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The development of full-spectrum photocatalysts active in the near-infrared (NIR) region has gained increasing attention for deleterious pollutant removal. The integration of plasmonic metals with semiconductors is an effective way to widen the light response range of photocatalysts due to the strong light absorption and fast plasmonic energy transfer of the localized surface plasmon resonance (LSPR). In this work, the full-spectrum responsive Bi@SrTiO3was prepared via facile solvothermal chemical reduction. The optimal Bi@SrTiO3achieves exceptional photocatalytic Cr(VI) reduction efficiency and tetracycline degradation, realizing bi-directional promotion effects on redox reaction. According to density functional theory (DFT) simulations, the extraordinary photocatalytic performance is attributed to the tunable built-in electric field (IEF) of the Ohmic contact. The favorable adaptability in real water and high stability of BSTO-25 were proved by experimental results. And the possible photocatalytic mechanism was proposed based on theoretical calculation and experimental results. Furthermore, the non-toxicity of the BSTO-25 was evaluated by E.colicultivation, which further proves the feasibility of treating wastewater with BSTO-25. This work provides a new perspective on constructing full-spectrum-driven photocatalysts for applications dealing with environmental remediation.