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Your search keyword '"Le Lagadec, Ronan"' showing total 4 results
Start Over Author "Le Lagadec, Ronan" Journal macromolecular symposia
4 results on '"Le Lagadec, Ronan"'

4. Application and Modification of Cyclometalated Ruthenium(II) Complex [Ru(o‐C6H4‐2‐C5H4N)‐ (MeCN)4]PF6for Atom Transfer Radical Polymerization

Author

Camacho, Francisco Diaz, Morales, Salvador Lopez, Le Lagadec, Ronan, and Alexandrova, Larissa

Abstract

Polymerizations of n‐butyl acrylate (BA), methyl methacrylate (MMA) and styrene (St) were promoted by the Ru(II) cyclometalated complex with labile MeCN ligand in the presence of Al(OiPr)3. The polymerization proceeds via radical mechanism and requires the loss of MeCN ligand. The poor control over the polymerizations can be explained in terms of the traditional ATRP scheme. However, the controllability may be significantly improved by addition of reducing SnCl2. Mechanism of the process is proposed.

Published
2006
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