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The hybridization of gas turbine technology with high temperature fuel cells represents an ultra-high efficiency, ultra-low emission, fuel flexible power generation platform. The performance of past prototypes has been limited by marginal compatibility of the two primary sub-systems. This paper addresses the challenge of selecting compatible hardware by presenting a simple and robust method for bespoke hybrid system design and off-the-shelf component integration. This is the first application of detailed, spatially resolved, physical models capable of resolving off-design performance to the integration analysis of FC-GT hybrids. Static maps are produced for both turbine and fuel cell sub-systems that readily evaluate the compatibility and hybrid performance. Molten carbonate and solid oxide fuel cells are considered for hybridization with recuperated micro-turbines and larger axial flow gas turbine systems. Current state-of-the-art molten carbonate technology is shown to pair well with present micro-turbine technology in an FC bottoming cycle design achieving 74.4% LHV efficiency. Solid oxide technology demonstrates remarkable potential for integration with larger scale axial turbo-machinery to achieve greater than 75% LHV efficiency. This performance map technique closely matches results from detailed integrated hybrid system analyses, and enables quick determination of performance requirements for balance of plant design and optimization. © 2014 Elsevier B.V. All rights reserved.

Fuel cell gas turbine hybrid systems have achieved ultra-high efficiency and ultra-low emissions at small scales, but have yet to demonstrate effective dynamic responsiveness or base-load cost savings. Fuel cell systems and hybrid prototypes have not utilized controls to address thermal cycling during load following operation, and have thus been relegated to the less valuable base-load and peak shaving power market. Additionally, pressurized hybrid topping cycles have exhibited increased stall/surge characteristics particularly during off-design operation. This paper evaluates additional control actuators with simple control methods capable of mitigating spatial temperature variation and stall/surge risk during load following operation of hybrid fuel cell systems. The novel use of detailed, spatially resolved, physical fuel cell and turbine models in an integrated system simulation enables the development and evaluation of these additional control methods. It is shown that the hybrid system can achieve greater dynamic response over a larger operating envelope than either individual sub-system; the fuel cell or gas turbine. Results indicate that a combined feed-forward, P-I and cascade control strategy is capable of handling moderate perturbations and achieving a 2:1 (MCFC) or 4:1 (SOFC) turndown ratio while retaining >65% fuel-to-electricity efficiency, while maintaining an acceptable stack temperature profile and stall/surge margin. © 2014 Elsevier B.V. All rights reserved.

A dynamic internal reforming-solid oxide fuel cell system model is developed and used to simulate the coproduction of electricity and hydrogen while meeting the measured dynamic load of a typical southern California commercial building. The simulated direct internal reforming-solid oxide fuel cell (DIR-SOFC) system is controlled to become an electrical load following device that well follows the measured building load data (3-s resolution). The feasibility of the DIR-SOFC system to meet the dynamic building demand while co-producing hydrogen is demonstrated. The resulting thermal responses of the system to the electrical load dynamics as well as those dynamics associated with the filling of a hydrogen collection tank are investigated. The DIR-SOFC system model also allows for resolution of the fuel cell species and temperature distributions during these dynamics since thermal gradients are a concern for DIR-SOFC. © 2013 Elsevier B.V. All rights reserved.

The degradation of solid oxide fuel cells (SOFC) depends on stack and system design and operation. A methodology to evaluate synergistically these aspects to achieve the lowest production cost of electricity has not yet been developed. A repeating unit model, with as degradation processes the decrease in ionic conductivity of the electrolyte, metallic interconnect corrosion, anode nickel particles coarsening and cathode chromium contamination, is used to investigate the impact of the operating conditions on the lifetime of an SOFC system. It predicts acceleration of the degradation due to the sequential activation of multiple processes. The requirements for the highest system efficiency at start and at long-term differ. Among the selected degradation processes, those on the cathode side here dominate. Simulations suggest that operation at lower system specific power and higher stack temperature can extend the lifetime by a factor up to 10, because the beneficial decrease in cathode overpotential prevails over the higher release of volatile chromium species, faster metallic interconnect corrosion and higher thermodynamic risks of zirconate formation, for maximum SRU temperature below 1150 K. The counter-flow configuration, combined with the beneficial effect of internal reforming on lowering the parasitic air blower consumption, similarly yields longer lifetime than co-flow. © 2012 Elsevier B.V.

Solid oxide fuel cell (SOFC) stack design must yield the highest performance, reliability and durability to achieve the lowest cost of electricity delivered to end-users. Existing modelling tools can cope with the first aim, but cannot yet provide sufficient quantitative guidance in the two others. Repeating unit models, with as degradation processes the decrease in ionic conductivity of the electrolyte, metallic interconnect corrosion, anode nickel particles coarsening and cathode chromium contamination are used to investigate their distribution, evolution and interactions in a stack. The spatial distribution of the degradation is studied for the operating conditions optimised in Part I for the highest system electrical efficiency during long-term operation under constant system power output. Current-voltage characterisations performed at different times underestimate the degradation. In the present conditions, the degradation of the cathode dominates. The lower and more uniform cathode overpotential in counter-flow configuration, combined with the beneficial effect of internal reforming on reducing the air-fuel ratio yields the highest lifetime, because it alleviates chromium contamination and interactions between the degradation processes. Increasing the operating temperature alleviates cathode chromium contamination. The beneficial decreases of the cathode overpotential exceed the detrimental higher release rate of chromium species from the metallic interconnect. © 2012 Elsevier B.V.

This work presents the development of a dynamic SOFC-GT hybrid system model applied to a long-haul freight locomotive in operation. Given the expectations of the rail industry, the model is used to develop a preliminary analysis of the proposed system's operational capability on conventional diesel fuel as well as natural gas and hydrogen as potential fuels in the future. It is found that operation of the system on all three of these fuels is feasible with favorable efficiencies and reasonable dynamic response. The use of diesel fuel reformate in the SOFC presents a challenge to the electrochemistry, especially as it relates to control and optimization of the fuel utilization in the anode compartment. This is found to arise from the large amount of carbon monoxide in diesel reformate that is fed to the fuel cell, limiting the maximum fuel utilization possible. This presents an opportunity for further investigations into carbon monoxide electrochemical oxidation and/or system integration studies where the efficiency of the fuel reformer can be balanced against the needs of the SOFC. © 2012 Elsevier B.V. All rights reserved.

