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In the engine of heavy trucks, the built-in fuel filter assumes the role of "lungs". The core of the filter, namely the fuel filter paper, acts as a filter for small impurities and separates oil and water. In order to be able to separate minute impurities from the fuel, in this study, we prepared a novel fuel oil filter paper with high efficiency and high dust holding capacity based on wet-laid forming by laminating PBT/PP two-component melt-blown nonwoven material and cellulose nanocrystals (CNC)-doped cellulose wood fiber pulp with the fiber mesh combination forming technology. The effects of the CNC mixing ratio, surface density of melt-blown nonwoven material layer, surface density of cellulose wood pulp paper layer and calendaring pressure on the pore size and filtration performance of the composite samples were investigated, and the filtration efficiency of the composite samples on the tiny impurities in the fuel were also studied. The results showed that the novel composite fuel filter paper material prepared by the combined forming technology of fibrous web had high filtration efficiency and dust holding capacity, and the filtration efficiency of the composite samples could respectively reach 99.90% and 99.52% for particles larger than 14 μm and 4 μm in diameter in the fuel. At the same time, the dust holding capacity of the composite sample can reach up to 27.63 mgcm−2. [ABSTRACT FROM AUTHOR]

Melamine-impregnated paper is made by impregnating paper with melamine-formaldehyde resin and can be hot-pressed and laminated onto the surface of wood boards. If the paper has antibacterial activity, it can prevent the spread of indoor bacteria, but impregnated paper with a long-term antibacterial effect has not been proposed. Metal–organic frameworks (MOFs) have been studied as a reservoir of metal ions. In this study, a silver-metal organic framework (Ag-BTC) was synthesized by a green and scalable method at 60 °C (A-60) and at room temperature (A-25). The structure and thermal stability of the Ag-BTC were characterized. Compared with A-25, the structure and particle size distribution of A-60 were more regular and uniform. The thermal stability and the compatibility of Ag-BTC and MF resin were suitable for hot-pressing process. Ag-BTC in the cured impregnated paper exhibited the sustained-release performance of Ag+. The antibacterial ratio of decorated blockboards with 0.10 wt% A-25 to E. coli and S. aureus exceeded 99.99%, reaching Level I antibacterial grade. Compared with A-60-decorated blockboards, the better antibacterial activity of A-25-decorated blockboards was due to the release of more Ag+. This study provides new ideas for the design of antibacterial melamine-impregnated paper. [ABSTRACT FROM AUTHOR]

This work brings in an eco-friendly, smart integrated miniaturized sensor system to determine the temperature of aqueous solution and soil in a more affordable way to yield quality farming, small-scale agricultural farming, greenhouse farming, domestic gardening, and hydroponics. Carbon-Graphite hybrid electrode-based planar disposable sensor strip is used for sensing the temperature over a range of 27 to 50°C. The temperature sensor element is compared to four distinct structures, and the meander geometrical structure is deduced as a result. The temperature sensing element is fabricated utilizing a prudent, efficacious, and inexpensive microfabrication methodology of screen printing. The temperature and resistance characteristics are plotted for the carbon-graphite electrode on PET and paper. The temperature coefficient of resistance is determined to be 1%/°C for PET and 0.8%/°C paper substrate in soil. Test experiment was carried out in water, oven and on field to find out the characteristic equation of study. The temperature sensor strip is integrated with a Wi-Fi SoC-assisted nodeMCU processor that is used in IoT platforms. An app is created using MIT app inventor user interface and is launched on an android smartphone. The app gives the suitable temperature range for sowing seed and germination of the plant growth information. The instantaneous temperature of soil or water is measured, and status information for plant cultivation is also provided by the app. [ABSTRACT FROM AUTHOR]

The Journal of Materials Science has awarded the 2023 William Bonfield Prize for the best review paper to "Cement hydration mechanisms through time—a review" by Elisabeth John and Barbara Lothenbach. The review examines the work of Henri Louis Le Chatelier and William Michaëlis in the late nineteenth century and proposes pathways for future research in cement hydration mechanisms. The authors provide a comprehensive review with over 150 references, making it valuable for researchers in the field. The review was chosen by Professor Bonfield, who praised its analysis and contribution to the understanding of cement and concrete technology. Honorable mentions were also given to reviews on carbon dots, biopolymer-based treatments for cultural heritage materials, and superwetting membranes for oil/water separation. The William Bonfield Prize was created to honor Professor Bonfield's contributions to the Journal of Materials Science and materials research. [Extracted from the article]

