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In our study, we employed a Mo2TiAlC2 thin film as a passive saturable absorber (SA) to create a stable pulsed fibre laser at 1564.52 nm. We synthesized a Mo2TiAlC2-PVA thin film with a 6% modulation depth and a 10 MW/cm2 saturation intensity. This thin film was integrated into the laser cavity between FC/PC fibre connectors, enabling Q-switching over a pump power range of 30 mW to 120 mW. This resulted in an increased repetition rate from 31.1 kHz to 66.83 kHz and a reduced pulse duration from 13.45 µs to 6.35 µs. The pulse train's stability was confirmed by a high signal-to-noise ratio (SNR) of 58 dB. The laser achieved a maximum output power of 6.56 mW and a pulse energy of 98.16 nJ. These results demonstrate Mo2TiAlC2 as a viable Q-switching modulator in the 1.55-µm wavelength range, with promising applications in compact and efficient pulsed fibre lasers. [ABSTRACT FROM AUTHOR]