Search

The Journal of Materials Science awards the annual Robert W. Cahn Prize to recognize the best paper published in the journal each year. The winner of the 2023 Cahn Prize is a research paper titled "Molecular modelling of graphene nanoribbons on the effect of porosity and oxidation on the mechanical and thermal properties." The paper presents molecular simulation models of graphene nanoribbons and examines the impact of porosity and oxidation on their mechanical and thermal conductivity properties. The paper is well-written and provides valuable insights for researchers in this field. Two other papers were selected as runners-up for the prize. All the monthly finalists for the Cahn Prize can be downloaded for free on the journal's website. [Extracted from the article]

Influence of the ion irradiation at elevated temperatures on the novel preceramic paper-derived SiCf/SiC laminated composites fabricated by spark plasma sintering was investigated. The composites were subjected to high-dose simultaneous irradiation of silicon (Si) ions at 400 °C. Irradiation induces amorphization of the damaged area up to 30 dpa, and then recrystallization of amorphous regions with increasing dose occur. No evidence of cavities was found in SiCf/SiC composites irradiated by silicon ions up to 100 dpa. The irradiated composites pre-injected with 5000 appm He displays low swelling (~ 0.3%). The irradiation with Si ions may suppress the cavity nucleation and they growth in SiC layers. [ABSTRACT FROM AUTHOR]

Graphical abstract: [ABSTRACT FROM AUTHOR]

The December 2023 cover paper of the Journal of Materials Science features a study by Xie and Luo from Chongqing Jiaotong University in China. The paper, included in the "Computation & Theory" Topical Collection, focuses on the use of carbon fiber-reinforced polymer (CFRP) for construction projects. The authors aim to provide insights into the transport behavior of liquids in epoxy-modified C–S–H pores in cement-based materials, combining MD simulations with experimental measurements. Xie is currently pursuing a master's degree in civil engineering, while Prof. Luo is an associate professor at Chongqing Jiaotong University and a researcher at Aarhus University in Denmark, with a focus on reducing the carbon and energy footprint of civil engineering materials and infrastructure. The paper is published open access and can be widely shared with readers using the provided link. [Extracted from the article]

The hydrogel in this paper is designed to do just that, by using controlled release from a hydrogel to deliver the drug quickly and at a relatively high concentration to the interior of cancer cells. The paper describes the synthesis and in-vitro testing of a hydrogel composite that is designed to maximize toxicity to cancer cells by both efficiently delivering the cancer drug doxorubicin (DOX) and overheating the cells with magnetically induced hyperthermia. This makes it highly desirable to develop a delivery system that can encapsulate the drug, bring the drug directly to the cancer cells then release the drug into the cancer tumor or cells. [Extracted from the article]

Professor Grimes summarizes the winning paper and the two runners-up:"Machine learning is certainly of great current interest to address the multivariable materials design challenge. 10.1007/s10853-022-07499-9 5 Wang Z, Lai A, Schuh CA, Radovitzky R. Phase transformation and incompatibility at grain boundaries in zirconia-based shape memory ceramics: a micromechanics-based simulation study. The winner of the 2022 Robert W. Cahn Best Paper award is "Machine learning guided alloy design of high-temperature NiTiHf shape memory alloys" by Udesh M.H.U. Kankanamge, Johannes Reiner, Xingjun Ma, Santiago Corujeira Gallo, and Wei Xu. [Extracted from the article]

Of course, the paper complements the SEM imaging, which is intrinsic to the FIB, with imaging and diffraction in the TEM. The paper does also have a SharedIt link like all articles in JMS (https://rdcu.be/cWW0L) so it can be widely and immediately shared with readers; all papers published in JMS are free-to-read using the SharedIt link from the moment they appear online with their permanent DOI. The cover for the November 2022 issues of the Journal of Materials Science comes from the paper by Tunes et al. which appeared in issue #35 from September 2022 [[1]]. [Extracted from the article]