Hybrid fuel cell gas turbine sensitivity to ambient perturbations is analyzed using experimental and dynamic simulation results. Experimental data gathered from the world's first pressurized hybrid SOFC-GT system tested at the University of California, Irvine, capture performance variations due to diurnal temperature oscillations. A dynamic modeling methodology demonstrates accuracy, robustness, and clearly identifies critical system sensitivities that require additional control systems development. Simulation results compare favorably with dynamic experimental responses. Predictions of component temperatures, pressures, voltage and system power exhibited 5 °C, 2 kPa, 2 mV, and 0.5% error respectively. Moderate ambient temperature fluctuations, 15 °C, caused variations in stack temperature of 30 °C, and system power of 5 kW. Small to moderate changes in fuel composition produced 30 °C shifts in stack temperature and 25% changes in system power. Simple control loops manipulating fuel cell air flow through SOFC bypass and inlet temperature through recuperator bypass are shown to effectively mitigate internal temperature transients at the expense of reduced system output. The observed temperature fluctuations resulting from typical environmental perturbations are of concern for performance loss and diminished longevity. Experiments and dynamic simulation results indicate the importance of integrated control systems development for hybrid fuel cell gas turbine systems. © 2012 Elsevier B.V. All rights reserved.

Integrated gasification fuel cell (IGFC) systems that combine coal gasification and solid oxide fuel cells (SOFC) are promising for highly efficient and environmentally sensitive utilization of coal for power production. Most IGFC system analysis efforts performed to-date have employed non-dimensional SOFC models, which predict SOFC performance based upon global mass and energy balances that do not resolve important intrinsic constraints of SOFC operation, such as the limits of internal temperatures and species concentrations. In this work, a detailed dimensional planar SOFC model is applied in IGFC system analysis to investigate these constraints and their implications and effects on the system performance. The analysis results further confirm the need for employing a dimensional SOFC model in IGFC system design. To maintain the SOFC internal temperature within a safe operating range, the required cooling air flow rate is much larger than that predicted by the non-dimensional SOFC model, which results in a larger air compressor design and operating power that significantly reduces the system efficiency. Options to mitigate the challenges introduced by considering the intrinsic constraints of SOFC operation in the analyses and improve IGFC design and operation have also been investigated. Novel design concepts that include staged SOFC stacks and cascading air flow can achieve a system efficiency that is close to that of the baseline analyses, which did not consider the intrinsic SOFC limitations. © 2011 Elsevier B.V. All rights reserved.

Integrated gasification fuel cell (IGFC) systems that combine coal gasification and solid oxide fuel cells (SOFC) are promising for highly efficient and environmentally sensitive utilization of coal for power production. Most IGFC system analysis efforts performed to-date have employed non-dimensional SOFC models, which predict SOFC performance based upon global mass and energy balances that do not resolve important intrinsic constraints of SOFC operation, such as the limits of internal temperatures and species concentrations. In this work, a detailed dimensional planar SOFC model is applied in IGFC system analysis to investigate these constraints and their implications and effects on the system performance. The analysis results further confirm the need for employing a dimensional SOFC model in IGFC system design. To maintain the SOFC internal temperature within a safe operating range, the required cooling air flow rate is much larger than that predicted by the non-dimensional SOFC model, which results in a larger air compressor design and operating power that significantly reduces the system efficiency. Options to mitigate the challenges introduced by considering the intrinsic constraints of SOFC operation in the analyses and improve IGFC design and operation have also been investigated. Novel design concepts that include staged SOFC stacks and cascading air flow can achieve a system efficiency that is close to that of the baseline analyses, which did not consider the intrinsic SOFC limitations. © 2011 Elsevier B.V. All rights reserved.

High temperature fuel cells can be designed and operated to poly-generate electricity, heat, and useful chemicals (e.g., hydrogen) in a variety of configurations. The highly integrated and synergistic nature of poly-generating high temperature fuel cells, however, precludes a simple definition of efficiency for analysis and comparison of performance to traditional methods. There is a need to develop and define a methodology to calculate each of the co-product efficiencies that is useful for comparative analyses. Methodologies for calculating poly-generation efficiencies are defined and discussed. The methodologies are applied to analysis of a Hydrogen Energy Station (H 2ES) showing that high conversion efficiency can be achieved for poly-generation of electricity and hydrogen. © 2010 Elsevier B.V.

High temperature fuel cells can be designed and operated to poly-generate electricity, heat, and useful chemicals (e.g., hydrogen) in a variety of configurations. The highly integrated and synergistic nature of poly-generating high temperature fuel cells, however, precludes a simple definition of efficiency for analysis and comparison of performance to traditional methods. There is a need to develop and define a methodology to calculate each of the co-product efficiencies that is useful for comparative analyses. Methodologies for calculating poly-generation efficiencies are defined and discussed. The methodologies are applied to analysis of a Hydrogen Energy Station (H 2ES) showing that high conversion efficiency can be achieved for poly-generation of electricity and hydrogen. © 2010 Elsevier B.V.

A Monte Carlo percolation model previously used to characterize Triple Phase Boundary (TPB) formation in composite SOFC electrode-electrolyte interfaces has been augmented to allow for investigation of the effects of composition, gas-phase percolation, and surface exchange and transport phenomena on the overall conductivity of these electrode-electrolyte interfaces. The model has been utilized to replicate the results of a previous modeling effort, with similar assumptions and application to an SOFC electrode electrolyte interface. Although the models are similar in many aspects, their key differences allow equivalent predictions of the behavior of overall electrode conductivity as a function of electrode composition, thereby verifying the assumptions and overall approach of the current model. The validity of omitting charge-transfer and activation resistances when comparing overall interfacial conductivity trends is confirmed. The current model is then used to simulate several experimental results. The comparisons among these results show the importance of including gas-phase percolation physics and surface exchange and transport phenomena features in the model. Including gas-phase percolation and these surface phenomena can significantly alter the predictions of conductivity behavior and better predicts experimental observations, particularly at low and high electronic conductor volume fractions. © 2010 Elsevier B.V.

