1. The Preparation of a Highly Stretchable Cellulose Nanowhisker Nanocomposite Hydrogel
- Author
-
Yiqiang Li, Jiufang Duan, Jianxin Jiang, Liujun Liu, Jianzhang Li, and Chao Guan
- Subjects
Nanocomposite ,Materials science ,Article Subject ,Scanning electron microscope ,Methacrylate ,chemistry.chemical_compound ,Compressive strength ,chemistry ,lcsh:Technology (General) ,Ultimate tensile strength ,Self-healing hydrogels ,lcsh:T1-995 ,General Materials Science ,Fourier transform infrared spectroscopy ,Cellulose ,Composite material - Abstract
Molecules that associate to form cross-links by hydrophobic association are designed and synthesised. Hydrogels, based on cellulose nanowhiskers (CNWs), acrylamide (AM), and stearyl methacrylate (C18), were synthesised by micellar copolymerisation, using ammonium peroxydisulfate as an initiator. CNWs composite hydrogels were characterised by Fourier transform infrared spectroscopy (FTIR) and their morphologies were investigated by scanning electron microscope (SEM). The system shows the original extensibility up to about 2500%: the tensile strength and compressive strength have maximum values of 1.338 MPa and 2.835 MPa, respectively. Besides excellent mechanical properties, CNWs composite hydrogels also have the ability to self-heal and remould: this is mainly attributed to the dissociation and reassociation of the associated micelles. In contrast to conventional cellulose hydrogels, these systems, when broken or cut, can be simply repaired by bringing together fractured surfaces to self-heal at room temperature.
- Published
- 2015