A facile and cost-effective modified sol–gel synthesis is employed to synthesize flexible silica-cellulose hybrid aerogels (SCHA) using recycled cellulose fibers (RCF). The effect of cellulose fiber concentrations and ambient temperature conditions on the thermal, acoustic, and oil absorption characteristics was quantified comprehensively. The experiments were conducted by considering the range of weight fractions from 1–4 wt.% from waste tissue paper with a cross-linker and tetraethylorthosilicate (TEOS) as silica precursors. The SCHA aerogels were modified by a silylating agent with surface hydroxyl groups to achieve superhydrophobic behavior with a water contact angle (WCA) as high as 168°. The synthesized aerogels were characterized by X-ray diffraction (XRD), Fourier transforms infrared spectroscopy (FTIR), scanning electron microscope (SEM), and Brunauer-Emmett-Test (BET) to identify the physical morphology. An excellent oil absorption capacity of 24.8 g.g−1 was also noticed with 4 wt.% of cellulose concentration in hybrid aerogel retained up to 5 cycles with an absorption capacity of 6.4 g.g−1. The average thermal conductivity of hybrid aerogels was estimated in the range of 0.038–0.032 W/m K. Slight enhancement in the thermal conductivity is noted with the increase in wt.% of cellulose to the silica aerogel. However, about 40–50 °C improvement in thermal degradability (as concluded from Thermogravimetric Analysis) with a minimum weight loss was observed in hybrid aerogel over cellulose aerogel. A comparatively high sound absorption coefficient of 0.453–0.628 at low frequency (1500 Hz) and 0.86–0.94 at high frequency (3600 Hz) was achieved with an average thickness of 8 mm compared to cellulose aerogel. The compressive Young's modulus of hybrid aerogels was also enhanced by 94.12%. [ABSTRACT FROM AUTHOR]

In-situ formation and integration of graphene into MoS2 interlayer spacing: expansion of interlayer spacing for superior hydrogen evolution reaction in acidic and alkaline electrolyte. The paper was handled by our Editor Mark Bissett and is entitled "In-situ formation and integration of graphene into MoS SB 2 sb interlayer spacing: expansion of interlayer spacing for superior hydrogen evolution reaction in acidic and alkaline electrolyte"; it is part of our "Energy materials" Topical Collection. The cover for the December 2022 issues of the Journal of Materials Science comes from the paper by Bui et al., which appeared in issue #40 from October 2022 [[1]]. [Extracted from the article]

Proton exchange membrane fuel cells (PEMFCs) require efficient water management. Microporous layers (MPLs) are crucial to solve this problem due to their positive effects on the two-phase mass transfer process. The performance of MPLs is mainly determined by the properties of the materials used for their construction as well as other basic transport properties, including morphology, porous structure, wettability, and electrical resistivity. In this study, graphite and reduced graphene oxide (rGO) were used as the main components to fabricate MPLs for use in PEMFCs because they are highly conductive and thermally efficient. Single-layer MPLs are prepared by compressing MPL powders with different proportions of ingredients. In contrast, two-layer gas diffusion layers were fabricated by applying MPL pastes to a benchmark Toray carbon paper using a screen-printing process. FTIR and XRD analysis of main components and some samples are performed to investigated functional groups and the nature of MPLs' surface, respectively. An analysis of the effects of graphite, rGO, and hydrophobic agents' constituents on the physical properties (electrical resistivity, contact angle, roughness, porosity, and permeability) of the fabricated MPL or MPL-coated carbon papers by screen-printing method has been performed. Also, the effect of different coating methods (screen-printing and spraying) on different properties of graphite-based and rGO-based MPLs has been investigated. The results show that composites based on rGO have higher electrical resistivity than that of graphite-based MPLs, but lower roughness. However, MPLs based on rGO exhibit better contact angle, higher porosity, and improved gas permeability. Moreover, as expected, the contact angle and electrical resistivity increase, while the porosity and permeability decrease when the hydrophobic agents (polytetrafluoroethylene, and polyvinylidene difluoride) which are also used as binders, are increased. On the other hand, screen printed graphite-based MPL has lower electrical resistivity, while screen printed rGO-based MPL has higher porosity percentage, roughness, and permeability than the sprayed one. [ABSTRACT FROM AUTHOR]