A Monte Carlo percolation model previously used to characterize Triple Phase Boundary (TPB) formation in composite SOFC electrode-electrolyte interfaces has been augmented to allow for investigation of the effects of composition, gas-phase percolation, and surface exchange and transport phenomena on the overall conductivity of these electrode-electrolyte interfaces. The model has been utilized to replicate the results of a previous modeling effort, with similar assumptions and application to an SOFC electrode electrolyte interface. Although the models are similar in many aspects, their key differences allow equivalent predictions of the behavior of overall electrode conductivity as a function of electrode composition, thereby verifying the assumptions and overall approach of the current model. The validity of omitting charge-transfer and activation resistances when comparing overall interfacial conductivity trends is confirmed. The current model is then used to simulate several experimental results. The comparisons among these results show the importance of including gas-phase percolation physics and surface exchange and transport phenomena features in the model. Including gas-phase percolation and these surface phenomena can significantly alter the predictions of conductivity behavior and better predicts experimental observations, particularly at low and high electronic conductor volume fractions. © 2010 Elsevier B.V.

Integrated gasification fuel cell (IGFC) technology combining coal gasification and solid oxide fuel cell (SOFC) is believed to be the only viable solution to achieving U.S. Department of Energy (DOE)'s performance goal for next generation coal-based power plants, producing electricity at 60% efficiency (coal HHV-AC) while capturing more than 90% of the evolved CO2. Achieving this goal is challenging even with high performance SOFCs; design concepts published to date have not demonstrated this performance goal. In this work an IGFC system concept consisting of catalytic hydro-gasification, proven low-temperature gas cleaning and hybrid fuel cell-gas turbine power block (with SOFC operating at about 10 bar) is introduced. The system is demonstrating an electricity efficiency greater than 60% (coal HHV basis), with more than 90% of the carbon present in the syngas separated as CO2 amenable to sequestration. A unique characteristic of the system is recycling de-carbonized, humidified anode exhaust back to the catalytic hydro-gasifier for improved energy integration. Alternative designs where: (1) anode exhaust is recycled directly back to SOFC stacks, (2) SOFC stack operating pressure is reduced to near atmospheric and (3) methanation reactor in the reactor/expander topping cycle is removed, have also been investigated and the system design and performance differences are discussed. © 2010 Elsevier B.V.

Integrated gasification fuel cell (IGFC) technology combining coal gasification and solid oxide fuel cell (SOFC) is believed to be the only viable solution to achieving U.S. Department of Energy (DOE)'s performance goal for next generation coal-based power plants, producing electricity at 60% efficiency (coal HHV-AC) while capturing more than 90% of the evolved CO2. Achieving this goal is challenging even with high performance SOFCs; design concepts published to date have not demonstrated this performance goal. In this work an IGFC system concept consisting of catalytic hydro-gasification, proven low-temperature gas cleaning and hybrid fuel cell-gas turbine power block (with SOFC operating at about 10 bar) is introduced. The system is demonstrating an electricity efficiency greater than 60% (coal HHV basis), with more than 90% of the carbon present in the syngas separated as CO2 amenable to sequestration. A unique characteristic of the system is recycling de-carbonized, humidified anode exhaust back to the catalytic hydro-gasifier for improved energy integration. Alternative designs where: (1) anode exhaust is recycled directly back to SOFC stacks, (2) SOFC stack operating pressure is reduced to near atmospheric and (3) methanation reactor in the reactor/expander topping cycle is removed, have also been investigated and the system design and performance differences are discussed. © 2010 Elsevier B.V.

A recent publication by Adams and Barton [1] in the Journal of Power Sources has appropriately espoused and analyzed the high efficiency and carbon separation capabilities of solid oxide fuel cells. Unfortunately, the paper also contains misleading statements and analyses regarding the internal reforming capabilities of solid oxide fuel cells. The current letter to the editor addresses this concern and provides insights into appropriate systems design for solid oxide fuel cells that considers their proven internal reforming capabilities. © 2010 Elsevier B.V. All rights reserved.

A recent publication by Adams and Barton [1] in the Journal of Power Sources has appropriately espoused and analyzed the high efficiency and carbon separation capabilities of solid oxide fuel cells. Unfortunately, the paper also contains misleading statements and analyses regarding the internal reforming capabilities of solid oxide fuel cells. The current letter to the editor addresses this concern and provides insights into appropriate systems design for solid oxide fuel cells that considers their proven internal reforming capabilities. © 2010 Elsevier B.V. All rights reserved.

Operating strategies of solid oxide fuel cell (SOFC) combined heat and power (CHP) systems are developed and evaluated from a utility, and end-user perspective using a fully integrated SOFC-CHP system dynamic model that resolves the physical states, thermal integration and overall efficiency of the system. The model can be modified for any SOFC-CHP system, but the present analysis is applied to a hotel in southern California based on measured electric and heating loads. Analysis indicates that combined heat and power systems can be operated to benefit both the end-users and the utility, providing more efficient electric generation as well as grid ancillary services, namely dispatchable urban power. Design and operating strategies considered in the paper include optimal sizing of the fuel cell, thermal energy storage to dispatch heat, and operating the fuel cell to provide flexible grid power. Analysis results indicate that with a 13.1% average increase in price-of-electricity (POE), the system can provide the grid with a 50% operating range of dispatchable urban power at an overall thermal efficiency of 80%. This grid-support operating mode increases the operational flexibility of the SOFC-CHP system, which may make the technology an important utility asset for accommodating the increased penetration of intermittent renewable power. © 2009 Elsevier B.V. All rights reserved.

