclusions could provide a theoretical basis to establish a standard for the solution aging of bitumen. [ABSTRACT FROM AUTHOR]

The objective of this study is to evaluate the rheological properties of SBS/CRP composite modified asphalt under different aging conditions in alpine cold regions. In this study, the styrene-butadiene-styrene (SBS) block copolymer, crumb rubber powder (CRP), softeners and various additives were used to prepare the SBS/CRP composite modified asphalt. The 4.5% SBS modified asphalt and SK90 virgin asphalt were also selected for comparing. The thin film oven test (TFOT) and pressure aging vessel (PAV) aging test were conducted to simulate the different aging conditions. The frequency sensitivity, high-temperature deformation resistance and low-temperature crack resistance of SBS/CRP composite modified asphalt under different aging conditions were studied by the dynamic shear rheometer (DSR) and bending beam rheometer (BBR) test. The results show that the frequency sensitivity of SBS/CRP composite modified asphalt is the lowest. At low and medium temperatures, it has relatively low strength and good flexibility. The master curve of composite modulus for the unaged and aged SBS/CRP composite modified asphalt is in a cluster state. It has strong anti-aging capability, which is less affected by aging conditions. It also has a strong low-temperature relaxation ability, which can meet the requirements of performance at −24 °C in PG classification. The high-temperature deformation resistance of SBS/CRP composite modified asphalt is not much different from SBS modified asphalt's. Therefore, it can provide the basic support for the application in alpine cold regions under the conditions of low temperature, strong radiation and heavy load. [ABSTRACT FROM AUTHOR]

Aging of asphalt binders is one of the main causes of its hardening, which negatively affects the cracking and fatigue resistance of asphalt binders. Understanding asphalt aging is crucial to improve the durability of asphalt pavements. In this regard, this study aims at understanding and differentiating the effect of temperature and oxygen uptake on the aging mechanisms of unmodified asphalt binders. For that, four laboratory aging procedures were employed. The two standardized procedures, rolling thin-film oven test (RTFOT) and pressure aging vessel (PAV), were considered to simulate the short-term and long-term aging of the asphalt binders, respectively. In addition, two thin-film aging test procedures, the nitrogen atmosphere oven aging test (NAAT) and ambient atmosphere oven aging test (OAAT) were employed to assess the effect of thermal and oxidative aging on unmodified asphalt binder properties. The NAAT procedure is based on the principle that the inert gas minimizes the oxidative aging. The rheological and chemical characterization showed that the high temperatures considered during the NAAT procedure did not change the properties of the unmodified asphalt binders. Therefore, it can be hypothesized that no significant thermal and oxidative aging was observed during NAAT aging procedure for the considered binders and that oxidative aging is the main cause for the hardening. [ABSTRACT FROM AUTHOR]

This study examined the effects of alloying elements (C, Mo) on hydrogen-induced cracking (HIC) and sulfide stress cracking (SSC) behaviors of A516-65 grade pressure vessel steel in sour environments. A range of experimental and analytical methods of HIC, SSC, electrochemical permeation, and immersion experiments were used. The steel with a higher C content had a larger fraction of banded pearlite, which acted as a reversible trap for hydrogen, and slower diffusion kinetics of hydrogen was obtained. In addition, a higher hardness in the mid-thickness regions of the steel, due to center segregation, resulted in easier HIC propagation. On the other hand, the steel with a higher Mo content showed more dispersed banded pearlite and a larger amount of irreversibly trapped hydrogen. Nevertheless, the addition of Mo to the steel can deteriorate the surface properties through localized pitting and the local detachment of corrosion products with uneven interfaces, increasing the vulnerability to SSC. The mechanistic reasons for the results are discussed, and a desirable alloy design for ensuring an enhanced resistance to hydrogen assisted cracking (HAC) is proposed. [ABSTRACT FROM AUTHOR]

Curing by CO2 is a way to utilize CO2 to reduce greenhouse gas emissions. Placing early-age cement paste in a CO2 chamber or pressure vessel accelerates its strength development. Cement carbonation is attributed to the quickened strength development, and CO2 uptake can be quantitatively evaluated by measuring CO2 gas pressure loss in the pressure vessel. A decrease in CO2 gas pressure is observed with all cement pastes and mortar samples regardless of the mix proportion and the casting method; one method involves compacting a low water-to-cement ratio mix, and the other method comprises a normal mix consolidated in a mold. The efficiency of the CO2 curing is superior when a 20% concentration of CO2 gas is supplied at a relative humidity of 75%. CO2 uptake in specimens with the same CO2 curing condition is different for each specimen size. As the specimen scale is larger, the depth of carbonation is smaller. Incorporating colloidal silica enhances the carbonation as well as the hydration of cement, which results in contributing to the increase in the 28-day strength. [ABSTRACT FROM AUTHOR]

Welding distortion is a critical issue as it leads to severe deterioration of structural integrity of welded work piece and dimensional precision. This study aims at studying the effects of shielded metal arc welding (SMAW) parameters on the evolution of mechanical properties, including tensile strength, impact toughness, and hardness, along with angular distortion on a welded joint from SA 516 grade 70. Such parameters are analyzed and optimized by employing the Taguchi method and Grey relational analysis. SA 516 grade 70 is commercially used for fabrication of storage tanks, boilers and pressure vessels. SMAW is investigated with three levels of root gap, groove angle, electrode diameter, and pre-heat temperature, which were varied on a butt joint in flat (1 G) position to determine their effects on response variables at room temperature. Nine experiments were designed using a Taguchi L9 orthogonal array, welded according to American Society of Mechanical Engineers (ASME) section IX, and samples were prepared and tested as per ASTM A 370. The Taguchi method and Grey relational analysis were employed to observe the most significant parameters and optimal levels that synergically yield improved responses. Results are validated by conducting confirmatory experiments that show good agreement with optimum results. [ABSTRACT FROM AUTHOR]

The load–deflection curve acquired from the Small Punch Test (SPT) is used to obtain the mechanical properties of materials using different correlation methods. The scattering level of these regressions tends to be high when a wide set of materials is analyzed. In this study, a correlation method based on a specific slope of the SPT curve was proposed to reduce scattering. Assuming the Ramberg–Osgood hardening law, the dependence of the SPT curve slope on the yield strength and the hardening coefficient is demonstrated by numerical simulations (FEM). Considering that the ultimate tensile strength could be obtained from the hardening coefficient, a response surface of the ultimate tensile strength with the yield strength and SPT curve slope, along with its equation, is presented for steel alloys. A summary of steel mechanical properties, based on the Boiler and Pressure Vessel Code (BPVC) and limited to yield strengths lower than 1300 MPa, is shown to select a set of experimental tests (tensile tests and SPTs) for which the range is completely covered. This experimental analysis validates the previous FEM analyses and the validity of the proposed correlation method, which shows more accurate correlations compared to the current methods. [ABSTRACT FROM AUTHOR]