High-entropy borides are deemed robust candidates because of their complex combination of entropy-driven, multi-component disordered solid solutions. They are particularly remarkable for their unique single-crystal structures and significant bandgap. This structural adaptability positions them uniquely among materials, setting them apart from conventional transition metal diborides. Researchers have been fascinated by the appeal of high-entropy borides for a long time, driven by the groundbreaking idea of 'High entropy ceramics'. Nevertheless, the lack of thorough review papers in this field has hindered the progress of creating strong and durable high-entropy borides. This paper proposes adopting a collaborative strategy to properly negotiate this unexplored region. This perspective covers the up-to-date research on successfully synthesized high-entropy boride complexes. It examines compositional strategies, historical backgrounds, structural complexity, fabrication methods, mechanical, thermal, and oxidation properties, as well as emergent properties with potential uses, pathways, and future possibilities. This attempt challenges materials science traditions by introducing novel materials with superior performance. [ABSTRACT FROM AUTHOR]

The dielectric loss of Cu with high thermal conductivity is large at high frequency, which cannot meet the performance requirements in high-integrated circuits. There is an urgent need for materials to reduce its dielectric loss. In this paper, the thermal conductivity and dielectric properties of the AlN coating-Cu substrate system were controlled by changing the N2 pressure. The results showed that the crystallinity of hcp-AlN in AlN coating increased significantly when the proportion of N2 pressure was increased. With the increase of the N2 pressure, the particle size on the surface and the roughness of the coating improved. The AlN coating prepared at high N2 pressure had high dielectric constant and low dielectric loss at high frequency compared to those of the coatings prepared at low N2 pressure. At the same time, the AlN coating prepared under high N2 pressure on the Cu substrate did not decrease the thermal conductivity of Cu substrate. The AlN-Cu system prepared in this paper had high thermal conductivity and good dielectric properties, providing theoretical guidance for integrated circuit packaging and capacitor applications. [ABSTRACT FROM AUTHOR]

The massive residues of tetracycline (TC) have caused serious harm to the human body and the environment, so it is urgent to explore a portable, on-site, sensitive and selective method to detect TC. In this study, a dual response ratiometric fluorescent probe (S,O-C3N4QDs-CitNa-Eu3+) for detecting TC was constructed by mixing sodium citrate (CitNa), europium ion (Eu3+) and sulfur and oxygen co-doped graphite phase carbon nitride quantum dots (S,O-C3N4QDs) solution in a specific proportion. The S,O-C3N4QDs was initially synthesized by using citric acid and thiourea as the precursors via a hydrothermal route. The blue fluorescence of S,O-C3N4QDs (λem = 445 nm) was decreased while the red fluorescence of Eu3+ was increased (λem = 620 nm) own to the synergistic effect of internal filter effect, static quenching and antenna effect when TC was added to the mixed system containing CitNa and Eu3+. As a result, the ultra-sensitive detection of TC was realized from 0.25 to 120 μM with a detection limit of 1.3 nM. An obvious color change of the solution from blue to purple to red with continuous adding TC was observed such that the semi-quantitative detection of TC can be realized. Moreover, a smartphone APP monitoring platform based on test paper was constructed by using color scanning application, demonstrating that the ratiometric fluorescent probe constructed in this work has great potential in medical and environmental fields. [ABSTRACT FROM AUTHOR]

This review paper investigates novel approaches to the fabrication of fiber-reinforced composites (FRCs) via additive manufacturing (AM), with a focus on improving mechanical properties in polymers, metals, and ceramics while reducing weight of the structures. FRCs have been regarded as the optimal material choice across the automobile, aerospace, and construction industries due to their exceptional characteristics, including high strength-to-weight ratio, elevated stiffness, commendable thermal stability, remarkable fatigue and impact resistance, as well as noteworthy chemical and corrosion resistance. AM plays a significant role in FRCs production by offering design flexibility, product customization, waste reduction, near net shape fabrication, cost-effectiveness, and fast prototyping. This paper initially categorizes AM of FRCs into three categories: AM of polymer-matrix, metal-matrix, and ceramic-matrix composites. These categories are further subdivided based on the types of matrix as well as fibers used. Subsequently, it emphasizes the roles of 4D printing and numerical simulation in AMFRCs. The review concludes by addressing potential applications, existing challenges, and scope of AMFRCs in future research and development. [ABSTRACT FROM AUTHOR]