Because of excellent insulation properties and thermal stability, meta-aramid paper can be commonly applied to a vast number of fields, like power systems. But poriferous and relatively lax structure of meta-aramid paper would limit its applications in high-voltage environment. This paper proposes a sandwich structure design to combine PDA@BNNS/PMIA film and meta-aramid paper with high breakdown strength. After coating with 6 wt% PDA@BNNS/PMIA solution, this kind of paper became more compact, so there were few pores in the paper and it further enhanced the mechanical and dielectric performances of specimens. The tensile strength in the cross direction increased from 31.3 to 40.5 MPa, and the performance in the machine direction was from 75.5 to 78.9 MPa. Furthermore, the breakdown strength of compound-coated paper achieved 55 kV/mm, which is much higher than meta-aramid paper. Additionally, compound-coated paper still remained outstanding thermal stability. Overall, our fabricated PDA@BNNS/PMIA compound-coated paper has excellent comprehensive properties, which provides a broad prospect for the applications in high-temperature and high-voltage transformers. [ABSTRACT FROM AUTHOR]

The interface structure greatly affects the material surface wettability. Polyphenylene sulfide (PPS) fiber paper was modified via regulation of thermally induced phase separation process to obtain interfacial nanofiber network-like morphology, which obeyed nucleate-growth mechanism with the PPS resin on the fiber surface as the core. PPS nanofiber network layer with rough concave surface feature endowed the modified PPS fiber paper with stable superhydrophobic properties, and it showed excellent oil absorption and oil/water separation performance. The separation efficiency of using P-2 paper to separate the five oil/water mixtures listed in this paper were more than 99.99%, and the kerosene flux was more than 7350 L m−2 h−1 driven by gravity. Excellent hydrophobicity and cycling performance made PPS fiber paper with excellent reusability. In addition, the PPS fiber paper had also been proved to be used in strong acid–base and organic solvents for a long time. This work provided a PPS fiber paper for oil/water separation with simple preparation process, which was expected to be produced in large scale and applied in industrial field. [ABSTRACT FROM AUTHOR]

The March 2024 issue of the Journal of Materials Science features a cover paper titled "Data-driven search for promising intercalating ions and layered materials for metal-ion batteries" by Shayani Parida and her colleagues at the University of Connecticut and EaglePicher. The paper, which falls under the "Computation & theory" Topical Collection, explores the use of density functional theory (DFT) calculations and machine-learning methods to identify alternative 2D materials and intercalating ions for high-power efficiency metal-ion batteries. The journal's Editor-in-Chief, Professor Jean-François Gohy, handled the paper, highlighting the journal's commitment to multidisciplinary research. The paper is freely accessible online, and additional details can be found in the Supplementary Information. [Extracted from the article]

The Journal of Materials Science awards the annual Robert W. Cahn Prize to recognize the best paper published in the journal each year. The winner of the 2023 Cahn Prize is a research paper titled "Molecular modelling of graphene nanoribbons on the effect of porosity and oxidation on the mechanical and thermal properties." The paper presents molecular simulation models of graphene nanoribbons and examines the impact of porosity and oxidation on their mechanical and thermal conductivity properties. The paper is well-written and provides valuable insights for researchers in this field. Two other papers were selected as runners-up for the prize. All the monthly finalists for the Cahn Prize can be downloaded for free on the journal's website. [Extracted from the article]

Using nanostructured materials issued from renewable resources could be the key to the development of good-quality low-cost products that help reduce pollution. Cellulose nanofibrils (CNFs) were obtained by alkaline and bleaching treatments of Amazonian Paricá hardwood sawdust, a waste material from the Brazilian forestry industry. This study evaluated a process consisting in alternating layers of Paricá CNFs and cassava starch to coat standard writing and printing (W&P) papers with a skim-coating method, in which one face of each paper sample is passed over the surface of a suspension containing either CNFs or cassava starch, alternatively. The coated samples were then compared to the uncoated paper in terms of mechanical and surface properties. The mechanical properties of the papers coated with alkaline CNFs showed a declining trend as the number of coating layers increased (from 47 to 31 MPa). The papers coated with starch layers showed improved mechanical performance compared to the samples only coated with alkaline and alkaline bleached CNFs. All the coated samples showed excellent resistance to water degradation. The worst degradation (4%) was observed for the samples coated with a single layer of alkaline CNFs. A significant improvement in surface wettability was observed when gelatinized cassava starch was applied to the paper samples, irrespective of the type of CNFs eventually present on the surface. All in all, these results suggest that using gelatinized cassava starch as an alternating layer between successive CNFs layers on the surface of W&P paper samples may be promising for improving their overall properties. [ABSTRACT FROM AUTHOR]

