1. Strain-controlled nanocrack formation in a Pd film on polydimethylsiloxane for the detection of low H concentrations.
- Author
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Kim, Sungyeon, Lee, Hyun-Sook, Jang, Byungjin, Cho, Sungmee, and Lee, Wooyoung
- Subjects
STRAINS & stresses (Mechanics) ,NANOSTRUCTURED materials ,FRACTURE mechanics ,PALLADIUM ,METALLIC thin films ,POLYDIMETHYLSILOXANE ,HYDROGEN analysis - Abstract
We report quantitative nanocrack formation upon adjusting the mechanical tensile strain applied to a Pd thin film on an elastomeric polydimethylsiloxane (PDMS) substrate and its detection properties for H gas in air. Nanocrack formation in Pd/PDMS substrates was controlled through the application of tensile strains that varied in the range 30-120 % during mechanical stretching/compression. This method can be used to modulate nanocrack formation along both the x- and y-axes over a large area. Increasing the applied tensile strain to 90 % induced the appearance of horizontal cracks along the y-axis in addition to an increased number of vertical cracks along the x-axis. When the strain reached 120 %, ordered nanocracks abundantly propagated on the Pd surface in both the directions. Gas detection properties were dramatically enhanced, with a very low detection limit of 50 ppm H in air observed for 120 % strain. This was attributed to the large surface area in the Pd nanocrack pattern, which readily allowed for volume expansion. These results provide a simple mechanism for controlling the detection properties of H gas sensors with low detection limits in air. [ABSTRACT FROM AUTHOR]
- Published
- 2016
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