This article discusses the importance and limitations of peer-reviewed journal articles in the scientific community. The author emphasizes that a single paper should not be seen as an indisputable scientific fact, but rather as part of an ongoing process of scientific discovery and refinement. The author suggests several ways to assess the trustworthiness of a paper, including evaluating the authors' track record, the number of citations the paper has received, and the reputation of the journal in which it is published. However, the author also highlights the importance of personal relationships and trust in assessing the quality of a paper. Overall, the article provides valuable insights into the peer-review system and the challenges it faces in the modern scientific landscape. [Extracted from the article]

Twinning is an important deformation mechanism for magnesium alloys, which has a significant impact on the texture evolution and mechanical properties. Pre-twinning deformation has been considered as an effective method for texture regulation. For each twinning mode, there are six crystallographically equivalent variants. Properly identifying the activated twin and understanding its variant selection criteria are essential for the development of high-performance magnesium alloys. As summarized in this paper, the observed twin variant by the commonly employed electron backscatter diffraction technique can be identified by several approaches, including misorientation analysis, trace analysis and matrix method. Schmid factor analysis was commonly performed to explain the selection of twin variants. To broaden the application scope under complex stress state, a generalized Schmid factor was derived by introducing a stress tensor. The efficiency of Schmid criteria to assess twin variant selection was confirmed to be influenced by the type of the applied stress. To consider the local effect on twin activation, in particular twin-twin transfer and slip-induced twinning, displacement gradient tensor calculation and geometrical compatibility factor analysis have been employed. It was demonstrated that local strain accommodation played a critical role in selecting the variants of cross-boundary twins in magnesium alloys. Assisted with crystal plasticity finite element modeling, the resolved shear stress on twinning and a composite Schmid factor combining the global Schmid factor and geometrical compatibility factor were obtained to better explain the activated twin variants in magnesium alloys. All the above-mentioned Schmid law based criteria and some energy based criteria as well are summarized in this paper. Their applications in evaluating twin variant selection in magnesium alloys are critically reviewed and discussed. [ABSTRACT FROM AUTHOR]

Microalloying has been an important method in aluminum alloy development for decades. Large number of papers have shown that the addition of trace element Erbium (Er) can effectively improve the comprehensive properties of aluminum alloys. Similar with the trace element Scandium (Sc), addition of trace element Er in aluminum alloys could form nano-sized L12-ordered Al3Er precipitates, which was coherent with the Al matrix. However, the dispersion precipitation strengthening effect of Al3Er was more significant than that of Al3Sc, at the same atomic content. In the case of the addition of both Er and Zr, core–shell-structured Al3(Er, Zr) precipitates formed instead of Al3Er precipitates. Those thermally-stable nanosized precipitates could significantly refine the grain size, retard the recrystallization, improve the mechanical properties and corrosion resistance. This paper reviewed several typical Er-containing microalloyed commercial aluminum alloys, like 2xxx (Al–Cu) alloys, 4xxx (Al–Si) alloys, 5xxx (Al–Mg) alloys, 7xxx (Al–Zn–Mg–Cu) alloys, as well as selective laser melting aluminum alloys. [ABSTRACT FROM AUTHOR]

With the development of society and technology, machinery and equipment have enhanced our work efficiency but have also introduced various hazards, such as electromagnetic radiation, medical, industrial, and agricultural rays. The harms these radiations inflict on human health are significant, with severe cases leading to cancer, disability, or even life-threatening situations. Therefore, effective protective measures in some fields are crucial. This paper firstly summarized the basic principles of radiation protection for different rays, then systematically introduced the widely used manufacturing methods for flexible radiation shielding materials, including weaving with metal fibers, fiber blending, silver-plated fibers, and so on. Subsequently, the paper reviewed the testing methods of radiation-protective clothing materials. Finally, it comprehensively concluded the discussions on flexible radiation shielding materials and offered a perspective on their future development trends. [ABSTRACT FROM AUTHOR]

