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2. The kinetics of competing multiple-barrier unimolecular dissociations of o-, m-, and p-chlorotoluene radical cations

Author

Jongcheol Seo, Hyun-Il Seo, Seung-Joon Kim, and Seung Koo Shin

Subjects
Radicals (Chemistry) -- Research, Benzene -- Chemical properties, Benzene -- Structure, Chemicals, plastics and rubber industries
Abstract

Several ab initio/Rice-Ramsperger-Kassel-Marcus (RRKM) calculations are conducted to explain the kinetics of competing multiple-barrier unimolecular dissociations of o-, m-, and p-chlorotoluene radical cations to benzyl and tropylium ions. The benzyl channel in the system is shown to be kinetically favored.

Published
2008

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