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Your search keyword '"N. V. Raghavan"' showing total 2 results
Start Over Author "N. V. Raghavan" Journal journal of organometallic chemistry
2 results on '"N. V. Raghavan"'

1. Reactions of copper acetylides. Structure of (π-C5H5)Ru(PPh3)2 (CCPh)CuCl, and new syntheses of transition metal cluster compounds

Author

M. I. Bruce, N. V. Raghavan, Raymond E. Davis, and O.M.Abu Salah

Subjects
Organic Chemistry, chemistry.chemical_element, Metal carbonyl, Photochemistry, Biochemistry, Copper, Inorganic Chemistry, chemistry.chemical_compound, Crystallography, Monomer, chemistry, Transition metal, Materials Chemistry, Cluster (physics), Physical and Theoretical Chemistry
Abstract

In contrast to a related iron—copper compound, the complex (π-C5H5)Ru(PPh3)2(C2Ph)CuCl is shown to be monomeric, and contains linear dicoordinate copper(I); the reactions of this and similar complexes with metal carbonyls are sources of new mixed-metal clusters, such as (π-C5H5)Fe2 Ru(C2Ph)(CO)6 (PPh3).

Published
1974
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2. A novel ring substitution reaction in a cyclopentadienylruthenium phosphine complex

Author

N. V. Raghavan, Raymond E. Davis, M. I. Bruce, F. G. A. Stone, and T. Blackmore

Subjects
Substitution reaction, Hydrogen bond, Stereochemistry, Organic Chemistry, Ring (chemistry), Biochemistry, Medicinal chemistry, Adduct, Inorganic Chemistry, chemistry.chemical_compound, Hexafluoroacetone, Cyclopentadienyl complex, chemistry, Intramolecular force, Materials Chemistry, Physical and Theoretical Chemistry, Phosphine
Abstract

The reaction between hexafluoroacetone and Ru(PPh3)2(π-C5H5)[σ-C2(CO2Me)2H] affords a 1 1 adduct, containing a coordinated ester group and an intramolecular hydrogen bond; formal insertion of (CF3)2CO into a CH bond of the cyclopentadienyl group has also occurred.

Published
1973
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