Operating strategies of solid oxide fuel cell (SOFC) combined heat and power (CHP) systems are developed and evaluated from a utility, and end-user perspective using a fully integrated SOFC-CHP system dynamic model that resolves the physical states, thermal integration and overall efficiency of the system. The model can be modified for any SOFC-CHP system, but the present analysis is applied to a hotel in southern California based on measured electric and heating loads. Analysis indicates that combined heat and power systems can be operated to benefit both the end-users and the utility, providing more efficient electric generation as well as grid ancillary services, namely dispatchable urban power. Design and operating strategies considered in the paper include optimal sizing of the fuel cell, thermal energy storage to dispatch heat, and operating the fuel cell to provide flexible grid power. Analysis results indicate that with a 13.1% average increase in price-of-electricity (POE), the system can provide the grid with a 50% operating range of dispatchable urban power at an overall thermal efficiency of 80%. This grid-support operating mode increases the operational flexibility of the SOFC-CHP system, which may make the technology an important utility asset for accommodating the increased penetration of intermittent renewable power. © 2009 Elsevier B.V. All rights reserved.

While the integration of base-load fuel cells into the built environment is expected to provide numerous benefits to the user, the steady-state and dynamic behavior of these stationary fuel cell systems can produce an undesirable impact on the grid distribution circuit at the point of connection. In the present paper, a load-following active power filter (LFAPF) is proposed to mitigate the grid impact of such systems and instead improve overall local power quality. To evaluate the strategy, the LFAPF is integrated into a SOFC system inverter with one-cycle control (OCC) to provide the fundamental benefits of a traditional active power filter (APF) while also damping out short-term line current transients. The LFAPF benefit is illustrated through simulation of an SOFC interconnected with the utility electric distribution system and a building electricity demand that is modeled as a dynamic non-linear load. Three installation cases are examined: (1) a load-following SOFC, (2) a base-loaded SOFC, and (3) an offline SOFC. Without LFAPF, the load-following SOFC causes load transients due to the finite SOFC response time, and the base-loaded SOFC case has transients that appear more severe because they represent a larger overall percentage of the grid-provided load. The integration of an LFAPF improves the steady-state behavior over the base case and mitigates voltage sags and step changes. Thus integrating an LFAPF can, by providing useful services to both the utility and the end-user, facilitate the integration of an SOFC into the distribution system. © 2009 Elsevier B.V. All rights reserved.

While the integration of base-load fuel cells into the built environment is expected to provide numerous benefits to the user, the steady-state and dynamic behavior of these stationary fuel cell systems can produce an undesirable impact on the grid distribution circuit at the point of connection. In the present paper, a load-following active power filter (LFAPF) is proposed to mitigate the grid impact of such systems and instead improve overall local power quality. To evaluate the strategy, the LFAPF is integrated into a SOFC system inverter with one-cycle control (OCC) to provide the fundamental benefits of a traditional active power filter (APF) while also damping out short-term line current transients. The LFAPF benefit is illustrated through simulation of an SOFC interconnected with the utility electric distribution system and a building electricity demand that is modeled as a dynamic non-linear load. Three installation cases are examined: (1) a load-following SOFC, (2) a base-loaded SOFC, and (3) an offline SOFC. Without LFAPF, the load-following SOFC causes load transients due to the finite SOFC response time, and the base-loaded SOFC case has transients that appear more severe because they represent a larger overall percentage of the grid-provided load. The integration of an LFAPF improves the steady-state behavior over the base case and mitigates voltage sags and step changes. Thus integrating an LFAPF can, by providing useful services to both the utility and the end-user, facilitate the integration of an SOFC into the distribution system. © 2009 Elsevier B.V. All rights reserved.

The intrinsic transient performance capability and limitation of integrated solid oxide fuel cell (SOFC) systems is evaluated based on the system balance-of-plant response and fuel cell operating requirements (i.e., allowable deviation from nominal operation). Specifically, non-dimensional relations are derived from conservation principles that quantify the maximum instantaneous current increase that a solid oxide fuel cell system can safely manage based on (1) the desired fuel cell operating point, (2) the maximum allowable fuel utilization, (3) the maximum average fuel cell temperature deviation, (4) the response delay and (5) the operating requirements of the system balance-of-plant components. New non-dimensional numbers representing the ratio of species or thermal convection to volumetric capacitance in the fuel cell during balance-of-plant delay have been developed. The analyses indicate: (1) SOFC intrinsic transient performance is largely limited by fuel processor flow delays that can cause fuel depletion in the anode compartment and (2) that with proper system actuators and control design transient operation of SOFC systems should be possible while maintaining SOFC average temperature within a degree. The SOFC system fuel processor lag appears to be the cause of SOFC load following limitation, while lag in air handling appears to be manageable. To demonstrate methods to avoid fuel depletion limitation a fuel flow lead compensator is developed. Integrated system simulations with proper control demonstrate significant SOFC transient performance within fuel cell operating requirements. © 2008 Elsevier B.V. All rights reserved.

The intrinsic transient performance capability and limitation of integrated solid oxide fuel cell (SOFC) systems is evaluated based on the system balance-of-plant response and fuel cell operating requirements (i.e., allowable deviation from nominal operation). Specifically, non-dimensional relations are derived from conservation principles that quantify the maximum instantaneous current increase that a solid oxide fuel cell system can safely manage based on (1) the desired fuel cell operating point, (2) the maximum allowable fuel utilization, (3) the maximum average fuel cell temperature deviation, (4) the response delay and (5) the operating requirements of the system balance-of-plant components. New non-dimensional numbers representing the ratio of species or thermal convection to volumetric capacitance in the fuel cell during balance-of-plant delay have been developed. The analyses indicate: (1) SOFC intrinsic transient performance is largely limited by fuel processor flow delays that can cause fuel depletion in the anode compartment and (2) that with proper system actuators and control design transient operation of SOFC systems should be possible while maintaining SOFC average temperature within a degree. The SOFC system fuel processor lag appears to be the cause of SOFC load following limitation, while lag in air handling appears to be manageable. To demonstrate methods to avoid fuel depletion limitation a fuel flow lead compensator is developed. Integrated system simulations with proper control demonstrate significant SOFC transient performance within fuel cell operating requirements. © 2008 Elsevier B.V. All rights reserved.

