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Start Over Author "Rehan, Mohammad" Topic catalysis Journal journal of organic chemistry

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1. Chemoselective C-Benzylation of Unprotected Anilines with Benzyl Alcohols Using Re2O7 Catalyst.

Author

Nallagonda, Rajender, Rehan, Mohammad, and Ghorai, Prasanta

Subjects
*CATALYSIS, *CHEMOSELECTIVITY, *BENZYL alcohol, *AROMATIC amines, *CHEMICAL reactions
Abstract

An unprecedented dehydrative C-C bond formation between unprotected anilines with benzyl alcohols is disclosed. Re2O7 catalyst (5 mol %) at elevated reaction temperature (80 °C) provided C-benzylanilines with high to excellent yields and with good chemoselectivities (over N-alkylation). A probable mechanism has been proposed based on mechanistic studies. [ABSTRACT FROM AUTHOR]

Published
2014
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