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Your search keyword '"Mulder, Willem H."' showing total 2 results
Start Over Author "Mulder, Willem H." Journal journal of the american chemical society
2 results on '"Mulder, Willem H."'

1. Experimental study of the interplay between long-range electron transfer and redox probe permeation at self-assembled monolayers: Evidence for potential-induced ion gating

Author

Cakvente, Juan Jose, Mulder, Willem H., Lopez-Perez, German, Andreu, Rafael, Ranirez, Pablo, Fernandez, Hector, and Zon, Maria Alicia

Subjects
Oxidation-reduction reaction -- Research, Ruthenium -- Electric properties, Electron transport -- Research, Chemistry
Abstract

Evidence for the competition between long-range electron transfer across self-assembled monolayers (SAMs) and incorporation of the redox probe into the film is reported for the electroreducion of Ru[NH(sub 3)](sub 6)(super 3+) at hydroxyl- and carboxylic-acid-terminated SAMs on a mercury electrode. Experimental evidence for voltage-induced gating of these monolayers is obtained in the form of a chronoamperometric spike, suggesting a disordering and partial desorption of the monolayer.

Published
2005

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