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In this paper we classify the range of feldspathic igneous rocks using five geochemical variables: the FeO/(FeO + MgO) ratio or Fe-index, the modified alkali–lime index, the aluminum-saturation index, the alkalinity index, and the feldspathoid silica-saturation index. The Fe-index distinguishes between melts that have undergone extensive iron enrichment during differentiation from those that have not. The transition from tholeiite to ferrobasalt allows us to extend this boundary to silica values as low as 48 wt %. We introduce the feldspathoid silica-saturation index, which, coupled with the alkalinity index, allows us to extend the geochemical classification to alkaline rocks. We show that most alkaline rocks are ferroan and that this probably reflects extensive fractional crystallization of olivine and pyroxene with minimal participation of Fe–Ti oxides. The expanded classification allows us to illustrate the geochemical and petrogenetic relationship of the plutonic rocks from ferroan granites to nepheline syenites that commonly occur in intracratonic environments. It also allows us to distinguish four families of feldspathic rocks: (1) magnesian rocks, which are exemplified by Caledonian and Cordilleran batholiths and are characterized by differentiation under oxidizing and relatively hydrous conditions; (2) ferroan rocks, which include fayalite granites, alkali granites, and nepheline syenites and are characterized by differentiation under reducing and relatively dry conditions; (3) leucogranites, which commonly form by crustal melting; (4) potassic and ultrapotassic rocks, which originate from mantle that has been enriched in K2O. [ABSTRACT FROM PUBLISHER]

Following previous publication of majorminor element data, this paper presents rare earth element (REE) data for heterogeneous (chemically zoned) garnets belonging to the peridotite suite of mantle xenoliths from the Jagersfontein kimberlite pipe, South Africa. The rim compositions of the garnets in the highest temperaturepressure (deepest) deformed peridotites show a typical megacryst-like pattern, of very low light REE (LREE) increasing through the middle REE (MREE) to a plateau of heavy REE (HREE) at c. 20 times chondrite; these compositions would be in equilibrium with small-volume melts of the mid-ocean ridge basalt (MORB) source (asthenosphere). With decreasing depth the garnet rims show increasing LREE and decreasing HREE, eventually resulting in humped relative abundance patterns. A set of compositions is calculated for melts that would be in equilibrium with the garnet rims at different depths. These show decreasing relative abundance of each REE from La to Lu, and the La/Lu ratio of the melts increases with decreasing depth of formation. Modelling of the effects of crystal fractionation shows that this process could largely generate the sequence of garnet rim and melt compositions found with decreasing depth, including the humped REE patterns in high-level garnets. Considering the behaviour of majorminor elements as well as REE, a process of percolative fractional crystallization is advocated in which megacryst source melts percolate upwards through peridotites and undergo fractionation in conjunction with exchange with the peridotite minerals. The initial megacryst melt probably includes melt of lithospheric origin as well as melt from the MORB source, and it is suggested that the process of percolative fractional crystallization may form a variety of metasomatic and kimberlitic melts from initial megacryst melts. Repeated metasomatism of the lower lithosphere by such differentiating melts is suggested by consideration of garnet core compositions. Such metasomatism would progressively convert harzburgites to lherzolites by increasing their CaO content, and this may account for the fact that the Cr-rich diamondgarnet harzburgite paragenesis is commonly preserved only where it has been encapsulated in diamonds. [ABSTRACT FROM AUTHOR]

We report new experimental data from ultrabasic basanite and ultrabasic tephrite as starting material compositions in the 1350°C to 1000°C temperature range. Crystallization experiments under low- to high-pressure (0.5–2.0 GPa) were carried out under reduced conditions (≈CCO buffer), while one-atmosphere, anhydrous, experiments were performed ranging from reduced to oxidized conditions (−2 ≤ ∆QFM ≤ +2). The results highlight the ƒO2 role on the silica saturation of the alkali liquids differentiated from these primary ultrabasic magmas, on the mineral assemblage, and its composition. The liquid lines of descent (LLDs) from basanite are sodic and strongly SiO2 undersaturated, whereas from tephrite, the LLDs are sodic-potassic/potassic for both weakly SiO2-undersaturated and SiO2-saturated compositions, being more silica saturated under oxidized conditions. At the lowest temperature experiments, the percentage of liquid remaining is significantly higher in the basanite-derived products (ca. 35 wt.%) than in tephrite, indicating that the equivalent magmas are more prone to produce larger quantities of evolved melts. The best obtained Fe–Mg olivine/melt and clinopyroxene/melt exchange coefficients for these alkali compositions considering the new and available data are |${K_D}_{Fe^{2+}- Mg}^{Ol- Alkali\ melt}=0.285\pm 0.014$| and |${K_D}_{Fe^{2+}- Mg}^{Cpx- Alkali\ melt}=0.245\pm 0.008$|⁠ , slightly lower than those observed in tholeiitic melts. Clinopyroxene compositions are Ti–Al-rich and Si-poor as compared with common clinopyroxenes in subalkali systems. We suggest that Ti should be allocated in the tetrahedral sites substituting for Si and that its contents are inversely correlated with pressure. Our results allow a simple new barometer based on clinopyroxene-only compositions, as follows: $$ P\left(\pm 0.16\ GPa,1\sigma \right)=16.028\left(\pm 1.042\right) Na-6.715\left(\pm 0.727\right)\frac{Ti}{Ti+ Al(t)}+0.494\left(\pm 0.441\right) Si+0.144\left(\pm 0.079\right) $$ where Na, Ti, Al(t), and Si are molar proportions relative to 6O. This formulation accounts for the jadeite (NaAlSi2O6) component, herein computed from the Na contents, corrected for the Ti-diopside (CaMgTi2O6) component in clinopyroxene and also considers the evolutionary trend from Mg-augite to ferroan diopside. It applies to alkali ultrabasic to intermediate compositions in the examined P–T–ƒO2 range, resulting in more accurate estimates than the available calibrations. The MgO-in-melt thermometer was optimized for the studied compositions at one-atmosphere pressure and anhydrous conditions, as follows: $$ T\ \left(\pm 5{}^{\circ}C,1\sigma \right)=27.35\left(\pm 0.65\right)\ \big({MgO}^{liq}\big)+984\left(\pm 4\right) $$ which provides much more reliable liquidus temperatures for these alkali systems. Given data restriction, this formulation may be expanded to include the pressure effects for relatively low-H2O (< 3 wt.%) systems as: $$ T\ \left(\pm 20{}^{\circ}C,1\sigma \right)=27.35\left(\pm 0.65\right)\big({MgO}^{liq}\big)+80.20\left(\pm 5.50\right)P(GPa)+981\left(\pm 4\right) $$ [ABSTRACT FROM AUTHOR]

The experimental determination of liquid compositions in lherzolite as functions of pressure and temperature provides constraints on mantle dynamics and magma genesis. In this paper, we present a detailed evaluation of the use of natural mineral mixes as starting material in peridotite melting studies at 1·0 GPa. As an example we have chosen to test the data obtained by Baker & Stolper (1994, Geochimica et Cosmochimica Acta 58, 2811-2827) on a lherzolite composition (MM-3) presented as a potential source for mid-ocean ridge basalts (MORB). That study is the most fully documented published melting study using natural mineral mixes. We have tested the Baker & Stolper data in three ways: (1) we have defined the liquidus phases and conditions of the partial melt compositions obtained by Baker & Stolper; (2) we have reacted these partial melt compositions with a fine-grained synthetic starting mix of MM-3 composition; (3) we have performed additional melting experiments at 1·0 and 1·5 GPa using the synthetic mix of peridotite MM-3. Our results demonstrate that only the highest temperature experiment of Baker & Stolper, performed at 1390°C, approached an equilibrium melt of peridotite MM-3 composition and that lower temperature experiments have not reached equilibrium, retaining residual unreacted minerals and metastable melt compositions. The degree of disequilibrium increases progressively with lower temperature. Disequilibrium is attributed to the lack of reaction of the natural mineral mix and to disequilibrium melting reactions of the metastable, relatively coarse-grained mineral mix. Other contributing factors include disequilibrium caused by the use of a diamond aggregate trap. We also present peridotite melting experiments using the mineral mix KLB-1 at 1·0 GPa. Our results demonstrate that the mineral mix KLB-1 fails to equilibrate even after ~340 h at temperatures of 1280-1300°C. We present reversals of the 1·0 GPa peridotite melting experiments of Hirose & Kushiro (1993, Earth and Planetary Science Letters 114, 477-489). Our reversals demonstrate that the mineral mix-diamond aggregate trap technique used by Hirose & Kushiro has also failed to produce equilibrium melts of a mantle peridotite composition. It is recommended that data from peridotite melting studies utilizing natural mineral mixes be used with reservation and that natural mineral mixes are not a suitable starting material for such studies. The use of diamond aggregate for separation and trapping of the melt phase compounds rather than solves the problems inherent in the use of natural mineral mixes. [ABSTRACT FROM PUBLISHER]

The geochemical variations of Kilauea's historical summit lavas (1790-1982) document the short-term magmatic evolution of one of the Earth's most active volcanoes. Most of these lavas are thought to have erupted directly from the shallow (2-4 km deep) magma reservoir that underlies the volcano's summit region. This paper details a remarkable variation of lava chemistry that spans nearly the entire known compositional range of the volcano in only 200 years. The Pb, Sr, and Nd isotope and incompatible trace element ratios (e.g. La/Yb or Nb/Y) of the lavas vary systematically over time with an abrupt reversal after 1924. This rapid geochemical fluctuation records the temporal changes in the parental magma composition delivered to Kilauea's summit reservoir since 1790. The isotope and incompatible trace element ratio systematics suggest that the source region of historical Kilauea magma is both isotopically and chemically heterogeneous. These source variations can be explained by the melting of small-scale heterogeneities within the Hawaiian mantle plume. Model calculations suggest that the degree of partial melting decreased from the early 19th century until the mid-20th century, which correlates with a lower eruption rate (and presumably a lower magma supply rate) for the volcano between 1840 and 1959. This interval of declining output from the Hawaiian plume culminated with an explosive summit eruption in 1924 and the longest quiescent period in Kilauea's historical record (1934-1952). Lavas erupted just after 1924 are geochemically anomalous and may have been contaminated by the assimilation of country rock into the volcano's magma reservoir during the explosions. Subsequently, the inferred degree of partial melting and the volcano's eruption rate have increased, with the highest values since the early 19th century observed during the current Puu Oo rift zone eruption. [ABSTRACT FROM PUBLISHER]

The Skaergaard intrusion is one of the most thoroughly studied layered mafic intrusions on Earth and an exceptional example of (near) closed-system magmatic differentiation. We report new Fe isotope data for whole rocks, and magnetite and ilmenite separates through the layered series (LS) and upper border series (UBS) of the intrusion. δ56Fe values for gabbroic rocks range from 0.033‰ to 0.151‰ with an abrupt step increase at the base of Lower Zone c (LZc) within LS with the appearance of cumulus magnetite and subsequent decline accompanying FeTi oxide fractionation. The lowest δ56Fe values are found near the Upper Zone b (UZb) to c (UZc) boundary followed by a sharp rise across UZc approaching the Sandwich Horizon. Magnetite–ilmenite separates straddle bulk rock compositions with fractionation factors (Δ56Femt-ilm) of 0.081‰ to 0.239‰, consistent with subsolidus equilibration. Granophyric rocks occurring as pods, sheets and wispy layers from the upper zone and UBS equivalents and having unradiogenic Sr similar to gabbroic rocks of Skaergaard, are isotopically heavier than their host ferrodiorites (Δ56Fegranophyre-ferrodiorite ≥ 0.1‰) reaching a maximum δ56Fe of 0.217‰ in UBS. A fused xenolith from UBS has δ56Fe = 0.372‰. This range in δ56Fe spans much of that reported for terrestrial igneous rocks, and like the global dataset, shows a pronounced increase in δ56Fe with inferred silica content of modeled Skaergaard liquids. Forward modeling of closed system fractional solidification was undertaken to account for Fe isotope systematics, first by testing published liquid lines of descent (LLD), and then by exploring improvements and considering the impacts of liquid immiscibility, crustal contamination, fluid exsolution and diffusional processes. Our modeling relies on published Fe+2 and Fe+3 force constants for magmatic minerals and silicate glasses, and the most reliable estimates of the average bulk composition and mass proportions of the well-defined subzones of the intrusion. We show that the increase in δ56Fe across the LZb–LZc boundary is readily explained by the increased incorporation of Fe+3 into the crystallizing solid including magnetite. We further demonstrate that the classic Fenner LLD, involving strong Fe enrichment at nearly constant silica, does not lead to a rise in δ56Fe toward the end stages of evolution, while a Bowen-like LLD, with little Fe enrichment and strong Si enrichment, also underestimates enrichment in heavy Fe isotopes in the ferrodiorites of UZc. A LLD following an intermediate path involving modest Fe and Si enrichment, followed by Fe depletion best explains the observations. We predict ~3.5% (by mass) residual liquid after crystallization of UZc having a composition similar to felsic segregations in pegmatitic bodies found in the intrusion. While liquid immiscibility may have been encountered within fractionating mush at the margins of the intrusion, the Fe isotope systematics do not support liquid phase separation of the bulk magma. Crustal contamination, fluid exsolution, hydrothermal alteration and thermal diffusion are also shown to have no resolvable effect on the Fe isotope composition of the gabbroic and granophyric rocks. We conclude that the Fe isotope systematics documented in the Skaergaard intrusion reflect the dominant role of fractionating Fe-rich minerals from gabbroic through ferrodioritic to rhyolitic liquids. The success of our model to account for the observed Fe isotope systematics for Skaergaard demonstrates the utility of Fe+2 and Fe+3 force constants determined at ambient conditions to model magmatic conditions and gives critical insights into plutonic processes fractionating Fe isotopes complementary to the volcanic record. [ABSTRACT FROM AUTHOR]