A dynamic model of a discrete reversible fuel cell (RFC) system has been developed in a Matlab Simulink® environment. The model incorporates first principles dynamic component models of a proton exchange membrane (PEM) fuel cell, a PEM electrolyzer, a metal hydride hydrogen storage tank, and a cooling system radiator, as well as empirical models of balance of plant components. Dynamic simulations show unique charging and discharging control issues and highlight factors contributing to overall system efficiency. © 2008 Elsevier B.V. All rights reserved.

Several methods to prevent fuel starvation in solid oxide fuel cells are developed and investigated. Fuel starvation can occur during transients, if fuel is consumed in the fuel cell faster than it can be supplied by the fuel processing and delivery system. It is demonstrated through simulation that fuel depletion can occur in the fuel cell if no corrective action is employed. Fuel starvation can be prevented by the use of rate limiters, reference governors, and modifications to the fuel-flow controller. The various methods to prevent fuel depletion within the fuel cell are developed and compared. Analysis indicates that reference governors can avoid hydrogen depletion with much less of an impact on transient load following capability than rate limiters. Hence, various reference governors ranging in level of fidelity were developed and compared for performance. It was further demonstrated that with knowledge of the fuel preprocessor response, it is possible to manipulate the fuel flow to minimize reformer flow dynamics, minimizing the need to govern the fuel cell transient capability. © 2008 Elsevier B.V. All rights reserved.

Several methods to prevent fuel starvation in solid oxide fuel cells are developed and investigated. Fuel starvation can occur during transients, if fuel is consumed in the fuel cell faster than it can be supplied by the fuel processing and delivery system. It is demonstrated through simulation that fuel depletion can occur in the fuel cell if no corrective action is employed. Fuel starvation can be prevented by the use of rate limiters, reference governors, and modifications to the fuel-flow controller. The various methods to prevent fuel depletion within the fuel cell are developed and compared. Analysis indicates that reference governors can avoid hydrogen depletion with much less of an impact on transient load following capability than rate limiters. Hence, various reference governors ranging in level of fidelity were developed and compared for performance. It was further demonstrated that with knowledge of the fuel preprocessor response, it is possible to manipulate the fuel flow to minimize reformer flow dynamics, minimizing the need to govern the fuel cell transient capability. © 2008 Elsevier B.V. All rights reserved.

Adding distributed generation (DG) is a desirable strategy for providing highly efficient and environmentally benign services for electric power, heating, and cooling. The interface between a solid oxide fuel cell (SOFC), typical loads, and the electrical grid is simulated in Matlab/Simulink and analyzed to assess the interactions between DG and the electrical grid. A commercial building load profile is measured during both steady-state and transient conditions. The load data are combined with the following models that are designed to account for physical features: a One-Cycle Control grid-connected inverter, a One-Cycle Control active power filter, an SOFC, and capacitor storage. High penetration of DG without any power filter increases the percentage of undesirable harmonics provided by the grid, but combined use of an inverter and active power filter allows the DG system interconnection to improve the grid tie-line flow by lowering total harmonic distortion and increasing the power factor to unity. © 2008 Elsevier B.V. All rights reserved.

Adding distributed generation (DG) is a desirable strategy for providing highly efficient and environmentally benign services for electric power, heating, and cooling. The interface between a solid oxide fuel cell (SOFC), typical loads, and the electrical grid is simulated in Matlab/Simulink and analyzed to assess the interactions between DG and the electrical grid. A commercial building load profile is measured during both steady-state and transient conditions. The load data are combined with the following models that are designed to account for physical features: a One-Cycle Control grid-connected inverter, a One-Cycle Control active power filter, an SOFC, and capacitor storage. High penetration of DG without any power filter increases the percentage of undesirable harmonics provided by the grid, but combined use of an inverter and active power filter allows the DG system interconnection to improve the grid tie-line flow by lowering total harmonic distortion and increasing the power factor to unity. © 2008 Elsevier B.V. All rights reserved.

A theoretical solid oxide fuel cell-gas turbine hybrid system has been designed using a Capstone 60 kW micro-gas turbine. Through simulation it is demonstrated that the hybrid system can be controlled to achieve transient capability greater than the Capstone 60 kW recuperated gas turbine alone. The Capstone 60 kW gas turbine transient capability is limited because in order to maintain combustor, turbine and heat exchangers temperatures within operating requirements, the Capstone combustor fuel-to-air ratio must be maintained. Potentially fast fuel flow rate changes, must be limited to the slower, inertia limited, turbo machinery air response. This limits a 60 kW recuperated gas turbine to transient response rates of approximately 1 kW s-1. However, in the SOFC/GT hybrid system, the combustor temperature can be controlled, by manipulating the fuel cell current, to regulate the amount of fuel sent to the combustor. By using such control pairing, the fuel flow rate does not have to be constrained by the air flow in SOFC/GT hybrid systems. This makes it possible to use the rotational inertia of the gas turbine, to buffer the fuel cell power response, during fuel cell fuel flow transients that otherwise limit fuel cell system transient capability. Such synergistic integration improves the transient response capability of the integrated SOFC gas turbine hybrid system. Through simulation it has been demonstrated that SOFC/GT hybrid system can be developed to have excellent transient capability. © 2007 Elsevier B.V. All rights reserved.

