1. Pt−Ru/CeO2/Carbon Nanotube Nanocomposites: An Efficient Electrocatalyst for Direct Methanol Fuel Cells
- Author
-
Zhimin Liu, Hongye Zhang, Xiang Wang, Zhenyu Sun, Ping Yu, and Lanqun Mao
- Subjects
Nanotube ,Materials science ,Nanocomposite ,Nanoparticle ,Nanotechnology ,Surfaces and Interfaces ,Carbon nanotube ,Condensed Matter Physics ,Electrocatalyst ,Catalysis ,law.invention ,chemistry.chemical_compound ,X-ray photoelectron spectroscopy ,Chemical engineering ,chemistry ,law ,Electrochemistry ,General Materials Science ,Methanol ,Spectroscopy - Abstract
Pt-Ru/CeO(2)/multiwalled carbon nanotube (MWNT) electrocatalysts were prepared using a rapid sonication-facilitated deposition method and were characterized by X-ray diffraction (XRD), X-ray photoemission spectroscopy (XPS), transmission electron microscopy (TEM), energy-dispersive spectroscopy (EDS), and voltammetry. Morphological characterization by TEM revealed that CeO(2) nanoparticles (NPs) were in intimate contact with Pt-Ru NPs, and both were highly dispersed on the exteriors of nanotubes with a small size and a very narrow size distribution. Compared with the Pt-Ru/MWNT and Pt/MWNT electrocatalysts, the as-prepared Pt-Ru/CeO(2)/MWNT exhibited a significantly improved electrochemically active surface area (ECSA) and a remarkably enhanced activity toward methanol oxidation. The effects of the Pt-Ru loading and the Pt-to-Ru molar ratio on the electrocatalytic activity of Pt-Ru/CeO(2)/MWNT for methanol oxidation were investigated. We found that a maximum activity toward methanol oxidation reached at the 10 wt % of Pt-Ru loading and 1:1 of Pt-to-Ru ratio. Moreover, the role of CeO(2) in the catalysts for the enhancement of methanol oxidation was discussed in terms of both bifunctional mechanism and electronic effects.
- Published
- 2010