Crystallization and solidification pathways in crustal magma chambers control the chemical and textural evolution of igneous rocks. However, deciphering these codes from completely solidified cumulates is challenging and requires a full understanding of growth processes of minerals and textures of rocks. In this study, we collected samples from a ca. 380-m-thick drill core intersecting the ultramafic sequence of the Xinjie layered intrusion in SW China, which is composed of wehrlite with poikilitic clinopyroxene (Cpx), and clinopyroxenite and olivine clinopyroxenite with euhedral to subhedral Cpx grains. Using micro-X-ray fluorescence and electron probe micro-analyzer mapping techniques, we found that the Cpx grains in clinopyroxenite and olivine clinopyroxenite are characterized by sector-zoned, Cr-rich cores, whereas the Cpx oikocrysts in wehrlite only show Cr-rich cores without sector zoning. The sector-zoned cores of the Cpx grains are widespread in clinopyroxenite and olivine clinopyroxenite and consist of Si–Mg-rich hourglass sectors and Cr–Al–Ti-rich prism sectors, indicating rapid growth of the Cpx grains due to moderate degrees of undercooling, which may be induced by fast cooling during initial emplacement of Cpx-saturated magma into cold country rocks. The sector-zoned Cpx grains thus likely constructed the initial crystal framework in the magma chamber. In contrast, the absence of sector zoning in Cr-rich cores of the Cpx oikocrysts indicates that an olivine-saturated magma may have intruded a high-temperature, Cpx-laden crystal mush so that magma undercooling was significantly reduced or eliminated and no sector zoning developed in the Cpx oikocrysts. Such a process may also result in the spatial variation of the medians of Cpx–Cpx–plagioclase dihedral angles (Θccp) in clinopyroxenite, which shows a significant reduction from an original impingement angle of ~60° in the middle and upper parts to ~40° in the basal part of the sequence. The reduction of Θccp could be attributed to melt-present textural equilibration in the Cpx-laden mush that was sustained by additional heat supplied by massive olivine-saturated melt input in the ~40-m-thick basal part. Here, we propose that the ultramafic sequence of the Xinjie layered intrusion may have formed by the intrusion of primitive, olivine-saturated magma into an early-formed Cpx-laden mush in a manner of sill-like sheets. This study provides new perspectives on the early history of a magma chamber and emphasizes the role of sill intrusion of primitive magmas into crystal mush in the formation of ultramafic sequences in layered intrusions, which has been relatively overlooked in previous studies. [ABSTRACT FROM AUTHOR]

Crystal clusters are common in both extrusive and plutonic rocks, but the mechanisms by which they form are not well-constrained. Following a consideration of the physics of nucleation, we outline the expected microstructural characteristics of clusters formed by heterogeneous nucleation and those formed by synneusis, together with the ways they might evolve during subsequent grain growth and textural equilibration. By combining analysis of the microstructures in experimental chromite-basalt charges with a detailed microstructural analysis of the UG2 chromitite of the Bushveld layered intrusion using EBSD, we argue that the UG2 chromitite formed by settling and accumulation of single grains and clusters comprising randomly oriented grains produced by the aggregation of previously isolated chromite crystals. Although there is no evidence of epitaxy, at least some of the lowermost chromite grains of the main UG2 chromitite may have nucleated heterogeneously on the silicate grains forming the floor, with subsequent accumulation and sintering of individual grains or clusters. The reduced thickness of chromitites on the steep and overhanging parts of the floor is thus due to the relative difficulty of sticking more grains to the existing layer in these orientations. The absence of any fining-upwards of grains in either the main UG2 chromitite or the associated stringer can be accounted for if both layers were formed by the settling and accumulation of clusters as well as single grains. Comparison with examples of clustered chromite grains in extrusive rocks suggests that aggregation by synneusis is a widespread magmatic process. The 'chicken-wire' texture formed by clustered chromite grains commonly found in olivine-rich cumulates is argued to also be formed by gravitational settling, with the possible exception of clusters of chromite grains in relatively thin seams argued to be the result of metasomatism, which may instead have formed by impingement during in situ growth. [ABSTRACT FROM AUTHOR]

Scanning electron microscope, cathodoluminescence (CL) imaging and laser ablation–inductively coupled plasma–mass spectrometry analyses were conducted on coexisting pairs of quartz and K-feldspar from 14 samples of various types of felsic igneous rocks. Difference of the concentration of trace elements in quartz and K-feldspar among plutonic, pegmatitic and volcanic rocks is closely related to the rock-forming process and P–T condition. In general, a decreasing Ti concentration and increasing Al, Li, and Ge concentrations from plutonic to pegmatitic quartz suggest a higher degree of magmatic fractionation and lower crystallization temperature. Sensitive elements to magma differentiation in K-feldspar such as Ba, Sr, and LREE show a decreasing trend from various granitic rocks to pegmatite, while Rb, Cs, Li, Ge, and P exhibit increasing trends. The K-feldspar from various types of felsic igneous rocks typically shows similar CL textures but relatively higher luminescence intensity compared with coexisting quartz. Both quartz and K-feldspar phenocrysts in the volcanic rhyolite have a bright rim and a dark core in CL images, corresponding to bimodal Ti concentrations. Among all samples, Ti concentrations in both quartz and coexisting K-feldspar positively correlate with their CL intensities, suggesting the activation of Ti-impurity in these minerals leads to increased CL intensity. Meanwhile, there is a good positive correlation between Ti concentrations in quartz and those in K-feldspar with an R 2 value of 0.86. It is considered that Ti concentrations in the both minerals are mainly temperature dependent at relatively constant pressure on basis of a fair a TiO2 restriction. Here, for the first time, we calculated a titanium-in-K-feldspar (TitaniKfs) thermometer in the form of log (X Ti, kfs/ a TiO2) = −(3430 ± 268)/ T (K) + (5.081 ± 0.298) for natural felsic magma systems. The Ti contents of K-feldspar (in ppm by weight) increase exponentially with reciprocal T at temperatures ranging from 500°C to 800°C, at 200–300 MPa. An application of this thermometer to granitic rocks from Xinjiang and Inner Mongolia in China fits well with other geothermometers. In addition, the present TitaniKfs thermometer is expected to be particularly useful in determining the temperature condition of K-feldspar-bearing extraterrestrial materials such as lunar rocks. [ABSTRACT FROM AUTHOR]

The concept of defrosting, heating and partially melting a crystal-rich, weakly mobile or immobile magma (magmatic mush) has gained wide support from volcanological studies. This process has been called on as a means to promote eruption of crystal-rich (monotonous) dacites and also to permit extraction of felsic magmas, which may accumulate in the upper crust and erupt as crystal-poor rhyolite or trachyte. Most studies of the latter type of defrosting call on a conjugate plutonic part of the system from which the felsic melt was extracted. Although petrographic and geochemical features of defrosting are well described for eruptive rocks, few studies have investigated petrographic and geochemical features of plutons that indicate defrosting. The Jurassic Ashland pluton is a tilted intrusive complex exposed in southern Oregon and northern California, USA. The central part of the pluton, quartz monzodiorite (QMD), displays petrographic features (crystal fragmentation, widespread resorption, local concentrations of refractory minerals) characteristic of partial melting. This unit is intruded and overlain by biotite granite, which displays plagioclase cores identical in composition to plagioclase in the underlying QMD, resorbed titanite cores in plagioclase, and local subhedral to anhedral cores of alkali feldspar in poikilitic alkali feldspar crystals. Hornblende and biotite in the biotite granite display enrichments in Ti and Nb relative to these minerals in QMD, negating fractional crystallization as a petrogenetic process. Instead, these high Ti and Nb contents reflect significant partial melting of titanite in the QMD, thereby releasing high field strength elements to the defrosted biotite granite melt. The biotite granite magmas are thus interpreted as the melt-rich products of defrosting caused by intrusion of mafic–intermediate magmas into the QMD magma column. [ABSTRACT FROM AUTHOR]

The Rio Blanco deposit, which is one of the largest porphyry Cu–Mo deposits in northern Peru, formed coevally with the subduction of the Inca Oceanic Plateau at 12–10 Ma. However, the genetic relationship between the subduction of oceanic plateaus and the porphyry deposit formation remains unclear. Igneous rocks emplaced at 23–12 Ma in northern Peru, including the Portachuela batholith (which hosts the Rio Blanco porphyry complex), are normal calc-alkaline to weakly adakitic. In comparison, the 12–8 Ma igneous rocks, including the ore-related Rio Blanco porphyry complex, have typical adakitic signatures, such as high Sr/Y ratios (up to 180) and LaN/YbN ratios (up to 32). The Rio Blanco igneous rocks (Portachuela batholith and Rio Blanco porphyry complex) have uniform zircon εHf(t) values (+0.3 ± 1.2) and δ18O values (6.5 ± 0.14‰). These geochemical characteristics indicate that the Rio Blanco igneous rocks evolved from mantle-derived parental melts in a long-lived, stable, homogeneous isotopic reservoir at the crust–mantle boundary. However, whereas both the Portachuela batholith and the Rio Blanco porphyry complex formed from hydrous parental magmas (>5 wt %; based on plagioclase hygrometry), the ones of the Rio Blanco porphyry complex seem to be more oxidized, hydrous, and sulfur-rich compared with the older batholitic rocks. Reverse zoning in plagioclase phenocrysts, with a systematic core–mantle–rim variation in An (anorthite) and Fe (total iron) contents, are common in the intermineralization rocks. The An content of the mantles of the plagioclase phenocrysts correlates positively with the Fe content, but in the rims, the An contents significantly decrease while Fe remains constant. The apatite inclusions in the mantles are richer in S (0.24 ± 0.06 wt %) and Cl (1.42 ± 0.32 wt %) than those in the phenocryst cores (S: 0.09 ± 0.07 wt %; Cl: 1.03 ± 0.56 wt %) and rims (S: 0.14 ± 0.09 wt %; Cl: 0.83 ± 0. 35 wt %). These systemic geochemical variations in the plagioclase phenocrysts suggest recharge by S- and Cl-rich melts followed by fluid exsolution. This magma recharge and subsequent fluid exsolution may have triggered porphyry Cu mineralization at Rio Blanco. The coincidence of timing between the geochemical transition and collision (initial subduction) of the Inca Oceanic Plateau with the South American plate may indicate a change in the tectonic regime to a compressional state of stress and a thickening of the crust during the collision. The tectonic transition would have facilitated the fractionation of mantle-derived magma in a deep crustal hot zone, resulting in oxidized, volatile-rich residual melts. Replenishment of the upper-crustal magma chamber by such volatile-rich magmas and the subsequent discharge of fluids are interpreted to be fundamental for porphyry Cu mineralization at Rio Blanco and plausibly for the formation of Late Miocene porphyry ore deposits in northern Peru in general. [ABSTRACT FROM AUTHOR]