A theoretical solid oxide fuel cell-gas turbine hybrid system has been designed using a Capstone 60 kW micro-gas turbine. Through simulation it is demonstrated that the hybrid system can be controlled to achieve transient capability greater than the Capstone 60 kW recuperated gas turbine alone. The Capstone 60 kW gas turbine transient capability is limited because in order to maintain combustor, turbine and heat exchangers temperatures within operating requirements, the Capstone combustor fuel-to-air ratio must be maintained. Potentially fast fuel flow rate changes, must be limited to the slower, inertia limited, turbo machinery air response. This limits a 60 kW recuperated gas turbine to transient response rates of approximately 1 kW s-1. However, in the SOFC/GT hybrid system, the combustor temperature can be controlled, by manipulating the fuel cell current, to regulate the amount of fuel sent to the combustor. By using such control pairing, the fuel flow rate does not have to be constrained by the air flow in SOFC/GT hybrid systems. This makes it possible to use the rotational inertia of the gas turbine, to buffer the fuel cell power response, during fuel cell fuel flow transients that otherwise limit fuel cell system transient capability. Such synergistic integration improves the transient response capability of the integrated SOFC gas turbine hybrid system. Through simulation it has been demonstrated that SOFC/GT hybrid system can be developed to have excellent transient capability. © 2007 Elsevier B.V. All rights reserved.

A novel SOFC system control strategy has been developed for rapid load following. The strategy was motivated from the performance of a baseline control strategy developed from control concepts in the literature. The basis for the fuel cell system control concepts are explained by a simplified order of magnitude time scale analysis. The control concepts are then investigated in a detailed quasi-two-dimensional integrated dynamic system model that resolves the physics of heat transfer, chemical kinetics, mass convection and electrochemistry within the system. The baseline control strategy is based on the standard operating method of constant utilization with no control of the combustor temperature. Simulation indicates that with this control strategy large combustor transients can take place during load transients because the fuel flow to the combustor increases faster than the air flow. To alleviate this problem, a novel control structure that maintains the combustor temperature within acceptable ranges without any supplementary hardware was introduced. The combustor temperature is controlled by manipulating the current to change the combustor inlet stoichiometry. The load following capability of SOFC systems is inherently limited by anode compartment fuel depletion during the time of fuel delivery delay. This research indicates that future SOFC systems with proper system and control configurations can exhibit excellent load following characteristics. © 2007 Elsevier B.V. All rights reserved.

A novel SOFC system control strategy has been developed for rapid load following. The strategy was motivated from the performance of a baseline control strategy developed from control concepts in the literature. The basis for the fuel cell system control concepts are explained by a simplified order of magnitude time scale analysis. The control concepts are then investigated in a detailed quasi-two-dimensional integrated dynamic system model that resolves the physics of heat transfer, chemical kinetics, mass convection and electrochemistry within the system. The baseline control strategy is based on the standard operating method of constant utilization with no control of the combustor temperature. Simulation indicates that with this control strategy large combustor transients can take place during load transients because the fuel flow to the combustor increases faster than the air flow. To alleviate this problem, a novel control structure that maintains the combustor temperature within acceptable ranges without any supplementary hardware was introduced. The combustor temperature is controlled by manipulating the current to change the combustor inlet stoichiometry. The load following capability of SOFC systems is inherently limited by anode compartment fuel depletion during the time of fuel delivery delay. This research indicates that future SOFC systems with proper system and control configurations can exhibit excellent load following characteristics. © 2007 Elsevier B.V. All rights reserved.

A model of a photovoltaic (PV) powered residence in stand-alone configuration was developed and evaluated. The model assesses the sizing, capital costs, control strategies, and efficiencies of reversible fuel cells (RFC), batteries, and ultra-capacitors (UC) both individually, and in combination, as hybrid energy storage devices. The choice of control strategy for a hybrid energy storage system is found to have a significant impact on system efficiency, hydrogen production and component utilization. A hybrid energy storage system comprised of batteries and RFC has the advantage of reduced cost (compared to using a RFC as the sole energy storage device), high system efficiency and hydrogen energy production capacity. A control strategy that preferentially used the RFC before the battery in meeting load demand allows both grid independent operation and better RFC utilization compared to a system that preferentially used the battery before the RFC. Ultra-capacitors coupled with a RFC in a hybrid energy storage system contain insufficient energy density to meet dynamic power demands typical of residential applications. © 2006 Elsevier B.V. All rights reserved.

A first principles dynamic model of the physical, chemical, and electrochemical processes at work in a proton exchange membrane fuel cell has been developed. The model solves the dynamic equations that govern the physics, chemistry and electrochemistry for time scales greater than about 10 ms. The dynamic equations are solved for a typical but simplified quasi-three dimensional geometric representation of a single cell repeat unit of a fuel cell stack. The current approach captures spatial and temporal variations in the important physics of heat transfer and water transport in a manner that is simple enough to make the model amenable to PEMFC system simulations and controls development. Comparisons of model results to experimental data indicate that the model can well predict steady state voltage-current relationships as well as the oxygen, water, and nitrogen spatial distribution within the fuel cell. In addition, the model gives dynamic insight into the distribution of current, water flux, species mole fractions, and temperatures within the fuel cell. Finally, a control system test is demonstrated using the simplified dynamic model. © 2006 Elsevier B.V. All rights reserved.

A model of a photovoltaic (PV) powered residence in stand-alone configuration was developed and evaluated. The model assesses the sizing, capital costs, control strategies, and efficiencies of reversible fuel cells (RFC), batteries, and ultra-capacitors (UC) both individually, and in combination, as hybrid energy storage devices. The choice of control strategy for a hybrid energy storage system is found to have a significant impact on system efficiency, hydrogen production and component utilization. A hybrid energy storage system comprised of batteries and RFC has the advantage of reduced cost (compared to using a RFC as the sole energy storage device), high system efficiency and hydrogen energy production capacity. A control strategy that preferentially used the RFC before the battery in meeting load demand allows both grid independent operation and better RFC utilization compared to a system that preferentially used the battery before the RFC. Ultra-capacitors coupled with a RFC in a hybrid energy storage system contain insufficient energy density to meet dynamic power demands typical of residential applications. © 2006 Elsevier B.V. All rights reserved.

