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For Hermitian and non-Hermitian Hamiltonian matrices H, we present the Schr¨odinger equation for qudit (spin-j system, N-level atom) with the state vector |ψ〉 in a new form of the linear eigenvalue equation for the matrix ℋ = (H ⊗ 1N) and the probability eigenvector |p〉 identified with quantum states in the probability representation of quantum mechanics. We discuss the possibility to experimentally detect the difference between the system states described by the solutions, corresponding to the Schrodinger equation with Hermitian and non-Hermitian Hamiltonians, by measuring the probabilities of artificial spin-1/2 projections m = ± 1/2, sets of which are identified with qudit states. We show that different symmetries of systems, including 𝒫𝒯 -symmetry and broken 𝒫𝒯 -symmetry, are determined by a set of N complex eigenvalues of the Hamiltonian matrix H.

We extend the Bell inequality known for two qubits to the four-level atom, including an artificial atom realized by the superconducting circuit, and qudit with j = 3/2. We formulate the extended inequality as the inequality valid for an arbitrary Hermitian nonnegative 4×4 matrix with unit trace for both separable and entangled matrices.

We obtain a new inequality for arbitrary Hermitian matrices. We describe particular linear maps called the matrix portrait of arbitrary N × N matrices. The maps are obtained as analogs of partial tracing of density matrices of multipartite qudit systems. The structure of the maps is inspired by “portrait” map of the probability vectors corresponding to the action on the vectors by stochastic matrices containing either unity or zero matrix elements. We obtain new entropic inequalities for arbitrary qudit states including a single qudit and discuss entangled single qudit state. We consider in detail the examples of N = 3 and 4. Also we point out the possible use of entangled states of systems without subsystems (e.g., a single qudit) as a resource for quantum computations.