The origin of the Eastern Mexican Alkaline Province has been explained by landward arc migration and subsequent asthenospheric upwelling after slab roll-back of the Farallon Plate. In this work, we present new petrographic, mineral chemical, geochemical, and geochronological data of the Sierra de San Carlos-Cruillas (SSCC), one of the most important complexes in the province. This information, together with published data, helped us to reinterpret the tectonic processes operating during the generation of this province, as well as the mantle sources involved in the partial melting process. Detailed geochemical analysis suggests the participation of two types of metasomatized mantle regions: a lithospheric source modified by past subduction processes and an asthenospheric source slightly affected by carbonatite-related metasomatism. Variations in the partial melting degrees controlled the extent of magma enrichment in the latter. Major and trace element geochemistry, together with geochronological data and field relations, evinced an older post-orogenic setting related to the arc-like rocks (Eocene) and a younger intraplate extensional environment associated with all enriched igneous rocks (Oligocene-Miocene). Bivariate diagrams of SiO2-trace element ratios and multi-element patterns indicate that magmas from the SSCC complex dominantly evolved through fractional crystallization with a limited crustal contribution. Petrographic and mineral chemistry features suggest that some of these magmas experienced open-system processes (e.g. recharge events) in a complex and dynamic magmatic feeding system. In contrast to the traditional petrotectonic model, we propound that the passage and subsequent foundering of the Hess conjugate under northeastern Mexico resulted in its eclogitization and triggered slab tearing and succeeding detachment. This latter process occasioned mantle upwelling and the partial melting of the two recognized metasomatized mantle sources, thus generating the San Carlos-Cruillas magmatism. [ABSTRACT FROM AUTHOR]

Mantle preconditioning may be defined as the extraction of small melt fractions from mantle asthenosphere during its flow to the site of magma generation. Equations may be written for mantle preconditioning, assuming that the mantle comprises enriched plums in a depleted matrix. The equations take into account variations in mass fraction of plums, the relative rate of melting of plums and matrix, the temperature and pressure of melt extraction, the mass fraction of melt extracted, the extent of chemical exchange between plums and matrix, and the efficiency of melt extraction. Monitoring mineralogical changes and variations in partition coefficients along the inferred PTt path of the mantle asthenosphere allows the equations to be correctly applied to the conditions under which melt extraction takes place. Numerical experiments demonstrate the influence of petrogenetic variables on the shape of melt extraction trajectories and provide new criteria for distinguishing between melt extraction and mixing as the cause of regional geochemical gradients. Representative examples of arcback-arc systems (Scotia), continental break-up (Afar) and plumeridge interaction (Azores) indicate that the compositions of the mantle sources of mid-ocean ridge basalts and island arc basalts may be determined, at least in part, by the melt extraction histories of their asthenospheric sources. [ABSTRACT FROM AUTHOR]

Granitic rocks, interpreted to be related to crustal melting, were emplaced into regions of thickened crust in southern Arizona during the Laramide orogeny (80–40 Ma). Laramide-age anatectic rocks are exposed as plutons, sills, and dike networks that are commonly found in the exhumed footwalls of metamorphic core complexes. This study investigates newly discovered exposures of granodioritic–leucogranitic rocks from three intrusive phases in the footwall of the Pinaleño–Jackson Mountain metamorphic core complex of southeastern Arizona, called the Relleno suite. Zircon U–Pb geochronology indicates that the suite was emplaced from 58 to 52 Ma. Zircon Lu/Hf isotope geochemistry, whole-rock Sr and Nd isotope geochemistry, and mineral O isotope geochemistry were used to investigate the source of these rocks and evaluate whether they are related to crustal anatexis. Average zircon εHf(t) values of the suite range from −4.7 to −7.9, whole-rock εNd(i) and 87Sr/86Sr(i) values range from −9.4 to −11.8 and 0.7064 to 0.7094 respectively, and quartz δ18OVSMOW values range from 6.8 to 9.4 ‰. Isotopic and geochemical data of these rocks are consistent with derivation from and assimilation of intermediate–mafic (meta)igneous rocks, at deep crustal levels, and are supported by thermodynamic melt models of Proterozoic igneous rocks equivalent to those exposed in the Pinaleño Mountains. In comparison with other Laramide-age anatectic granites in SE Arizona, those exposed in the Pinaleño Mountains are temporally similar but present compositional and isotopic differences that reflect melting and assimilation of different lithologies, producing distinct mineralogical and isotopic characteristics. The results suggest that crustal melting during this interval was not limited to metasedimentary protoliths and may have affected large portions of the deep crust. The early Paleogene Relleno suite in the Pinaleño Mountains strengthens the relationship between crustal melting and regions of thickened crust associated with the Sevier and Laramide orogenies. [ABSTRACT FROM AUTHOR]

Mesoproterozoic metaplutonic rocks in northern Cape Breton Island, Nova Scotia, occur in a tectonic inlier within the Appalachian orogen. Although they have been multiply metamorphosed and variably deformed, the petrology and geochemistry of these rocks provide insight into the tectonomagmatic evolution of easternmost Laurentia. Anorthosite, syenite, and granitoid plutons (1100–980 Ma) intruded the Sailor Brook and Polletts Cove River gneisses. New Nd isotopic data are presented from a biotite-rich part of the Sailor Brook gneiss (εNdi = −0·7), two anorthosite samples (εNdi = +2·1 and +2·8), and a charnockite unit (εNdi = −0·4). New U–Pb zircon data from the anorthosite yield 207Pb/206Pb ages between 975 and 1095 Ma. Disrupted U–Pb systematics preclude a unique age interpretation, but the ∼1095 Ma single-grain date is a minimum age for the anorthosite. Field relations, major and trace-element geochemistry, and isotopic characteristics indicate that the anorthosite and charnockite were probably coexisting melts, but not differentiates of a single parent magma. The lithological and chemical characteristics of the Lowland Brook Syenite are similar to those of a contemporaneous belt of ultrapotassic plutons in the southern Grenville Province, and both have the chemical characteristics of certain modern continental-margin arc magmas. These data indicate that the Mesoproterozoic units in the Blair River inlier were juvenile crustal additions to eastern Laurentia during Grenville-related orogenic events. [ABSTRACT FROM PUBLISHER]

Most known porphyry Cu ± Au deposits are associated with moderately oxidized and sulfur-rich, calc-alkaline to mildly alkalic arc-related magmas in the Phanerozoic. In contrast, sodium-enriched tonalite–trondhjemite–granodiorite–diorite (TTG) magmas predominant in the Archean are hypothesized to be unoxidized and sulfur-poor, which together preclude porphyry Cu deposit formation. Here, we test this hypothesis by interrogating the causative magmas for the ~2·7 Ga TTG-related Côté Gold, St-Jude, and Clifford porphyry-type Cu ± Au deposit settings in the Neoarchean southern Abitibi subprovince. New and previously published geochronological results constrain the age of emplacement of the causative magmas at ~2·74 Ga, ~2·70 Ga, and ~ 2·69 Ga, respectively. The dioritic and trondhjemitic magmas associated with Côté Gold and St-Jude evolved along a plagioclase-dominated fractionation trend, in contrast to amphibole-dominated fractionation for tonalitic magma at Clifford. Analyses of zircon grains from the Côté Gold, St-Jude, and Clifford igneous rocks yielded ε Hf(t) ± SD values of 4·5 ± 0·3, 4·2 ± 0·6, and 4·3 ± 0·4, and δ18O ± SD values of 5·40 ± 0·11 ‰, 3·91 ± 0·13 ‰, and 4·83 ± 0·12 ‰, respectively. These isotopic signatures indicate that, although these magmas are mantle-sourced with minimal crustal contamination, for the St-Jude and Clifford settings the magmas or their sources may have undergone variable alteration by heated seawater or meteoric fluids. Primary barometric minerals (i.e. zircon, amphibole, apatite, and magnetite–ilmenite) that survived variable alteration and metamorphism (up to greenschist facies) were used for estimating f O2 of the causative magmas. Estimation of magmatic f O2 values, reported relative to the fayalite–magnetite–quartz buffer as ΔFMQ, using zircon geochemistry indicates that the f O2 values of the St-Jude, Côté Gold, and Clifford magmas increase from ΔFMQ –0·3 ± 0·6 to ΔFMQ +0·8 ± 0·4 and to ΔFMQ +1·2 ± 0·4, respectively. In contrast, amphibole chemistry yielded systematically higher f O2 values of ΔFMQ +1·6 ± 0·3 and ΔFMQ +2·6 ± 0·1 for Côté Gold and Clifford, respectively, which are consistent with previous studies that indicate that amphibole may overestimate the f O2 of intrusive rocks by up to 1 log unit. Micro X-ray absorption near edge structure (μ-XANES) spectrometric determination of sulfur (i.e. S6+/ΣS) in primary apatite yielded ≥ΔFMQ −0·3 and ΔFMQ +1·4–1·8 for St-Jude and Clifford, respectively. The magnetite–ilmenite mineral pairs from the Clifford tonalite yielded ΔFMQ +3·3 ± 1·3 at equilibrium temperatures of 634 ± 21 °C, recording the redox state of the late stage of magma crystallization. Electron probe microanalyses revealed that apatite grains from Clifford are enriched in S (up to 0·1 wt%) relative to those of Côté Gold and St-Jude (below the detection limit), which is attributed to either relatively oxidized or sulfur-rich features of the Clifford tonalite. We interpret these results to indicate that the deposits at Côté Gold and Clifford formed from mildly (~ΔFMQ +0·8 ± 0·4) to moderately (~ΔFMQ +1·5) oxidized magmas where voluminous early sulfide saturation was probably limited, whereas the St-Jude deposit represents a rare case whereby the ingress of externally derived hydrothermal fluids facilitated metal fertility in a relatively reduced magma chamber (~ΔFMQ +0). Furthermore, we conclude that variable modes of formation for these deposits and, in addition, the apparent rarity of porphyry-type Cu–Au deposits in the Archean may be attributed to either local restriction of favorable metallogenic conditions, and/or preservation, or an exploration bias. [ABSTRACT FROM AUTHOR]

We present microbeam major- and trace-element data from 14 monzodiorites collected from the Malaspina Pluton (Fiordland, New Zealand) with the goal of evaluating processes involved in the production of andesites in lower arc crust. We focus on relict igneous assemblages consisting of plagioclase and amphibole with lesser amounts of clinopyroxene, orthopyroxene, biotite and quartz. These relict igneous assemblages are heterogeneously preserved in the lower crust within sheeted intrusions that display hypersolidus fabrics defined by alignment of unstrained plagioclase and amphibole. Trace-element data from relict igneous amphiboles in these rocks reveal two distinct groups: one relatively enriched in high field strength element concentrations and one relatively depleted. The enriched amphibole group has Zr values in the range of ∼25–110 ppm, Nb values of ∼5–32 ppm, and Th values up to 2·4 ppm. The depleted group, in contrast, shows Zr values <35 ppm and Nb values <0·25 ppm, and Th is generally below the level of detection. Amphibole crystallization temperatures calculated from major elements range from ∼960 to 830 °C for all samples in the pluton; however, we do not observe significant differences in the range of crystallization temperatures between enriched (∼960–840 °C) and depleted groups (∼940–830 °C). Bulk-rock Sr and Nd isotopes are also remarkably homogeneous and show no apparent difference between enriched (εNdi = 0·1 to –0·1; 87Sr/86Sri = 0·70420–0·70413) and depleted groups (εNdi = 0·3 to –0·4; 87Sr/86Sri = 0·70424–0·70411). Calculated amphibole-equilibrium melt compositions using chemometric equations indicate that melts were highly fractionated (molar Mg# <50), andesitic to dacitic in composition, and were much more evolved than bulk lower continental crust or primitive basalts and andesites predicted to have formed from hydrous melting of mantle-wedge peridotite beneath an arc. We suggest that melts originated from a common, isotopically homogeneous source beneath the Malaspina Pluton, and differences between enriched and depleted trace-element groups reflect varying contributions from subducted sediment-derived melt and sediment-derived fluid, respectively. Our data demonstrate that andesites and dacites were the dominant melts that intruded the lower crust, and their compositions mirror middle and upper bulk-continental crust estimates. Continental crust-like geochemical signatures were acquired in the source region from interaction between hydrous mantle-wedge melts and recycled subducted sediment rather than assimilation and/or remelting of pre-existing lower continental crust. [ABSTRACT FROM AUTHOR]