A first principles dynamic model of the physical, chemical, and electrochemical processes at work in a proton exchange membrane fuel cell has been developed. The model solves the dynamic equations that govern the physics, chemistry and electrochemistry for time scales greater than about 10 ms. The dynamic equations are solved for a typical but simplified quasi-three dimensional geometric representation of a single cell repeat unit of a fuel cell stack. The current approach captures spatial and temporal variations in the important physics of heat transfer and water transport in a manner that is simple enough to make the model amenable to PEMFC system simulations and controls development. Comparisons of model results to experimental data indicate that the model can well predict steady state voltage-current relationships as well as the oxygen, water, and nitrogen spatial distribution within the fuel cell. In addition, the model gives dynamic insight into the distribution of current, water flux, species mole fractions, and temperatures within the fuel cell. Finally, a control system test is demonstrated using the simplified dynamic model. © 2006 Elsevier B.V. All rights reserved.

This study is focused on a hybrid fuel cell/gas turbine (FC/GT) system with an atmospheric pressure solid oxide fuel cell (SOFC). The impact of the gas turbine rotational speed on dynamic performance and controllability of a hybrid system is investigated. The transient response of the FC/GT system to perturbations in the power demand has been investigated. Two operational strategies of gas turbines are compared: (1) fixed speed operation, and (2) variable speed operation. For both operation strategies, a wide range of power production is numerically simulated. The results show that variable speed operation is superior for the FC/GT hybrid configuration studied. Variable speed operation allows a 50% turn down in power with no additional balance of plant equipment required. The system efficiency is maintained above 66% for variable speed operation compared to 53% for fixed speed operation with auxiliary combustion. © 2006 Elsevier B.V. All rights reserved.

This study is focused on a hybrid fuel cell/gas turbine (FC/GT) system with an atmospheric pressure solid oxide fuel cell (SOFC). The impact of the gas turbine rotational speed on dynamic performance and controllability of a hybrid system is investigated. The transient response of the FC/GT system to perturbations in the power demand has been investigated. Two operational strategies of gas turbines are compared: (1) fixed speed operation, and (2) variable speed operation. For both operation strategies, a wide range of power production is numerically simulated. The results show that variable speed operation is superior for the FC/GT hybrid configuration studied. Variable speed operation allows a 50% turn down in power with no additional balance of plant equipment required. The system efficiency is maintained above 66% for variable speed operation compared to 53% for fixed speed operation with auxiliary combustion. © 2006 Elsevier B.V. All rights reserved.

This paper addresses how the power and temperature are controlled in a biomass gas fueled solid oxide fuel cell (SOFC) and micro gas turbine (MGT) hybrid system. A SOFC and MGT dynamic model are developed and used to simulate the hybrid system performance operating on biomass gas. The transient behavior of both the SOFC and MGT are discussed in detail. An unstable power output is observed when the system is fed biomass gas. This instability is due to the fluctuation of gas composition in the fuel. A specially designed fuel controller succeeded not only in allowing the hybrid system to follow a step change of power demand from 32 to 35 kW, but also stably maintained the system power output at 35 kW. In addition to power control, fuel cell temperature is controlled by introduction and use of a bypass valve around the recuperator. By releasing excess heat to the exhaust, the bypass valve provided the control means to avoid the self-exciting behavior of system temperature and stabilized the temperature of SOFC at 850 °C. © 2006 Elsevier B.V. All rights reserved.

This paper addresses how the power and temperature are controlled in a biomass gas fueled solid oxide fuel cell (SOFC) and micro gas turbine (MGT) hybrid system. A SOFC and MGT dynamic model are developed and used to simulate the hybrid system performance operating on biomass gas. The transient behavior of both the SOFC and MGT are discussed in detail. An unstable power output is observed when the system is fed biomass gas. This instability is due to the fluctuation of gas composition in the fuel. A specially designed fuel controller succeeded not only in allowing the hybrid system to follow a step change of power demand from 32 to 35 kW, but also stably maintained the system power output at 35 kW. In addition to power control, fuel cell temperature is controlled by introduction and use of a bypass valve around the recuperator. By releasing excess heat to the exhaust, the bypass valve provided the control means to avoid the self-exciting behavior of system temperature and stabilized the temperature of SOFC at 850 °C. © 2006 Elsevier B.V. All rights reserved.

A detailed dynamic model incorporating geometric resolution of a molten carbonate fuel cell (MCFC) with dynamic simulation of physical and electrochemical processes in the stream-wise direction is presented. The model was developed using mass and momentum conservation, electrochemical and chemical reaction mechanisms, and heat-transfer. Results from the model are compared with data from an experimental MCFC unit. Furthermore, the model was applied to predict dynamic variations of voltage, current and temperature in an MCFC as it responds to varying load demands. The voltage was evaluated using two different approaches: one applying a model developed by Yuh and Selman [C.Y. Yuh, J.R. Selman, The polarization of molten carbonate fuel cell electrodes: I. Analysis of steady-state polarization data, J. Electrochem. Soc. 138 (1991) 3642-3648; C.Y. Yuh, J.R. Selman, The polarization of molten carbonate fuel cell electrodes: II. Characterization by AC impedance and response to current interruption, J. Electrochem. Soc. 138 (1991) 3649-3655] and another applying simplified equations using average local temperatures and pressures. The results show that both models can be used to predict voltage and dynamic response characteristics of an MCFC and the model that uses the more detailed Yuh and Selman approach can predict those accurately and consistently for a variety of operating conditions. © 2005 Elsevier B.V. All rights reserved.

