1. Second-order Structural Transition in (Ca0.5Sr0.5)3Rh4Sn13
- Author
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Hibiki Kanagawa, Kenichi Yoshimura, Satoshi Tsutsui, Y. Tanioku, Swee K. Goh, F. M. Grosche, T. Matsumoto, Masaki Imai, Peter W. Logg, Yiu Wing Cheung, Koji Kaneko, and Y. J. Hu
- Subjects
Diffraction ,History ,Condensed matter physics ,Scattering ,Chemistry ,Superlattice ,02 engineering and technology ,021001 nanoscience & nanotechnology ,01 natural sciences ,Heat capacity ,Computer Science Applications ,Education ,Reflection (mathematics) ,Electrical resistivity and conductivity ,Quantum critical point ,0103 physical sciences ,010306 general physics ,0210 nano-technology ,Stoichiometry - Abstract
(Ca0.5Sr0.5)3Rh4Sn13 is a member of the substitution series (CaxSr1–x)3Rh4Sn13 which has recently been argued to feature a structural quantum critical point at xc = 0.9. In the stoichiometric compound Sr3Rh4Sn13, the structural transition at T* ≈ 138 K has been shown to be second-order. Moving towards xc, we examine the character of the structural transition in (Ca0.5Sr0.5)3Rh4Sn13 (i.e. x = 0.5, T* ≈ 55 K) using electrical resistivity, heat capacity and X-ray scattering. The absence of the thermal hysteresis in specific heat around T*, and the continuous evolution of the superlattice reflection detected by X-ray diffraction are consistent with the scenario that the structural transition associated with a modulation vector q = (0.5 0.5 0) in (Ca0.5Sr0.5)3Rh4Sn13 remains second-order on approaching the quantum critical point.
- Published
- 2017
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