The Bushmanland Subprovince of the Mesoproterozoic Namaqua-Natal orogenic belt in southern Africa hosts numerous occurrences of monazite-magnetite-(biotite-apatite-sulfide)-bearing veins and granitoid dykes, including the Steenkampskraal vein system, which is one of the highest-grade REE-Th ore deposits in the world. Here, we provide whole-rock geochemical data along with zircon and monazite U-Pb dates and monazite Sm-Nd isotope analyses of these REE-Th-rich veins and granitoid dykes. The U-Pb geochronology indicates that the monazite-rich veins and granitoid dykes formed between 1050 and 1010 Ma, contemporaneously with late-Namaqua granulite-facies metamorphism. They are also coeval with the Koperberg Suite mafic magmas at 1060–1020 Ma and the late stage of a major event of A-type granitoid magmatism that occurred from 1100 to 1030 Ma (i.e. the Spektakel Suite). Similar to the mafic intrusive rocks from the Koperberg Suite, monazite-rich veins and granitoid dykes, located in the southern part of the Bushmanland Subprovince, have more radiogenic Nd isotopic compositions (ɛNd(t) ∼ −1 to zero) than equivalent dykes and veins to the north (ɛNd(t) ∼ −12 to −6). Mafic rocks of the Koperberg Suite reach Th and La concentrations of >400 ppm that significantly exceed those of other rock types from the region, except for the monazite-rich veins and granitoid dykes, which suggests a genetic link between these rocks. Within veins and granitoid dykes, monazite, biotite and magnetite are commonly anhedral and occur interstitially between the felsic minerals; they are, thus, late crystallizing phases. The whole-rock REE-Th concentrations of the granitoid dykes increase with Fe-Mg contents. Therefore, their incompatible element enrichment is not linked to assimilation-fractional crystallization processes. The Nd isotopic signature as well as Fe-Mg- and REE-Th-rich character of the Koperberg Suite and monazite-rich granitoid dykes might reflect partial melting of lithospheric mantle domains, metasomatized during previous Namaqua subduction events, and the mixing of mantle-derived melts with REE-Th-rich metamorphic fluids during their ascent through the crust. We propose that the monazite-magnetite vein mineralizations represent Fe-P-rich immiscible liquids that exsolved from mantle-derived magmas with compositions similar to the most mafic and monazite-rich granitoid dykes. Within this petrogenetic model, conjugate silicate-rich immiscible liquids formed the more felsic granitoid dykes characterized by lower modal abundances of biotite, magnetite and monazite. Although they do not reach similarly high REE-Th concentrations, other A-type granitoids from the region, represented by the Spektakel Suite, also share geochemical affinities with mafic igneous rocks from the Koperberg Suite; they may have originated by melting of underplated equivalents of these late-orogenic mafic rocks. [ABSTRACT FROM AUTHOR]

Abundant silica-undersaturated potassic lavas are found in the centre of the Turkish–Iranian plateau (NW Iran) as flows, pillows and dykes. They display abundant zoned clinopyroxene macrocrysts and xenoliths of igneous cumulates. We determined four types of zoned crystals (Type-I, -II, -III and -IV) on the basis of their composition and zoning patterns. Use of in situ compositional data, together with whole-rock major and trace elements and the isotopic signatures of the host lavas provided evidence for the derivation of the different types of zoned clinopyroxenes from at least two contrasting parental melts. Our findings are consistent with an origin of the ultrapotassic and sodic alkaline melts from the deep-seated compaction pockets inferred from our previous studies of the alkaline magmatism throughout the Turkish–Iranian plateau. The ultrapotassic melt, which accumulated at the top of the compaction pockets, eventually ponded close to the spinel–garnet mantle transition and generated colourless antecrysts (Type-I and Type-II) and clinopyroxenite cumulates. When the compaction pocket impinged on the continental lithosphere, interstitial melts segregated and flowed inside dykes where grass green antecrysts (Type-III) and zoned phenocrysts (Type-IVa) crystallized from a melt having a geochemical signature of sodic alkaline melt. Later, at the crustal level, melt crystallization processes produced Type-IVb zoned phenocrysts. Our results are at odds with the paradigm of potassic magmas in NW Iran being derived strictly from a single mantle source. [ABSTRACT FROM AUTHOR]

Porphyry systems, the most important reserves of Cu and Mo with significant Au, are genetically linked to the emplacement of hydrous and oxidized intermediate to acidic magmas, in response to temporal and geochemical evolution of crust in orogenic terranes. In this study, comprehensive whole-rock and zircon geochemical and isotopic datasets of intermediate to acid igneous rocks were integrated to characterize the crustal evolution and metallogeny of porphyry deposits in the Central Asian Orogenic Belt (CAOB). The ore-forming porphyries of Cu ± Au ± Mo and Mo deposits have higher but largely overlapped ΔFMQ (the proxy for oxygen fugacity) with those of the barren igneous rocks. However, the ore-forming porphyries of Cu ± Au ± Mo deposits are characterized by distinctly higher whole-rock V/Sc and zircon Eu/Eu* (both are proxies for water content) than barren rocks. Furthermore, the V/Sc ratios positively correlate with the Cu tonnages of calc-alkali porphyry Cu deposits, suggesting that magmatic water contents may yield the first-order control on metal endowment. The general decrease of V/Sc from the Paleozoic to Mesozoic, combined with the negative correlation of V/Sc with K2O and SiO2, also indicates the gradual evolution of crust in CAOB clearly controls the end members of porphyry-type systems (i.e. Cu‒Au and Mo deposits). The crustal residence age (TRes, the time difference between Nd depleted-mantle model age and the crystallization age) of c. 500 Ma from the Nd isotopes is proposed as the threshold distinguishing porphyry Cu ± Au ± Mo (TRes < 500 Ma) and Mo deposits (TRes > 500 Ma) in the CAOB. The coupled zircon Hf isotopes and crustal thickness reveal that the fundamental crustal architecture in the eastern and western CAOB had been built by the Late Permian and Late Carboniferous, respectively, highlighted by the converging trends of εHf(t) commencing at c.250 Ma in the eastern segment and c.300 Ma in the western segment of CAOB, indicating reworking and homogenizing of juvenile crust after collision. In the eastern CAOB, porphyry Cu ± Au ± Mo deposits were formed by juvenile materials in thin island arcs, while porphyry Mo deposits were formed by reworked materials in the thickened orogenic crust after c.250 Ma. In the western CAOB, porphyry Cu deposits in the Balkhash region during the Late Carboniferous were formed in thickened continental crust (generally > 40 km), genetically linked to the culmination of world-wide magmatic addition rates (MARs) triggered by accelerated production of the juvenile crust, in contrast to the porphyry Cu ± Au ± Mo deposits formed in thin island arc (generally < 40 km) during the Early Paleozoic. This study tests the zircon ΔFMQ as proxy for f O2, and zircon Eu/Eu* and whole-rock V/Sc ratios as proxy for water content. It highlights that whole-rock V/Sc ratio is a favorable index for the Cu tonnages of porphyry Cu ± Au ± Mo deposits, and that the distinct porphyry-type mineralization in the CAOB is controlled by the crustal evolution reflected by crustal composition and thickness. [ABSTRACT FROM AUTHOR]

The role of subducting oceanic crust-derived fluids in generating mafic arc magmatism has been widely documented. However, the subducting oceanic crust is generally composed of basaltic igneous crust and seafloor sediment, which may give rise to different compositions of liquid phases causing metasomatism of the mantle wedge. Because of the similarity in enrichment of fluid-mobile incompatible elements in the two sources of subduction zone fluids, it has been a challenge to distinguish between them when studying the products of mafic arc magmatism. This difficulty is overcome by a combined study of whole-rock Li isotopes and zircon O isotopes in addition to whole-rock major-trace elements and Sr–Nd–Hf isotopes in Late Paleozoic mafic igneous rocks from southwestern Tianshan in western China. Zircon U–Pb dating yields consistent ages of 313 ± 3 Ma to 305 ± 1 Ma for magma crystallization. The mafic igneous rocks exhibit arc-like trace element distribution patterns and depleted whole-rock Nd–Hf isotopes but slightly high (87Sr/86Sr)i ratios of 0·7039– 0·7057. They also show positive zircon εHf(t) values and slightly higher zircon δ18O values of 5·2–7·6‰. There are covariations of whole-rock Sr isotopes with Th/La and Rb/Nb ratios, indicating a contribution from terrigenous sediment-derived fluids to their mantle source in addition to basaltic igneous crust-derived fluids. Based on the slightly higher zircon δ18O values but variably lower whole-rock δ7Li values of -0·8 to 3·5‰ for the target rocks than those of mantle respectively, both altered oceanic basalt- and terrigenous sediment-derived fluids are identified in the mantle source of these mafic igneous rocks. Model calculations for trace elements and Sr–Nd–Li isotopes further confirm that the geochemical compositions of these mafic igneous rocks can be explained by chemical reaction of depleted MORB mantle peridotite with the mixed fluids to generate ultramafic metasomatites at subarc depths. Therefore, chemical metasomatism of the mantle wedge is a key mechanism for the incorporation of crustal components into the source of arc-like mafic igneous rocks above oceanic subduction zones. [ABSTRACT FROM AUTHOR]

This paper presents the first detailed studies on the petrology of abyssal peridotites and related fault rocks recovered from an oceanic core complex (OCC) in the southern part of the Central Indian Ridge using the submersible SHINKAI 6500 of the Japan Agency for Marine–Earth Science and Technology. Less deformed, statically serpentinized peridotites were recovered from the ridge-facing slope, whereas highly deformed rocks were recovered from sheet-like structures on the top surface of the OCC. The top surface of the OCC is interpreted to be the main detachment fault. The serpentinized peridotites are consistent with an origin as residues after moderate degrees (13–15%) of partial melting; these were later chemically modified as a result of the infiltration of evolved melts of probable granitic composition resulting in the formation of leucocratic veins. The deformed rocks from the detachment fault are divided into talc-rich and chlorite-rich parts, probably formed as a result of interaction of hydrothermal fluids with peridotite and gabbro precursors along the detachment fault, respectively. Deformation and alteration were locally concentrated along the detachment fault, resulting in mechanical mixing of both altered gabbros and serpentinized peridotites in the deformed rocks during the exhumation of the OCC associated with long-lived fault activity. Our results reveal that gabbros and peridotites are tectonically exposed in oceanic core complexes on the seafloor along the intermediate-spreading CIR, as well as in slow-spreading regions. Fluid-mobile elements such as Li, Rb, Ba, Pb, Sr and U are higher in serpentines than their precursor mantle minerals. The uranium content in serpentine is variable but is abundant in the outermost margin of the precursor minerals. The trace element compositions of serpentine appear to have been continuously changed along with changes in the chemistry of the hydrothermal fluids as temperature decreased. Fluid-mobile elements were thus added and/or leached out during the serpentinization of the peridotite combined with later seafloor weathering. [ABSTRACT FROM AUTHOR]

Strongly peraluminous granites (SPGs) form through the partial melting of metasedimentary rocks and therefore represent archives of the influence of assimilation of sedimentary rocks on the petrology and chemistry of igneous rocks. With the aim of understanding how variations in sedimentary rock characteristics across the Archean–Proterozoic transition might have influenced the igneous rock record, we compiled and compared whole-rock chemistry, mineral chemistry, and isotope data from Archean and Paleo- to Mesoproterozoic SPGs. This time period was chosen as the Archean–Proterozoic transition broadly coincides with the stabilization of continents, the rise of subaerial weathering, and the Great Oxidation Event (GOE), all of which left an imprint on the sedimentary rock record. Our compilation of SPGs is founded on a detailed literature review of the regional geology, geochronology, and inferred origins of the SPGs, which suggest derivation from metasedimentary source material. Although Archean and Proterozoic SPGs are similar in terms of mineralogy or major-element composition owing to their compositions as near-minimum melts in the peraluminous haplogranite system, we discuss several features of their mineral and whole-rock chemistry. First, we review a previous analysis of Archean and Proterozoic SPGs biotite and whole-rock compositions indicating that Archean SPGs, on average, are more reduced than Proterozoic SPGs. This observation suggests that Proterozoic SPGs were derived from metasedimentary sources that on average had more oxidized bulk redox states relative to their Archean counterparts, which could reflect an increase in atmospheric O2 levels and more oxidized sedimentary source rocks after the GOE. Second, based on an analysis of Al2O3/TiO2 whole-rock ratios and zircon saturation temperatures, we conclude that Archean and Proterozoic SPGs formed through partial melting of metasedimentary rocks over a similar range of melting temperatures, with both 'high-' and 'low-'temperature SPGs being observed across all ages. This observation suggests that the thermo-tectonic processes resulting in the heating and melting of metasedimentary rocks (e.g. crustal thickening or underplating of mafic magmas) occurred during generation of both the Archean and Proterozoic SPGs. Third, bulk-rock CaO/Na2O, Rb/Sr, and Rb/Ba ratios indicate that Archean and Proterozoic SPGs were derived from partial melting of both clay-rich (i.e. pelites) and clay-poor (i.e. greywackes) source regions that are locality specific, but not defined by age. This observation, although based on a relatively limited dataset, indicates that the source regions of Archean and Proterozoic SPGs were similar in terms of sediment maturity (i.e. clay component). Last, existing oxygen isotope data for quartz, zircon, and whole-rocks from Proterozoic SPGs show higher values than those of Archean SPGs, suggesting that bulk sedimentary 18O/16O ratios increased across the Archean–Proterozoic boundary. The existing geochemical datasets for Archean and Proterozoic SPGs, however, are limited in size and further work on these rocks is required. Future work must include detailed field studies, petrology, geochronology, and constraints on sedimentary source ages to fully interpret the chemistry of this uniquely useful suite of granites. [ABSTRACT FROM AUTHOR]

