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Continuing the work of Monnier [Israel J. Math. 129, 189–207 (2002)], we determine the Gerstenhaber algebra structure over the Poisson cohomology groups for a large class of Poisson structures with isolated singularities over the plane. It reveals that there exists a GAGA-type phenomenon. We give an explicit description via generators and relations for the case of simple singularities. [ABSTRACT FROM AUTHOR]