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This report describes how doping liquid crystals (LC) with rod-like hexagonal semiconductor nanoprisms alters the dielectric and elastic properties of the composites as compared with a pristine nematic liquid crystal (NLC). Cadmium sulfide nanorods were synthesized via the solvothermal process and blended with a NLC. Nanorods were highly miscible with NLC and produced a topological defect-free texture up to a certain limit. A good dark state was achieved during the homeotropic configuration of the cell within that limit. Appreciable changes in splay and bend elastic constants of the LCs were observed after blending with nanorods. Long-range order was established in the hybrid system, and consequently the anisotropy was increased. The threshold voltage decreased dramatically by ∼31%. Dielectric study revealed a high-frequency mode, which might be due to anchoring of the LC with nanorods.