1. Selective oxidation of rare metal oxide insulation layers on particle substrates for optimizing the performance of FeSiCr-based soft magnetic composites.
- Author
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Huang, Huaqin, Wang, Jian, Cui, Zhenghao, Gao, Zihan, Huang, Zhenyi, and Wu, Zhaoyang
- Subjects
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NONFERROUS metals , *CERIUM oxides , *EDDY current losses , *FERROMAGNETIC materials , *ELECTROMAGNETIC devices , *METALLIC oxides , *MAGNETIC alloys , *THERMAL insulation - Abstract
[Display omitted] • Gained FeSiCr-based SMCs with a CeO 2 ·SiO 2 composite layer by selective oxidation between substrate and CeO 2 insulation layer. • The CeO 2 insulation layer promotes selective oxidation of Si in substrate during sintering in water vapor environment. • CeO 2 ·SiO 2 composite insulation layer demonstrated a 22.9% reduction in core loss than using the CeO 2 insulating layer alone. • CeO 2 ·SiO 2 composite insulation layer mitigated core loss while maintaining high magnetic conductivity in FeSiCr-based SMCs. This study introduces an approach to fabricating soft magnetic composites (SMCs) that effectively address core loss while maintaining high magnetic conductivity. During the sintering process in a water vapor environment, the CeO 2 insulation layer facilitates the selective oxidation of Si while simultaneously impeding the outward diffusion of Fe and Cr. Consequently, a CeO 2 ·SiO 2 composite insulation layer forms within the FeSiCr-based SMCs. The FeSiCr-based SMCs with the CeO 2 ·SiO 2 composite insulation layer achieve a saturation magnetization of 153.1 emu/g, which is 10.9% lower than that of FeSi 3.7 Cr 4.5 compacts, and exhibits a deterioration rate lower than previously reported values. Moreover, the permeability of the FeSiCr-based SMCs remains highly stable, demonstrating outstanding insulation characteristics. The total core loss and core loss separation results further corroborate that incorporating a CeO 2 ·SiO 2 composite insulation layer leads to a more pronounced reduction in interparticle eddy current loss than using a CeO 2 insulating layer alone. This performance enhancement can be attributed to the selective oxidation of a rare metal oxide insulation layer on a ferromagnetic metal particle substrate, a technique applied to SMCs for the first time. These findings hold significant implications for the design of high-performance SMCs in miniaturized and lightweight electromagnetic devices. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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