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Start Over Author "N. Indictor" Journal journal of polymer science: polymer chemistry edition
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3. Cleavage of poly(vinyl alcohol) in the presence of tert-butyl hydroperoxide and biologically active metal complexes

Author

T. Jochsberger, N. Indictor, and A. Auerbach

Subjects
Vinyl alcohol, Dimethyl sulfoxide, Chlorophyllin, chemistry.chemical_element, Vanadium, Metal, chemistry.chemical_compound, chemistry, visual_art, Polymer chemistry, Phthalocyanine, visual_art.visual_art_medium, tert-Butyl hydroperoxide, Organic chemistry, Cobalt
Abstract

The cleavage of poly(vinyl alcohol) in dimethyl sulfoxide at 42°C has been measured viscometrically in the presence of tert-butyl hydroperoxide and metal complexes. Phthalocyanine complexes of copper(II), iron(III), cobalt(II), and vanadium as VO(II) as well as hemin, hematin, chlorophyllin, and cytochrome c were used. The rates of decomposition of tert-butyl hydroperoxide in the presence of these metal complexes were measured idometrically. These data are compared to results obtained with other metal complexes in similar reactions.

Published
1976
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