Igneous complexes with a wide variety of lithologies in continental magmatic arcs provide a critical insight into the composition and formation mechanism of continental crust. We report, for the first time, a systematic dataset for the petrology, mineralogy, geochronology, and geochemistry of the Cuijiu Igneous Complex in the eastern Gangdese Arc of southern Tibet. This complex includes a wide variety of rocks from ultramafic–mafic and felsic cumulates to mafic to felsic non-cumulate plutonic rocks. Cumulate and non-cumulate rocks can be distinguished by combining petrography and bulk-rock composition. Titanite and zircon U–Pb dating of 15 samples shows that the varying lithologies within this complex crystallized contemporaneously at c. 200 Ma. The non-cumulate plutonic rocks were formed through hornblende-dominated fractional crystallization from cogenetic primitive basaltic magmas, which were derived from partial melting of a mantle wedge metasomatized by subduction-related fluids. The ultramafic–mafic and felsic cumulates have similar isotopic compositions and crystallization order of minerals to the non-cumulate plutonic rocks, representing complementary compositions of the fractional crystallization processes. Petrological and geochemical signatures call upon two-step fractional crystallization as the dominant process to generate the Gangdese Arc during the Early Mesozoic. The assemblage and crystallization order of minerals, as well as Al-in-Hb geobarometry, reveal that the c. 200 Ma Cuijiu Igneous Complex crystallized at a range of pressures between 10 and 2·5 kbar. This result allows us to propose that the Early Mesozoic Gangdese crust had a normal thickness (∼35 km), in which the middle to lower part (20–35 km) was dominated by hornblende-rich rocks with minor diorites and tonalites intruding metamorphosed Late Paleozoic igneous rocks, followed upward by a thick granitoid batholith (4–20 km) and by volcano-sedimentary rocks (0–4 km). [ABSTRACT FROM AUTHOR]

In situ trace element analysis of cumulus minerals may provide a clue to the parental magma from which the minerals crystallized. However, this is hampered by effects of the trapped liquid shift (TLS). In the Main Zone (MZ) of the Bushveld Complex, the Ti content in plagioclase grains shows a clear increase from core to rim, whereas most other elements [e.g. rare earth elements (REE), Zr, Hf, Pb] do not. This is different from the prominent intra-grain variation of all trace elements in silicate minerals in mafic dikes, which have a faster cooling rate. We suggest that crystal fractionation of trapped liquid occurred in the MZ of Bushveld and the TLS may have modified the original composition of the cumulus minerals for most trace elements except Ti during slow cooling. Quantitative model calculations suggest that the influence of the TLS depends on the bulk partition coefficient of the element. The effect on highly incompatible elements is clearly more prominent than that on moderately incompatible and compatible elements because of different concentration gradients between cores and rims of cumulate minerals. This is supported by the following observations in the MZ of Bushveld: (1) positive correlation between Cr, Ni and Mg# of clinopyroxene and orthopyroxene; (2) negative correlation between moderately incompatible elements (e.g. Mn and Sc in clinopyroxene and orthopyroxene; Sr, Ba and Eu in plagioclase); but (3) poor correlation between highly incompatible elements and Mg# of clinopyroxene and orthopyroxene or An# of plagioclase. Modeling suggests that the extent of the TLS for a trace element is also dependent on the initial fraction of the primary trapped liquid, with strong TLS occurring if the primary trapped liquid fraction is high. This is supported by the positive correlation between highly incompatible trace element abundances in cumulus minerals and whole-rock Zr contents. We have calculated the composition of the parental magma of the MZ of the Bushveld Complex. The compatible and moderately incompatible element contents of the calculated parental liquid are generally similar to those of the B3 marginal rocks, but different from those of the B1 and B2 marginal rocks. For the highly incompatible elements, we suggest that the use of the sample with the lowest whole-rock Zr content and the least degree of TLS is the best approach to obtain the parental magma composition. The heavy REE contents of the magma calculated from orthopyroxene are similar to those of B3 rocks and lower than those of B2 rocks. The calculated REE contents from clinopyroxene are generally significantly higher than for B2 or B3 rocks, and those from plagioclase are in the lower level of B2, but slightly higher than for B3. However, the calculated REE patterns for both clinopyroxene and plagioclase show strong negative Eu anomalies, which are at the lower level of the B2 field and within the B3 field, respectively. We suggest that Eu may be less affected by TLS than other REE owing to its higher bulk compatibility. Based on this and the fact that the calculated REE contents of the parental magma should be higher than the real magma composition owing to some degree of crystal fractionation and TLS, even for the sample with the lowest amount of trapped liquid, we propose that a B3 type liquid is the most likely parental magma to the MZ of the Bushveld Complex. In the lowermost part of the MZ, there is involvement of the Upper Critical Zone (UCZ) magma. [ABSTRACT FROM AUTHOR]

The Alcurra Dolerite in the Musgrave Province, central Australia, is part of the c. 1075 Ma Warakurna large igneous province (LIP), which is interpreted to have been emplaced contemporaneously with intracontinental rifting. The Alcurra Dolerite in the eastern Musgrave Province comprises two types of continental tholeiite. Dominant Group 1 dolerites are mainly magnesian tholeiites, whereas subordinate Group 2 dolerites are normal tholeiites. These two groups have distinct chondrite-normalized rare earth element (REE) patterns, primordial mantle-normalized trace element patterns, and incompatible element ratios (e.g. Th/Yb, Nb/Yb, La/Yb and Zr/Y). Both groups are low-Ti and low-Zr, but Group 1 dolerites have higher Ti/Zr (>60) and Ti/Y (>310) values than those of Group 2. Group 1 mainly comprises olivine-microgabbros, and is volumetrically dominant, whereas Group 2 is proportionally minor and includes noritic-microgabbros. Dolerites from both groups plot in discrete fields in 143Nd/144Nd versus 147Sm/144Nd space, along a mixing trend between chondritic or depleted mantle and the c. 1·59 Ga Musgravian basement. Group 1 dolerites have low Rb, Th and K2O contents that preclude their contamination by Musgravian continental crust. They also have incompatible element ratios that overlap with mid-ocean ridge basalt or primitive mantle. Group 2 dolerites have more negative ɛNd values and are also the more incompatible element enriched group; they may have, to some extent, been directly contaminated by Musgravian basement. Low concentrations of light REE (LREE) in Group 1 dolerites indicate a moderate to high percentage of partial melting of a relatively depleted source. Mixing this partial melt with a small proportion of melt derived by a moderate percentage of partial melting of a more incompatible element enriched mantle source could have resulted in the low (La/Sm)N ratios and low absolute La contents seen in these dolerites. Group 1 is divided into two subgroups (1A and 1B) on the basis of LREE abundances and Nb/Yb ratios. These two subgroups may reflect different percentages of partial melting of the depleted source. Petrogenetic interpretations for the Alcurra Dolerite of the eastern Musgrave Province must address published geophysical evidence for asthenospheric mantle upwelling and underplating in the Musgrave Province, and for contemporaneous low- and high-Ti Alcurra Dolerites indicative of a plume to the west where they are associated with Giles Suite layered intrusions. The large proportion of probable asthenosphere-derived melt in the petrogenesis of the Group 1 dolerites from the eastern Musgrave Province indicates either substantial heat transfer, or significant decompression in the mantle. The Warakurna LIP could result from a complex interaction between a plume and mantle upwelling. [ABSTRACT FROM AUTHOR]

The occurrence of numerous chromitite layers within the Rustenburg Layered Suite of the Bushveld Complex, South Africa, has been widely cited in models to explain the origin of the igneous layering. Most hypotheses are based around the principle of episodic replenishment of the magma chamber. Chromitite layers occur in both the Lower Critical Zone (LCZ), which is wholly ultramafic, and the Upper Critical Zone (UCZ), where they are part of repetitive units that include pyroxenite (± minor harzburgite), norite and anorthosite. The UCZ also reveals stringers of disseminated chromite, which, despite being only a few millimetres thick, are laterally very persistent. We investigate chromite stringers from the uppermost part of the UCZ at Winnaarshoek in the Eastern Limb of the intrusion, where they are preferentially located on contacts between layers of pyroxenite and anorthosite. Stringers overlain by anorthosite are of particular interest as they are located in the centre of units and are unlikely to have developed from replenishment by basal flows of magma. The uppermost of the two chromite stringers associated with the Merensky Reef is unusual as it is located wholly within a layer of pyroxenite, and does not demarcate a lithological contact. Stringers are categorized as Type III chromite to distinguish them from the thicker layers of chromitite, Type I (in the LCZ) and Type II (in the UCZ). The Cr-spinel in the stringers is characterized by relatively low Cr/Fe ratios and is associated with recrystallized, unusually calcic, plagioclase as the principal silicate phase. Accessory phases include rutile, corundum, zircon and baddeleyite, in addition to base-metal sulphides and PGM. The origin of Type III stringers is ascribed to replenishment by sheets of picritic magma injected, not as basal flows, but as sills into an earlier-formed crystalline substrate dominated by well-defined layers of norite and anorthosite. In the framework of this hypothesis, the units that characterize the UCZ are, therefore, not differentiation cycles: the ultramafic components crystallized from U-type (picritic) magmas and the norite–anorthosite from A-type (tholeiitic) magmas. The two components of the units were emplaced non-sequentially, but the ultramafic rocks (± chromitite layers and/or chromite stringers) still occur in stratigraphic sequence relative to each other. Type III stringers developed on either the lower or upper contacts of the picritic magma sheets, dependent on whether they were emplaced above or below a layer of anorthosite. Nucleation of Cr-spinel was triggered by contamination of the picritic magma by partial melting of the anorthosite. Melting of low-temperature oikocrysts of pyroxene and interstitial plagioclase produced a thin boundary layer of melt mush. This boundary layer achieved rapid saturation in Cr-spinel, in part owing to Cr2O3 released from the pyroxene oikocrysts. Heat was insufficient to melt the main framework of plagioclase crystals in the anorthosite or the noritic wall-rocks. The different occurrences of chromite in the Bushveld should not be aggregated into a single overarching hypothesis. Type III stringers are probably an entirely different phenomenon from the thicker layers and provide corroborating evidence of the sill hypothesis. [ABSTRACT FROM AUTHOR]

The 4·0–3·6 Ma Don Manuel igneous complex (DMIC), central Chile, provides a window into igneous processes involved in magma genesis associated with porphyry-style copper mineralization. This study uses petrographic, petrological, geochemical and isotopic data to examine the evolution of magmas from the mid- to lower-crustal source region to shallow emplacement. The data provide evidence for progressive oxidation of magma during differentiation and ascent, fractionation of Cl from S through degassing, and the late-stage, near-solidus removal of Cl from the system. Magmas of basaltic andesite to rhyolite composition were produced by polybaric differentiation of hydrous parental mafic magmas. Variations in crustal differentiation depths led to variable suppression of plagioclase saturation that is recorded in distinctive strontium versus anorthite evolution patterns. Hydrous, derivative magmas generated over a wide range of pressures were episodically emplaced into the shallow crust at depths between 3·5 and 5 km. Intermediate porphyry dikes closely associated with copper mineralization contain diverse crystal cargoes indicating significant magma mixing. These crystal cargoes represent samples of crystal mush entrained from different depths, as well as crystals originating in different magmas and crystals grown in situ from hybridized magmas. Mafic enclaves containing plagioclase and amphibole compositions that match those of the basaltic andesites occur within biotite tonalite, testifying to magma mingling during ascent. Sulfur and chlorine contents of apatite within the different DMIC units record variable degassing and decoupling of volatile components with sulfur showing variations of three orders of magnitude compared with one order of magnitude for chlorine. The hypabyssal nature of the DMIC affords a detailed, integrated record of magmatic differentiation processes occurring within trans-crustal magmatic systems of the sort thought to characterize many crustal arc settings and play a fundamental role in driving porphyry-style copper mineralization. [ABSTRACT FROM AUTHOR]

