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Graphene is one of the important candidates in ceramic toughening due to its outstanding physical and chemical properties. For the weak interface toughening of large-diameter graphene sheet and alleviation of the interfacial reaction between ceramic precursors and graphene sheets during high-temperature pyrolysis, ZrC–SiC‒Graphene composite was synthesized via a facile technology of infiltrating ceramic slurry instead of ceramic precursor into macroporous graphene network and spark plasma sintering. The incorporation of the graphene network improved fracture toughness, critical crack size, and fracture energy of ZrC–SiC ceramic. The multiple length-scale toughening mechanisms of ZrC–SiC‒Graphene composite include the macroscopic toughening mechanism of crack deflection and bifurcation and the micro toughening mechanism of graphene bridging, ceramic micro zone tearing, graphene pull-out, graphene and ceramic brick slipping.

Multi-composition coating consisting of multilayer MoSi 2 -SiC w -SiB 6 -borosilicate glass/TaSi 2 -MoSi 2 -SiC w -SiB 6 -borosilicate glass has been prepared on the surface of SiOC ceramics-modified carbon bonded carbon fiber composites by a rapid sintering method. Arc jet test has been utilized to evaluate the oxidation-resistance ability from room temperature to 1800 K during the total exposure time between 1000 s and 1500 s. The experimental results show that the multilayer coating can form a robust oxidation protection layer to protect M-CBCF substrates effectively. The surface temperatures of tested samples reach 1573–1973 K and mass ablation rates of the samples vary from 1.23 × 10 −6 g/s cm 2 to 9.39 × 10 −6 g/s cm 2 .