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Photocatalytic degradation of toluene was carried out both in gas–solid and in liquid–solid regime by using polycrystalline samples of TiO2 Merck and TiO2 Degussa P25. For the gas–solid regime two types of continuous photoreactor were used, a fixed bed one of cylindrical shape and a Carberry type photoreactor, both irradiated by near-UV light. The inlet reacting mixture consisted of air containing toluene and water vapours. The influence of the gas flow rate and the presence of water vapour on the photocatalytic process was investigated. CO2 and benzaldehyde were the toluene degradation products detected in the gas phase by using TiO2 Merck. In the presence of water vapour this catalyst exhibited a stable activity, which greatly decreased in the absence of water vapour. On the contrary, TiO2 Degussa P25 produced CO2 and traces of benzaldehyde but it continuously deactivated even in the presence of water vapour. For the liquid–solid regime a batch photoreactor with immersed lamp was used. In order to increase the reaction rate, a zwitterionic surfactant, i.e. tetradecyldimethylamino-oxide, was added to the reacting mixture. A complete photo-oxidation of toluene was achieved after few hours of irradiation in the presence of both types of photocatalysts; longer irradiation times produced the photodegradation of surfactant. The main intermediates of toluene degradation were p-cresol and benzaldehyde while traces of pyrogallol and benzyl alcohol were also found. Benzoic acid, hydroquinone and trans, trans-muconic acid were detected only with TiO2 Merck. The reaction rate was higher in the presence of the surfactant suggesting that this compound acts as a sequestration agent. An FTIR study gave information on the role played by superficial hydroxyl groups both on the onset of activity and on the deactivation process. On the basis of photoreactivity results and of FTIR investigation the differences of activity and distribution and nature of toluene degradation products are critically discussed for the three reacting systems used. [Copyright &y& Elsevier]