The origin of chromitites in the Bushveld Complex has been attributed to two principal mechanisms: (1) gravity-controlled settling of chromite onto the chamber floor from magma that was saturated in chromite, either initially or owing to some internal process; or (2) gravity- and size-controlled separation of chromite from coexisting olivine and orthopyroxene within crystal-rich slurries, either formed directly within the chamber or brought into the chamber from some deep staging reservoirs. Here we present field observations from potholes, roughly circular structures in which footwall rocks were removed by magmatic erosion, that rule out both approaches. A key observation is that chromitites drape the irregular margins of potholes, even where they are vertical or overhanging. These relationships eliminate both early settling of chromite from the overlying magma and late mechanical segregation of chromite within cumulates as viable hypotheses. In addition, thick chromitites commonly consist of several texturally and compositionally distinct sublayers that are locally separated by thin partings of silicate rocks. The absence of thick sequences of intervening silicate rocks from which chromite may have been separated to form these sublayers refutes an origin from crystal slurries. Transgression of chromitite-orthopyroxenite units by hanging-wall rocks excludes the origin of chromitites from crystal slurries that intrude as late-stage sills into pre-existing cumulates. The field relationships appear to be compatible only with the emplacement of superheated, dense magma along the temporary base of the chamber that led to intense melting and dissolution of the preexisting floor cumulates, followed by the in situ crystallization of chromite directly on the irregular chamber floor. Chromitites of differing thicknesses are produced, according to the volume of the multiple replenishments. This model involving in situ crystallization of basal layers of magmas, which are saturated with chromite on cooling in the chamber, can be extended to explain the origin of chromitites in other layered intrusions. [ABSTRACT FROM AUTHOR]

A primary goal of igneous petrology is to understand the temperature range of crystallization for large intrusive bodies. Well-preserved layered intrusions, with their more or less stratigraphic mineral and compositional evolution, offer both a challenge and an opportunity to understand their thermometry. The challenge comes in a petrographic understanding of the appropriate rocks to study; the opportunity arises in the evolution of the intrinsic stratigraphic diversity. Whereas the crystallization temperatures of the troctolitic Lower Zone of the Kiglapait intrusion were determined experimentally in our laboratory at the liquidus of successively more evolved compositions, the temperatures of the Upper Zone are now determined at the solidus of adcumulate rocks. Ideal adcumulates have no zoning in plagioclase and so must have crystallized isothermally by rejection of interstitial solute to the main magma. The solidus thermometry of rock powders at pressure avoids any prospect of metastability. Here the solidus temperature was found in a piston-cylinder apparatus at 5 kbar. Melting experiments were made on rock powders held for 2 h or more in graphite capsules. Melt volumes were estimated visually in reflected light and by SEM, and scaled against temperature to determine the solidus at zero melt. The previously determined Lower Zone temperature limit and the first of the new Upper Zone determinations are the same at 1200°C, 5 kbar. The new results for temperature, plotted against stratigraphic progress, form a concave-up curve to a flat end point at 1010°C, 5 kbar, and 1000°C referred to 3 kbar. The entire magmatic history of the intrusion spans 250°C over a pressure gradient of 5·2-2·8 kbar and a duration of near 1 Myr of crystallization. [ABSTRACT FROM AUTHOR]

Volatiles play an important role in magmatic and volcanic processes. Melt inclusions are a powerful tool to study pre-eruptive volatiles, but interpretation of their H2O and CO2 variations can be difficult. The H2 O and CO2 contents of melt inclusions from nine basanites from Hut Point Peninsula, Mt Terror and Mt Bird on Ross Island, Antarctica, were studied to understand better the behavior of volatiles in the magmas and to provide insight into magma transport and storage processes. Ninety olivine-hosted (Fo78-88) melt inclusions were examined along with the composition of the associated bulk-rock samples. The H2 O (0.4-2.0wt %) and CO2 (0.2-9wt %, or 0.2-1-8wt % after correction for vapor bubbles) variations in the melt inclusions cannot be explained by equilibrium degassing. A strong correlation between melt inclusion radius and H2 O content for Hut Point samples indicates that diffusive loss of Hþ has occurred. Based on vapor saturation pressure trends, it is inferred that a magma reservoir existed below Hut Point at a depth of ∼18 km and by modeling diffusive loss of H+ for melt inclusions, it is shown that the magmas ascended from this depth in less than a year. Melt inclusions from Terror and Bird lack evidence of diffusive loss of H+ and there are no strong chemical indicators of CO2 fluxing. Compositional heterogeneities in melt inclusions indicate that magma mixing occurred, making it difficult to interpret H2 O and CO2 trends. Melt inclusions from these volcanoes were entrapped polybarically, inconsistent with entrapment in a single storage region. Published analyses of 54 olivine-hosted (Fo53-83) melt inclusions in seven samples from Erebus volcano on Ross Island were re-examined for comparative purposes. Low H2 O (∼0.1wt %) and CO2 (0-0.2wt %) contents and the evolved compositions of these indicate that Erebus magmas undergo shallow (<6 km) crystallization before eruption, probably in a shallow storage region. Magmas from the surrounding volcanoes show no sign of shallow storage. [ABSTRACT FROM AUTHOR]

In this study we examined Meso- to Neoarchean granitoids from the North Caribou Terrane within the Western Superior Province, Canada. Petrology, whole-rock geochemistry, zircon and titanite geochronology, and zircon trace element concentrations were analyzed. U-Pb ages from zircon and titanite are between 262 and 313 Ga. Although most of the granitoids in this study appear to record a complex magmatic history, about a third contain features that we interpret to be a result of hydrothermal alteration. Notable traits in rocks that contain altered zircons include K-feldspar overgrowths on plagioclase and compositional zoning in titanite. The altered zircon material itself occurs as CL-bright resorption shadows showing distinct chemical changes, including lower Th/U values and elevated LREE concentrations. The isotopic ages of the rims on the altered zircons (2835 Ma, 2760-2678 Ma) are similar to coexisting U-Pb titanite ages and regional U-Pb titanite and zircon ages. We propose that during the hydrothermal event, the affected areas of zircon reequilibrated with fluid, which promoted Pb loss, resetting the isotopic clock. These results suggest that zircon rims might be useful for dating hydrothermal fluid flow episodes in addition to magmatic events and that a multi-element approach is useful for distinguishing ages that are magmatic from those that have been isotopically disturbed owing to alteration. [ABSTRACT FROM AUTHOR]

Adakites are unusual felsic igneous rocks commonly associated with asthenospheric slab window opening or fast subduction of a young (<25?Ma) oceanic plate that may allow slab melting at shallow depths. Their genesis has been extensively debated, as they are also observed in other geodynamic settings where thermal models do not predict slab melting in the fore-arc region. Here, we present a new approach that provides new constraints on adakite petrogenesis in hot subduction zones (e.g. the Philippines) and above an asthenospheric window (e.g. Baja California, Mexico). We use amphibole compositions to estimate magma storage depths and the composition of the host melts to test the hypothesis that adakites are pristine slab melts. We find that adakites from the Philippines and Baja California fore-arcs formed in two distinct petrogenetic scenarios: in the Philippines, water-rich mantle melts stalled and crystallized within lower and upper crustal magma storage regions to produce silica-rich melts with an adakitic signature; in Baja California, slab melts that percolated through the mantle wedge mixed or mingled with water-rich mantle melts within a lower crustal (~30 km depth) magma storage region before stalling in the upper arc crust (~7-15 km depth). Alternatively, the Baja California adakites may represent mixing products between high-pressure differentiated mantle melts and mantle melts in a lower crustal magma reservoir, periodically refluxed by mantle melts. Thus, slab melting is not necessarily required to produce an adakitic geochemical fingerprint in hot subduction zones. The hot downgoing plate may cross the 'adakitic window' and melt in specific geodynamic settings such as the opening of a slab tear, as beneath Baja California. [ABSTRACT FROM AUTHOR]

A combined study of zircon U-Pb ages, whole-rock chemistry, Sr-Nd isotopes and in situ Lu-Hf isotopic ratios in zircons was carried out on Permian monzogranites and mafic microgranular enclaves (MME) and coeval massive gabbros in the northern Alxa block, North China. The data obtained were used to constrain magma sources and petrogenetic processes involved in the generation of this igneous suite. Zircon U-Pb dating yields ages of 271 ± 1 Ma, 270 ± 1 Ma and 276-270 Ma for the monzogranites, MME and massive gabbros, respectively. Two populations of MME, gabbroic (SiO2 <49 wt %) and dioritic (SiO2 >53 wt %) enclaves, are identified. They represent mafic to intermediate magmas quenched in a partially crystallized granitic (sensu lato) host; evidence to support this conclusion includes their fine-grained textures, sinuous margins and diffuse contacts with the host monzogranites. Back-veins and xenocrysts of quartz and plagioclase, as well as various disequilibrium textures and mineral assemblages, indicate mingling or mixing processes. The two magma systems, mafic and felsic, have broadly similar isotopic characteristics with whole-rock initial 87Sr/86Sr(i) ratios ranging from 0·7075 to 0·7077 in the monzogranite host and from 0·7067 to 0·7069 in the MME, with eN d(t) values ranging from -10·2 to -12·4 in monzogranites and from -8·2 to -9·9 in the MME. Zircon eHf(t) values of the monzogranites, gabbroic enclaves and massive gabbros show a wide range and significant overlap from -1·2 to -15·2, -4 to -13·3 and -5·4 to -19·5, respectively; the maximum frequency value of the Hf model age is almost coincident with the whole-rock Nd model age. Mafic, gabbroic rocks similar in composition to some enclaves form layered synplutonic intrusions several metres in thickness and more than 100 m in lateral extent. A mixing test based on mass balance for whole-rock major element compositions reveals that mixing was an efficient process between two coeval magmas. The fraction of felsic magma involved in the hybrid rocks ranged from 0·19-0·29 in the dioritic enclaves to 0·84 in granodiorite and good linear fits (r² > 0·9) are obtained using the average composition of gabbroic enclaves and the most felsic monzogranite as end-members. Although the monzogranites and enclaves may be derived from distinct magma sources, they share similar isotopic signatures, pointing to interaction processes in the source region. The combination of information from geochronology, petrology, whole-rock geochemistry and isotopic compositions leads us to conclude that the processes of hybridization and magma mixing were effective at both the level of emplacement in the shallow crust and at depth in the magma source region. Hybridization in a source region within the lithospheric mantle, involving mantle and crustal source rocks, produced magma bimodality with strong geochemical affinities between end-members and clear calc-alkaline arc signatures, compatible with a subduction setting. A plausible subduction erosion plus relamination model, which differs from classical models based on mafic magma underplating, is proposed. Accordingly, the Yamatu monzogranites are argued to have been generated from granitic melt segregated and ponded in buoyant silicic diapirs, which formed by melting of subducted mélanges in the lithospheric mantle and eventually relaminated to the lower crust. They represent the melts that metasomatized the mantle region during a pre-Permian subduction event. The massive gabbros were formed by decompression melting of the previously metasomatized mantle. The gabbroic enclaves and gabbro layers of the Yamatu pluton are interpreted as magmas formed by decompression melting of this modified hydrated mantle. The dioritic enclaves represent hybrid liquids generated from reaction between granitic melts, which were derived from subducted mélanges, and the hydrated mantle or melts derived from it. [ABSTRACT FROM AUTHOR]

Dunite bands and dikes in ophiolitic mantle peridotites are interpreted as fossil melt channels within the suboceanic mantle. Concordant dunite bands (i.e. fossil melt channels transposed by outward transportation from the ridge axis via horizontal mantle flow) are particularly important as they possibly represent the melt channels through which the parental melts of mid-ocean ridge basalt (MORB) were transported to shallower depths beneath the paleo-ridge axis. We conducted field observations and sampling of concordant dunite bands (CDB) and their host harzburgite at selected outcrops covering a wide depth range in the mantle section along an inferred paleo-ridge segment in the northern to central part of the Oman ophiolite. The CDB increase in thickness and decrease in frequency upward. They are thicker and more frequent in the centre of the segment than near the segment ends when compared at the same stratigraphic level. The CDB consist mostly of olivine with minor spinel and very rare amounts of pyroxene. Clinopyroxene has a small grain size and an interstitial position relative to olivine. The constituent minerals in the CDB and their host harzburgite were analyzed by electron microprobe for major elements and by laser ablation inductively coupled plasma mass spectrometry for trace elements. Most of the CDB have refractory major element mineral compositions, such as high Fo [100 x Mg/(Mg / Fe)] in olivine (>90.5), high Cr# [Cr/(Cr / Al)] in chromian spinel (>0.50), and low Al2O3 (<3.5 wt %) in clinopyroxene. Chondrite-normalized trace element patterns of clinopyroxene in the host harzburgites consistently show a gentle decrease from heavy REE (HREE) to middle REE (MREE) and a sharp decrease from MREE to light REE (LREE) (= highly depleted), but those in the CDB show weaker LREE depletion, which is more variable depending on the stratigraphic level and position along the paleo-ridge segment. In contrast, the HREE concentrations in clinopyroxene in the CDB are higher than or similar to those of the host harzburgites. Trace element compositions of clinopyroxene in the CDB and their host harzburgites are evaluated with a one-dimensional, steady-state, opensystem decompressional melting-reaction model. The modeling results suggest that an LREE-enriched melt generated at high pressure was transported upwards through melt channels to the shallow mantle (up to the Moho transition zone), where it mingled with highly depleted melts accumulated from fractionally melted peridotites to generate normal (N)-MORB-like melts. The mantle started upwelling (= melting) in the garnet stability field in the segment centre, but either in the garnet or in the spinel stability field near the segment ends. This suggests a variation of geothermal gradient along the paleo-ridge segment: higher in the segment centre and lower near the segment ends. This inference is supported by the presence of thicker (up to 250 cm) CDB as well as more frequent occurrence of CDB in the segment centre than near the segment end and by the geochemical evidence for chromatographic N-MORB-like melt percolation into the host peridotite only in the uppermost horizons near the segment ends. [ABSTRACT FROM AUTHOR]