Due to increased environmental awareness, the depletion of fossil fuels, and expanding ecological concerns, today's society has a larger need for environmentally friendly materials. The idea of sustainable development of environmental material resources with enhanced economic activities was born from the rise in ecological consciousness. The textile industry generates enormous amounts of cotton waste. The environmental impact of disposing of this cotton waste makes it difficult for the textile sector to dispose of the vast amounts of produced cotton waste. As a result, all-cellulose composites (ACCs) have piqued the interest of researchers in recent years. All-cellulose composites are cellulose-based mono-component cellulose composites in which the reinforcing phase is typically composed of high-strength cellulose fibres, and the matrix is composed of regenerated cellulose. This composite type is distinguished by its exceptional interfacial compatibility and biodegradability due to the matrix and reinforcing phase having common cellulosic compositions. ACCs will become a more alluring option as enterprises prioritize sustainability and environmental responsibility because they can be recycled and reused rapidly and simply. This will contribute to less waste and enhance the overall sustainability of our society. This review paper discusses various methods to develop ACCs, textile waste-based thermoset and thermoplastic composites and textile waste-based cellulose composites (TWCCs). This review paper emphasizes approaches to develop TWCCs and the challenges and opportunities in TWCCs. [ABSTRACT FROM AUTHOR]

Compared to the individual fiber, the core problem limiting the mechanical strength of the aramid nanopaper is the weak interfacial bonding strength, and the hydrogen bond-induced aggregation is an important factor influencing the well compositing of aramid nanofibers (ANFs) with other enhancers. In this work, we introduced sodium alginate (SA) as a mechanical additive during the formation process of ANFs to realize the uniform wrapping of the SA on the surface of ANFs. The resultant ANFs/SA paper shows an ultimate strength of 308.23 MPa, a toughness of 42.33 MJ⋅m−3, and an elongation of 21.99%, which are 1.63, 5.16, and 3.12 times of the pure ANFs film. The excellent mechanical performances are attributed to the good dispersion of SA in the ANFs matrix, which can result in the fine physical cross-link and enhanced hydrogen bonding at interfaces. Meanwhile, the ANFs/SA composite also shows favorable electrical insulation behaviors. [ABSTRACT FROM AUTHOR]

Nowadays, the scientific community emphasizes the use of reversible and non-toxic materials in the field of cultural heritage. Biopolymers are one of the alternative materials to synthetic polymers and solvents that are dangerous for human health and for the environment, applied in consolidation and coating treatment. Natural biopolymers may be divided into polysaccharide, protein, and polyester: All of them are low cost, eco-friendly, and biocompatible, besides many physicochemical characteristics such as being transparent, soluble in water, hydrogel, and film-forming, and can be easily functionalized. The addition of nanoclay, essential oil, and active molecules improves the physicochemical properties of biopolymers and proposes smart response abilities to the new composite material. This work is intended to provide an overview of the development of biopolymers by considering the most general aspects and scanning the diverse substrates of application for the conservation and protection of cultural heritage. [ABSTRACT FROM AUTHOR]

The field of tissue engineering involves various methodologies employed to improve or replace biological tissues with extracellular matrices (ECMs). Significant progress has been made, particularly in the fabrication of three-dimensional (3D) scaffolds for replacing damaged tissues or organs. The current review broadly focuses on the various research works carried out involving the use of biomaterials (biopolymers, bio-ceramics and dopants) in this area. A detailed discussion on several scaffold-making modern technologies has also been provided, along with a demonstration of different characterization techniques. Though a number of review papers have been published on biomaterials and fabrication techniques, a very small number focuses on the clinical trials carried out and the commercialization of scaffolds in the biomedical field. Thus, a critical analysis and detailed discussion of some of the clinical trials, market growth, and future demands have been presented in this paper. [ABSTRACT FROM AUTHOR]