1. Caulking polydimethylsiloxane molecular networks by thermal chemical vapor deposition of Parylene-C
- Author
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Wei Wang, Chi Mo, Lingqian Zhang, Wengang Wu, Yanping Cao, and Yaoping Liu
- Subjects
chemistry.chemical_classification ,Materials science ,Polydimethylsiloxane ,Scanning electron microscope ,010401 analytical chemistry ,Biomedical Engineering ,Nucleation ,Bioengineering ,Nanotechnology ,02 engineering and technology ,General Chemistry ,Polymer ,021001 nanoscience & nanotechnology ,01 natural sciences ,Biochemistry ,0104 chemical sciences ,chemistry.chemical_compound ,Chemical engineering ,chemistry ,Surface modification ,Deposition (phase transition) ,0210 nano-technology ,Hybrid material ,Layer (electronics) - Abstract
Surface functionalization of polydimethylsiloxane (PDMS) is important in developing high-performance microfluidic devices. This work applied the thermal chemical vapor deposition (t-CVD) of Parylene-C onto PDMS to caulk the molecular network while retaining the original surface properties for the oxygen plasma bonding. The very low deposition rates (for example, a nominal rate of 0.12 A min-1 at 135 °C) of Parylene-C at elevated substrate temperatures enabled the reactive Parylene-C monomers to penetrate into the PDMS matrix up to 4.6 ± 0.1 μm (135 °C), which was verified for the first time by a scanning electron microscope with an energy dispersive X-ray analysis (SEM-EDAX). The Parylene-C caulked in the molecular network of PDMS matrix guaranteed an excellent resistance to small molecule permeations. Meanwhile, only discrete nucleation islands were formed on the top surface rather than a continuous Parylene-C layer as observed under the AFM scan, which made the processed PDMS surface ready for device assembly. This surface functionalization method has better long-term stability than the other wet-type rivals. The barrier for oxygen plasma bonding in previously reported dry surface treatments was also avoided, thereby, facilitating the device assembly. The present work successfully developed a novel pcPDMS (Parylene-C caulked PDMS) technique, which overcame the bonding difficulty in the previous works but retained the low small molecule permeability as before. Caulking a molecular network through the t-CVD of Parylene-C also demonstrated a new strategy of functionalizing polymer surfaces and preparing new hybrid materials for wide lab-on-a-chip applications.
- Published
- 2016