A detailed dynamic model incorporating geometric resolution of a molten carbonate fuel cell (MCFC) with dynamic simulation of physical and electrochemical processes in the stream-wise direction is presented. The model was developed using mass and momentum conservation, electrochemical and chemical reaction mechanisms, and heat-transfer. Results from the model are compared with data from an experimental MCFC unit. Furthermore, the model was applied to predict dynamic variations of voltage, current and temperature in an MCFC as it responds to varying load demands. The voltage was evaluated using two different approaches: one applying a model developed by Yuh and Selman [C.Y. Yuh, J.R. Selman, The polarization of molten carbonate fuel cell electrodes: I. Analysis of steady-state polarization data, J. Electrochem. Soc. 138 (1991) 3642-3648; C.Y. Yuh, J.R. Selman, The polarization of molten carbonate fuel cell electrodes: II. Characterization by AC impedance and response to current interruption, J. Electrochem. Soc. 138 (1991) 3649-3655] and another applying simplified equations using average local temperatures and pressures. The results show that both models can be used to predict voltage and dynamic response characteristics of an MCFC and the model that uses the more detailed Yuh and Selman approach can predict those accurately and consistently for a variety of operating conditions. © 2005 Elsevier B.V. All rights reserved.

Current high temperature fuel cell (HTFC) systems used for stationary power applications (in the 200-300 kW size range) have very limited dynamic load following capability or are simply base load devices. Considering the economics of existing electric utility rate structures, there is little incentive to increase HTFC ramping capability beyond 1 kWs-1 (0.4% s-1). However, in order to ease concerns about grid instabilities from utility companies and increase market adoption, HTFC systems will have to increase their ramping abilities, and will likely have to incorporate electrical energy storage (EES). Because batteries have low power densities and limited lifetimes in highly cyclic applications, ultra capacitors may be the EES medium of choice. The current analyses show that, because ultra capacitors have a very low energy storage density, their integration with HTFC systems may not be feasible unless the fuel cell has a ramp rate approaching 10 kWs-1 (4% s-1) when using a worst-case design analysis. This requirement for fast dynamic load response characteristics can be reduced to 1 kWs-1 by utilizing high resolution demand data to properly size ultra capacitor systems and through demand management techniques that reduce load volatility. © 2005 Elsevier B.V. All rights reserved.

Current high temperature fuel cell (HTFC) systems used for stationary power applications (in the 200-300 kW size range) have very limited dynamic load following capability or are simply base load devices. Considering the economics of existing electric utility rate structures, there is little incentive to increase HTFC ramping capability beyond 1 kWs-1 (0.4% s-1). However, in order to ease concerns about grid instabilities from utility companies and increase market adoption, HTFC systems will have to increase their ramping abilities, and will likely have to incorporate electrical energy storage (EES). Because batteries have low power densities and limited lifetimes in highly cyclic applications, ultra capacitors may be the EES medium of choice. The current analyses show that, because ultra capacitors have a very low energy storage density, their integration with HTFC systems may not be feasible unless the fuel cell has a ramp rate approaching 10 kWs-1 (4% s-1) when using a worst-case design analysis. This requirement for fast dynamic load response characteristics can be reduced to 1 kWs-1 by utilizing high resolution demand data to properly size ultra capacitor systems and through demand management techniques that reduce load volatility. © 2005 Elsevier B.V. All rights reserved.

The operation of solid oxide fuel cells on various fuels, such as natural gas, biogas and gases derived from biomass or coal gasification and distillate fuel reforming has been an active area of SOFC research in recent years. In this study, we develop a theoretical understanding and thermodynamic simulation capability for investigation of an integrated SOFC reformer system operating on various fuels. The theoretical understanding and simulation results suggest that significant thermal management challenges may result from the use of different types of fuels in the same integrated fuel cell reformer system. Syngas derived from coal is simulated according to specifications from high-temperature entrained bed coal gasifiers. Diesel syngas is approximated from data obtained in a previous NFCRC study of JP-8 and diesel operation of the integrated 25 kW SOFC reformer system. The syngas streams consist of mixtures of hydrogen, carbon monoxide, carbon dioxide, methane and nitrogen. Although the SOFC can tolerate a wide variety in fuel composition, the current analyses suggest that performance of integrated SOFC reformer systems may require significant operating condition changes and/or system design changes in order to operate well on this variety of fuels. © 2005 Elsevier B.V. All rights reserved.

The operation of solid oxide fuel cells on various fuels, such as natural gas, biogas and gases derived from biomass or coal gasification and distillate fuel reforming has been an active area of SOFC research in recent years. In this study, we develop a theoretical understanding and thermodynamic simulation capability for investigation of an integrated SOFC reformer system operating on various fuels. The theoretical understanding and simulation results suggest that significant thermal management challenges may result from the use of different types of fuels in the same integrated fuel cell reformer system. Syngas derived from coal is simulated according to specifications from high-temperature entrained bed coal gasifiers. Diesel syngas is approximated from data obtained in a previous NFCRC study of JP-8 and diesel operation of the integrated 25 kW SOFC reformer system. The syngas streams consist of mixtures of hydrogen, carbon monoxide, carbon dioxide, methane and nitrogen. Although the SOFC can tolerate a wide variety in fuel composition, the current analyses suggest that performance of integrated SOFC reformer systems may require significant operating condition changes and/or system design changes in order to operate well on this variety of fuels. © 2005 Elsevier B.V. All rights reserved.

The power generation community faces a major challenge: to protect the environment while producing a plentiful supply of clean low-cost energy. "21st Century Energy Plants" (Vision 21 Plants) have been proposed and conceptualized to meet the energy and environmental challenges. The solid oxide fuel cell and intercooled gas turbine (SOFC-ICGT) hybrid cycle introduced in this work is one example of a Vision 21 Plant. The system includes an internal-reforming tubular-SOFC, an intercooled gas turbine, a humidifier, and other auxiliary components. A recently developed thermodynamic analysis computer code entitled advanced power systems analyses tools (APSAT) was applied to analyze the system performance of the SOFC-ICGT cycle. Sensitivity analyses of several major system parameters were studied to identify the key development needs and design and operating improvements for this hybrid cycle. A novel optimization strategy including a design of experiments (DOEx) approach is proposed and applied to the hybrid system. Using this optimization strategy, a system electrical efficiency higher than 75% (net ac/lower heating value (LHV)) could be achieved when the system was designed to operate under a high operating pressure (50bara) and with a low percent excess air (EA) (55%) in the SOFC. © 2003 Elsevier B.V. All rights reserved.