Pyroxenite layers embedded within peridotite represent widespread lithological mantle heterogeneities and are potential components in the mantle source of many oceanic basalts. They can be generated by a variety of magmatic and metamorphic processes. However, in most natural samples (especially in ultramafic massifs), their primary characteristics are partially or completely erased by later processes (e.g. metamorphism, metasomatism or partial melting). Here we investigate a suite of pyroxenites from the External Liguride Jurassic ophiolites (Northern Apennines, Italy). These are spinel-bearing websterites and clinopyroxenites, partially recrystallized under plagioclase-facies conditions, and occur as centimetre-scale layers parallel to the tectonite foliation of their host peridotites. The pyroxenites have bulk-rock Mg-numbers from 74 to 88 and display rather constant light rare earth element (LREE) depletion relative to middle REE (MREE) (LaN/SmN = 0.15-0.35), but variable MREE-heavy REE (HREE) fractionation, with some having markedly positive HREE slopes (SmN/YbN = 0.30-0.96). The HREE enrichment, coupled with high Zr and Sc contents in clinopyroxene porphyroclasts from spinel-bearing domains, provides strong evidence that garnet was present in the precursor mineral assemblages. Mass-balance calculations suggest that the pyroxenites originally contained up to about 40 vol. % garnet, indicating that they originated by segregation of melts at relatively high pressure (P > 1.5 GPa). The parental melts of the pyroxenites have reacted to some extent with the host peridotite during mantle infiltration. Lack of olivine in the primary mineral assemblage and the presence of orthopyroxene-rich rims along the contact with the wall-rock peridotites suggest that the pyroxenites crystallized from silica-rich melts. These probably had REE patterns and Sr-Nd isotope compositions similar to those of enriched mid-ocean ridge basalt. We propose that the pyroxenites originated from melts derived from a hybrid eclogite-bearing peridotite source, which subsequently reacted with their host peridotite to form 'secondary pyroxenites'. The existence of such pyroxenites has been invoked in current models of basalt petrogenesis. During later decompression, the pyroxenites experienced recrystallization at spinel-facies conditions, at 1.2-1.5 GPa and minimum temperatures of 950-1000°C, and partial re-equilibration in the low-pressure plagioclase facies. The latter event is dated by internal Sm-Nd isochrons at 178 (±8) Ma and is associated with Mesozoic exhumation during extension of the Tethys lithosphere. [ABSTRACT FROM AUTHOR]

The article discusses various reports published within the issue, including one by Obata and Takazawa on the compositional model of Horoman peridotite, another by Zimmerman and Kohlstedt on the diffusional and dislocation deformation in molten mantle and one by Brueckner and colleagues on the structure of garnet-peridotites and puroxenites.

We have recently discovered several chromitite dykes that cut a sequence of alternating layers of dunite and chromitite in the lower part of the Monchegorsk Layered Intrusion, Russia. The chromitite dykes are up to 18cm wide and several metres long, have sharp boundaries with the host dunite, are fine-grained and contain up to 80-85% chromite. The dykes are internally zoned, with chromite showing an inward decrease in FeO and an increase in MgO and Mg-number [Mg/(Mg+Fe2+)]. Most olivine crystals in dunite adjacent to chromitite dykes are also reversely zoned and their rims show an increase in Mg-number towards contacts with the chromitite dykes. The dykes and layers differ in their platinum-group element (PGE) patterns, with the former being relatively enriched in Os, Ir and Ru and depleted in Pt, Pd and Rh. These differences preclude the chromitite dykes being remobilized chromitite layers. Similarly, the dykes cannot have formed from chromite-rich slurries emplaced into the evolving magma chamber. Gravity-induced separation of chromite from such slurries in feeder conduits cannot result in such a high concentration of chromite. Also, the lack of chromitite layers higher up in the layered series of the intrusion is not compatible with this idea. We propose that chromitite dykes resulted from the prolonged flow of chromite-saturated magma that crystallized chromite in situ along the walls of conduits. The high abundance of chromite in the dykes can be explained by the ability of magma flowing through channels to displace interstitial liquid from growing chromite. The zoning in the dykes and reversely zoned wall-rock olivine can be attributed to postcumulus interaction between chromite in dykes and olivine in the adjacent dunite, a process not fully understood but thought to require a film of trapped liquid. We infer that in situ crystallization of chromite from replenishing chromitesaturated magma may be a viable origin of massive chromitite in layered intrusions. [ABSTRACT FROM AUTHOR]

Well-preserved primary magmatic zonation is observed in the harzburgite-hosted chromitites in the central part of the Uitkomst Complex in South Africa. The complex represents a magmatic conduit system of Bushveld affinity and age. Stratigraphic changes in chromite composition suggest that the chromitites were formed from pulses of incrementally more primitive, Cr-rich melts that precipitated chromite with progressively higher Cr2O3 (from 44 to 55% Cr2O3) and MgO (from 9 to 12% MgO), and lower TiO2 contents from the base upwards. This reverse compositional trend is believed to be part of a major reverse trend of increasing Mg# in both olivine and whole-rock compositions through the entire ultramafic section of the complex. The lower part of chromitites was formed from a contaminated melt that had chemically interacted with and replaced host-rock dolomites, resulting in crystallization of chromite with low Mg (as low as 0.5% MgO), and high Ti (up to 4% TiO2) contents. The preservation of chemical trends suggests that the precipitation of chromite and olivine occurred 'onstage' in an open system; this is not consistent with either a cumulate concept or the supply of a magmatic slurry. AlphaMelts modelling shows that the melt needs to have a komatiitic composition to be capable of crystallizing olivine of Mg# 92, which forms the thick dunite lenses overlying the chromitite body. We propose a model for chromitite formation in magmatic conduits that has much in common with models conventionally proposed for the formation of podiform chromitites and komatiite-hosted chromitites, albeit that the Uitkomst chromite chemistry lies within the field of the most chemically primitive compositions found in layered intrusions such as the Lower Zone of the Bushveld Complex. [ABSTRACT FROM AUTHOR]

The Sierra Valle Fértil Complex of west-central Argentina represents a section of the Ordovician (~470 Ma) Famatinian arc and exposes a continuous, tilted crustal arc section ranging in depth from ~12 to 32 km (~4-8 kbar pressure). This arc section exposes the complete compositional architecture from ultramafic and mafic rocks to upper crustal granodiorites. Field and compositional data are presented to document the deep (~6-8 kbar) mafic complex of the Sierra Valle Fértil. The mafic complex is composed of many tens to hundreds of plutonic cumulate bodies in a complex and non-regular arrangement. There is no simple compositional, kinematic or age relationship between neighboring plutons throughout the section, as expressed by cumulate compositions, emplacement horizon, size, composition, texture or style of contact. Amphibole gabbronorites and mafic tonalites dominate, but norites, amphibole websterites, troctolites and minor anorthosites are present. Amphibole is common but always as a replacement phase, and is never observed undergoing subsequent dehydration melting. Hence there is no evidence that voluminous tonalites were produced by dehydration melting of mafic precursors. A field-based, cumulate-removal fractionation model is presented that produces the observed compositional variations in five steps. Isotopic compositions of Sr and Nd deviate significantly from primitive mantle values, indicating a crustal contribution; however, this hybridization appears to have played a minor role in the major element evolution of the mafic complex. We interpret this isotopic and elemental decoupling as a byproduct of prolonged, punctuated MASH (melting, assimilation, storage, homogenization) processes in the lower crust. Isotopes may be the only residual evidence of assimilation within the mafic zone. This requires that melt removal from the cumulates was extraordinarily efficient. [ABSTRACT FROM AUTHOR]

The Upper Critical Zone (UCZ) of the Bushveld Igneous Complex displays spectacular layering in the form of cyclic units comprising a basal chromitite layer overlain by a sequence of silicate cumulates in the order, from bottom to top, pyroxenite-norite-anorthosite. Electron microprobe and laser ablation inductively coupled plasma mass spectrometry analyses of chromite and silicate minerals in layers between the UG2 chromitite and the Merensky Reef reveal variations in major and trace element compositions that defy explanation with existing models of cumulate mineral- melt evolution. The anomalous features are best developed at sharp contacts of chromitite with adjacent anorthosite and pyroxenite cumulates. Here, chromite compositions change abruptly from high and constant Mg/(Mg+Fe2+) and Fe2+/Fe3+ ratios in chromitite layers to variable and generally lower values in chromite disseminated in silicate layers. Furthermore, the composition of disseminated chromites varies depending on the host silicate assemblage; for example, in Ti, V and Zn contents. Importantly, the abrupt change in chromite composition across the chromitite-silicate layer contacts is independent of the thickness of the chromitite layer and the estimated mass proportions of chromite to intercumulus liquid. Chemical variations in plagioclase are also abrupt and some are hard to reconcile with conventional models of re-equilibration with intercumulus liquid. Among those features is the decoupling of alkalis from other incompatible lithophile elements. In comparison with cumulus plagioclase, intercumulus poikilitic plagioclase in chromitite layers is enriched in rare earth elements but strongly depleted in equally incompatible Li, K and Rb. Strong alkali depletion is also observed in intercumulus pyroxene from ultramafic cumulates and chromitite layers. To explain these features, we propose a new model of post-cumulus recrystallization, which intensifies the modal layering in the crystal-liquid mush, producing the observed sequence of nearly monomineralic layers of chromitite, pyroxenite and anorthosite that define the cyclic units. The crucial element of this model is the establishment of redox potential gradients at contacts between chromite-rich cumulates and adjacent silicate layers owing to peritectic reactions between the crystals and intercumulus melt. Because basaltic melts are ionic electrolytes with Na+ as the main charge carrier, the redox potential gradient induces electrochemical migration of Na+ and other alkali ions. Selective mobility of alkalis can explain the enigmatic features of plagioclase composition in the cyclic units. Sodium migration is expected to cause remelting of previously formed cumulates and major changes in modal mineral proportions, which may eventually result in the formation of sharply divided monomineralic layers. The observed variations in ferric/ferrous iron ratios in chromite from the cyclic units and Fe distribution in plagioclase imply a redox gradient of the order of 0.9 log-units fO2, equivalent to a potential gradient of 60 mV. Preliminary estimates suggest that the resulting electrochemical flux of Na+ ions is sufficient to mobilize about one-third of the total Na content of a 1m thick mush layer within 10 years. The proposed electrochemical effect of post-cumulus crystallization is enhanced by the presence of cumulus chromite but, in principle, it can operate in any type of cumulates in which ferrous and ferric iron species are distributed unequally between crystalline and liquid phases. [ABSTRACT FROM AUTHOR]

