1. Study of phase change heat absorption on inhibiting coal spontaneous combustion: microcalorimetry and coal autoxidation properties under the interrupted programmed heating.
- Author
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Xin, Haihui, Wang, Hezi, Zhang, Pengcheng, Qi, Zhangfan, Zhou, Banghao, Wu, Jinfeng, Huang, Yingming, Wu, Zhiwen, Xu, Chun, and Wang, De-ming
- Subjects
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SPONTANEOUS combustion , *HEAT radiation & absorption , *COAL combustion , *ENTHALPY , *PHASE change materials , *OXIDATION - Abstract
Coal spontaneous combustion (CSC) is one of the main disasters in the process of coal mining. In this paper, the important role of high-latent heat phase change material CH3COONa·3H2O (SAT) in controlling CSC was studied and compared with common inhibitors (NaCl, CaCl2, ascorbic acid (VC)). The thermal performance characteristics of SAT were revealed by the C80 micromanometer, and the effects of different inhibitors on the thermal behavior of Shengli lignite were analyzed and compared. Furthermore, the gas–solid coaxial fixed bed measurement system was used in conjunction with the Pfeiffer online mass spectrometer, to design the natural temperature rise experiment of coal after the heating interruption in the same programmed temperature rise interval, investigating the effects of different inhibitors on the temperature and gas production in the process of coal oxidation. The results show that the heat absorption effect of SAT is more significant than common inhibitors, which not only improves the heat absorption rate of the samples but also increases the total heat absorption of the sample by 236.6 J·g−1 compared with the raw coal. In the programmed temperature rise experiment, the maximum temperature point of the SAT-inhibited coal sample is reduced by 15.5% compared with raw coal, the time to reach the maximum temperature point is delayed by 20.5%, and the SAT inhibitor effectively inhibits the production of CO and CO2 gases. The method described in this paper provides a new idea for the prevention and control of CSC. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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