The Franklin sills and dykes on Victoria Island in the Canadian Arctic represent the sub-volcanic plumbing system to the Natkusiak flood basalts, which are associated with the late Neoproterozoic (c. 723–716 Ma) break-up of Rodinia. The Lower Pyramid Sill (LPS) is the distal end of a sill complex that may be rooted in the Uhuk Massif, a major fault-guided magmatic feeder system. The LPS is unusual for a thin (c. 21 m), shallow, tholeiitic intrusion because it displays well-developed cumulate layering similar to that seen in large layered intrusions. The LPS has an aphanitic, olivine-phyric (c. 5%) Lower Chilled Margin (LCM), a (<1 m thick) dendritic, olivine-phyric Lower Border Zone (LBZ), a (c. 7 m thick) olivine-dominated (up to c. 55%) melagabbro–feldspathic-peridotite zone (OZ), a thin (c. 1 m) clinopyroxene-rich cumulate gabbro (CPZ) containing sector-zoned euhedral clinopyroxene, a (c. 10 m thick) doleritic gabbro zone (DZ), a (<1 m thick) aphyric, dendritic Upper Border Zone (UBZ) and an aphanitic, olivine-phyric (c. 5%) Upper Chilled Margin (UCM). Distinct compositional groups recognized in olivines from the OZ can be associated with specific crystal morphologies, some showing significant reverse zoning. Melt compositions were calculated through application of the olivine–melt Fe = Mg exchange coefficient. The calculations suggest that phenocrystic and primocrystic olivine (Fo88–82) in the LCM–LBZ and lower OZ formed from melts with c. 13–10 wt % MgO. Modeling implies that reversely zoned olivine primocrysts and chadacrysts have rims in equilibrium with melts of c. 10–8 wt % MgO that were saturated only in olivine (+ minor chromite), whereas some olivine cores formed from melts as evolved as c. 6–5 wt % MgO that would have coexisted with a gabbroic assemblage. The presence of multiple olivine populations in the OZ (some reverse zoned) indicates that the LPS did not crystallize from a single pulse of melt that evolved by closed-system fractional crystallization. We propose that the reverse zoning pattern records incorporation of evolved crystals, most derived from the mushy gabbroic host, when an olivine-charged replenishment under- or intraplated the partly crystallized basaltic magma, now preserved as the DZ. The intervening CPZ may also owe its origin to the emplacement of the olivine slurry, possibly as a result of pore-scale melt mixing at this interface. The DZ shows inward differentiation trends that can be explained by in situ differentiation. The data imply that late emplacement of olivine-rich crystal slurries and in situ differentiation both played a role in the development of the layered LPS. [ABSTRACT FROM AUTHOR]

The petrology, mineralogy and geochemistry of a section of the Merensky Reef at Bafokeng Rasimone Platinum Mine (BRPM) are described. A model for the formation of platinum-group minerals (PGM), sulphide and chromitite is proposed that explains the stratigraphic relationships observed in the Merensky Reef, both at BRPM and at other locations in the Bushveld Complex. To achieve this it is necessary to understand platinum-group element (PGE) behaviour in naturally occurring mafic systems and for this reason comparisons are drawn from core TN207 through the Platreef at Tweefontein. The common link between the Platreef and Merensky Reef is the presence of unusually high concentrations of As, Sb, Bi and Te that promote the crystallisation of semi-metal bearing PGM from sulphide liquids. Under conditions of increasing semi-metal contamination, Pt is the first PGE to be extracted from a sulphide liquid followed by Rh, Ru, Os and Ir. While some Pd is released to form Pd-PGM much of it remains within the Ni-rich sulphide phase that crystallizes to form pentlandite. A critical aspect is the timing of their introduction into the magmatic system. For the Merensky magmas, contamination occurred predominantly within a staging chamber owing to wall-rock interaction with Transvaal sediments. This led to the formation of sulphide liquids that captured PGE and, ultimately, the crystallization of Pt- and Ru-PGM. The extreme enrichment in PGE and the high Pt/Pd ratios in the Merensky chromitites are attributed to density-driven concentration of PGM transported by magmas displaced from a staging chamber. Emplacement of these magmas into the Bushveld Complex resulted in thermo-mechanical erosion of the floor and deposition of chromites + sulphides + PGM. In places, these assemblages collected in sedimentary-like scour channels. In the Platreef, contamination occurred largely after magma emplacement owing to interaction with the local Transvaal sediments. As a result, mechanical separation of PGM did not occur and most PGM remain spatially associated with their original sulphide hosts.The Merensky Reef is a prime example of highly efficient PGE concentration resulting from mechanical processes, whereas the Platreef is a prime example of highly efficient PGE removal from sulphide liquids in response to extreme contamination by semi-metals. [ABSTRACT FROM AUTHOR]

The early stages of magmatic processes operating at mantle depths beneath continental arcs are poorly known. The chemical compositions of minerals and rocks, mineral Sr–Nd–Hf–O isotopes and zircon U–Pb ages of garnet clinopyroxenite dykes from the Shenglikou peridotite massif (North Qaidam Orogen, NE Tibet, China) were studied to constrain their sources and genesis, and the dynamic processes that controlled pyroxenite formation beneath an early Paleozoic active continental margin. Major-element compositions of bulkrocks suggest that the pyroxenitic protoliths were cumulates segregated from a melt, which was extracted from a peridotite-dominated mantle source. Bulk-rock and mineral trace-element patterns show strong enrichment in fluid-mobile elements (e.g. Cs, Rb, Ba, Th, U, K, Pb and Li) and marked negative anomalies in the high field strength elements relative to rare earth elements, similar to the characteristics of melts derived from a volatile-rich sub-arc mantle. Enriched Sr and Nd initial isotopic compositions at 500 Ma (87Sr/86Sr of 0·70919–0·71774 and εNd of −16·3 to −3·4) are in contrast to the highly radiogenic Hf isotope compositions (similar to those of the depleted-mantle reservoir) and to the uncontaminated upper-mantle δ18OV-SMOW (garnet: 5·6 ± 0·3‰, 2SD, n = 61; zircon: 5·9 ± 0·3‰, 2SD, n = 28). These decoupled isotopic signatures suggest that the melt source was located in a convective mantle wedge (controlling the Hf and O isotopes) that had been pervasively metasomatized by fluids from a subducted Proto-Tethys oceanic slab (controlling the Sr–Nd isotopes and highly incompatible elements). Zircons with two groups of U–Pb ages (430 ± 5 Ma and 401 ± 7 Ma) were generated by recrystallization events, corresponding to UHP metamorphism and a major uplift stage during the North Qaidam orogeny, respectively. The combined evidence reveals a picture of continental arc magmatism at mantle depths and subsequent continental collision. The subduction of the Proto-Tethys oceanic slab beneath the southern Qilian margin triggered flux melting of the metasomatized convective mantle wedge and generated hydrous arc magmas. These primitive magmas intruded into the overlying lithospheric mantle and segregated the cumulates parental to the Shenglikou pyroxenites. Subsequent continental subduction incorporated fragments of the mantle-wedge peridotite (containing pyroxenite dykes) at ∼430 Ma and carried them to shallow depths during exhumation at ∼400 Ma. [ABSTRACT FROM PUBLISHER]

The Central Atlantic Magmatic Province (CAMP) is one of the largest igneous provinces on Earth, with an areal extent exceeding 107 km2. Here we document the geochemical characteristics of CAMP basalts from Triassic–Jurassic basins in northeastern USA and Nova Scotia (Canada). The CAMP rocks occur as lava flows, sills and dykes. All of our analysed samples show chemical characteristics typical of CAMP basalts with low titanium content, which include enrichment in the most incompatible elements and negative Nb anomalies. All the basalts also show enriched Sr–Nd–Pb initial (t = 201 Ma) isotopic compositions (206Pb/204Pbini. = 18·155–18·691, 207Pb/204Pbini. = 15·616–15·668, 208Pb/204Pbini. = 38·160–38·616, 143Nd/144Ndini. = 0·512169–0·512499). On the basis of stratigraphy, rare earth element (REE) chemistry and Sr–Nd–Pb isotope composition, three chemical groups are defined. The Hook Mountain group, with the lowest La/Yb ratios, initial 206Pb/204Pbini. >18·5 and 143Nd/144Ndini. > 0·51238, comprises all the lastest and upper stratigraphic units. The Preakness group, with intermediate La/Yb ratios, 206Pb/204Pbini. > 18·5 and 0·51233 > 143Nd/144Ndini. > 0·51225, comprises the intermediate units. The Orange Mountain group has the highest La/Yb ratios and 143Nd/144Ndini. < 0·51235 and involves all the earliest and stratigraphically lowest units, including the entire North Mountain basalts from Nova Scotia. In this last group, three sub-groups may be distinguished: the Rapidan sill, which has 206Pb/204Pbini. higher than 18·5, the Shelburne sub-group, which has 143Nd/144Ndini. < 0·51225, and the remaining Orange Mt samples. With the exception of one sample, the Eastern North America (ENA) CAMP basalts display initial 187Os/188Os ratios in the range of mantle-derived magmas (<0·15). Simple modelling shows that the composition of the ENA CAMP basalts cannot plausibly be explained solely by crustal contamination of oceanic island basalt (OIB), mid-ocean ridge basalt (MORB) or oceanic plateau basalt (OPB) magmas. Mixing of such magma compositions with sub-continental lithospheric mantle (SCLM)-derived melts followed by crustal contamination, by either assimilation–fractional crystallization (AFC) or assimilation through turbulent ascent (ATA) processes is somewhat more successful. However, this latter scenario does not reproduce the REE and isotopic composition of the ENA CAMP in a fully satisfactory manner. Alternatively, we propose a model in which asthenospheric mantle overlying a subducted slab (i.e. mantle wedge) was enriched during Cambrian to Devonian subduction by sedimentary material, isotopically equivalent to Proterozoic–Lower Paleozoic crustal rocks. Subsequently, after subduction ceased, the isotopic composition of this mantle evolved by radioactive decay for another 170 Myr until the CAMP magmatic event. Varying amounts and compositions of the incorporated sedimentary component coupled with radiogenic ingrowth over time can account for the main geochemical characteristics of the ENA CAMP (enriched incompatible element patterns, negative Nb anomalies, enriched Sr–Nd–Pb isotopic composition) and the differences between the three chemical groups. [ABSTRACT FROM PUBLISHER]

Eclogite and omphacite granulite occur interlayered on centimetre to decametre scales to form the Cretaceous Breaksea Orthogneiss, with assemblages reflecting peak conditions of P ≈1·8 GPa and T ≈850°C. It is the highest-grade part of the c. 125–115 Ma Western Fiordland Orthogneiss, New Zealand. A gneissic fabric in the host omphacite granulite truncates igneous layering in decametre-scale, coarsely layered clinopyroxenite and garnetite inclusions. Field and microstructural relationships, together with rare earth element (REE) characteristics across all rock types, support the conclusion that most garnet has a common igneous origin; geochemical data alone do not discriminate whether it is igneous or metamorphic. Igneous diopside persists in coarse-grained, weakly deformed samples of clinoyroxenite. Garnet cores in garnetite, late-formed garnet rims in garnetite and delicate garnet films in clinopyroxenite have a range of REE contents interpreted to reflect cumulate processes involving progressive grain growth isolated from the parent magma. Clear rims on inclusion- and Ca-Tschermakite-rich diopside in clinopyroxenite, of a composition that is distinct from grain cores, are interpreted as recrystallization features. Garnet in omphacite granulite occurs in three textural settings, the most common Type 1 garnet having REE characteristics identical to garnet in eclogite, but depleted in heavy REE (HREE) relative to garnet in garnetite. Type 2 garnet in omphacite granulite forms metamorphic coronae on omphacite in contact with plagioclase, has a pronounced positive Eu anomaly and is depleted in HREE compared with Type 1 garnet. Type 3 garnet in omphacite granulite migmatite is indistinguishable from Type 1 garnet, consistent with its formation through magma injection. Cumulate eclogite, pyroxenite and garnetite formed at c. 1·8 GPa, exposing an unusually deep and coherent arc section. [ABSTRACT FROM PUBLISHER]

Magmatic textures provide an insufficiently explored tool to interpret physical processes and environmental variables that drive differentiation and crystallization in magma chambers. We derive a new method, which utilizes the crystal size distribution (CSD), to retrieve the rates of nucleation and growth from natural igneous rocks. However, a single CSD results from an arbitrary number of combinations of nucleation and growth rates; if additional parameters such as crystallinity evolution are employed, the solution for rates becomes unique. Interpretation of representative log–linear CSD trends shows that the nucleation rates are sensitive to even minor features of the CSD, whereas the growth rate functions are mainly related to the crystallinity evolution. The reconstructed growth rates become minimal at intermediate crystallinities but diverge to very high values at the beginning and the end of crystallization. This general result is related to the small effective area of the solid–liquid interface close to the liquidus (few small grains) and near the solidus (largely solidified with diminishing melt pools). Assuming that growth rate is related to environmental variables such as magma undercooling, these results suggest that the solid fraction in many magmas increases in a sigmoidal manner over their crystallization interval and indicate the tendency for largest undercooling at the beginning and at the end of crystallization. For crystallization times constrained by conductive cooling models, the growth rates calculated for representative CSDs are of the order of 10−11 cm s−1, which is in a good agreement with in situ observations of Hawaiian lava lakes. Calculated growth rates are inversely proportional to the magma body size and increase from the chamber interior to the margins. [ABSTRACT FROM AUTHOR]