Cellulose nanofibril (CNF) papers have attracted great interests in recent years because of their attractive performance and the green resource of CNF. However, the thermomechanical properties of CNF papers are insufficient for some sophisticated applications that require higher mechanical properties or smart functionalities. In this paper, a dual bio-inspired strategy is reported to improve the thermal and mechanical properties, as well as the humidity-responsive behavior of CNF papers. CNF is first functionalized by mussel-inspired polydopamine, and then, composite CNF papers with nacre-like layered structure are fabricated by the incorporation of graphene oxide (GO). In addition, Fe3+ is introduced into the composite CNF papers to provide coordination cross-linking for each components. By such compositional and structural design, the composite papers demonstrate significantly enhanced mechanical properties as compared to original CNF paper. Meanwhile, the improved thermal stability and humidity-responsiveness are also demonstrated. This study is expected to provide alternative approach for high-performance and functional CNF materials. [ABSTRACT FROM AUTHOR]

Poly(p-phenylene benzobisoxazole) (PBO) fibre-based specialty paper has become a promising candidate for high-performance insulating materials due to the remarkable properties of PBO fibres. However, the porous structure and poor interfacial interaction of PBO paper seriously weaken its mechanical strength and greatly limit its practical application. Herein, proposed for the first time, a homogeneous reinforcement strategy is developed to regulate the microstructure of PBO paper and efficiently enhance its overall properties. For this reason, flexible ortho-hydroxy polyamic acid (HPAA) was first synthesized and used to impregnate PBO paper. Subsequently, HPAA was thermally converted into a benzoxazole-containing resin, manifesting excellent interfacial compatibility with PBO paper. As a result, the compact structure and solid interface endow the composite paper with impressive performance. The tensile strength, modulus, and electrical breakdown strength of the composite paper are 116.86 MPa, 5.47 GPa, and 63.7 kV mm−1, respectively, increasing by 33.1, 8.1, and 1.1 times compared with those parameters of the original paper (3.43 MPa, 0.60 GPa, and 30.5 kV mm−1). Moreover, the composite paper also exhibits an ultra-low dielectric constant and loss tangent (1.6 and 0.004 at 106 Hz, respectively), as well as superhigh thermal stability (maximum decomposition temperature, Tmax ≈ 600 °C) due to the elaborate design of the structure. Thus, the mechanical strength has been successfully integrated with the outstanding insulation and thermal properties, rendering the lightweight PBO composite paper promising in the field of high-temperature and high-voltage electrical insulation. [ABSTRACT FROM AUTHOR]

Mechanical properties of fiber-based materials, such as paper, are governed by the heterogeneous microstructure induced by the formation process. For example, in paper materials during tensile tests, lower strains are observed in the flocs (fiber aggregates where the basis weight is larger than the average one) than in the antiflocs (complement of flocs). To explain such behavior, we investigated the mechanical and structural properties of both flocs and antiflocs. Using tensile tests on flocs and antiflocs, we measured their elastic modulus and found that the elastic modulus of flocs was larger than the antiflocs' one. To understand these differences, a multiscale structural analysis was conducted on 3D X-ray images of flocs and antiflocs at two different spatial resolutions. We found that the floc was thicker than the antifloc, whereas the microscale analysis showed the studied floc and antifloc exhibited the same bulk porosity. Then, it was concluded that the difference in elastic modulus between flocs and antiflocs is mainly due to their thickness difference. [ABSTRACT FROM AUTHOR]

Carbon fiber paper (CFP) has been widely investigated as a gas diffusion layer for high-performance fuel cells, while the paper formation, one of the most important properties of CFP, has been rarely reported before owing to the lack of accurate characterization methods. Herein, using a 2D laboratory sensor, a quantitative analysis was conducted to comprehensively analyze CFP formation, carbon fiber (CF) flocs and their influencing factors. Within the study scope of this paper, improved paper formation was always accompanied with a smaller floc area and a lower ratio of large-size flocs for CFP prepared with the same length of CF. CF was too long negatively affected paper formation, as the look-through index rose from 282 (2 mm CF) to 940 (8 mm CF). Either using polyethylene oxide as a disperser or reducing the CF concentration could reduce the look-through index of the CFP (2 mm CF) to below 200. The crowding factor of the CF suspension was suggested to be no more than 5. In addition, improvement in CFP formation led to higher tensile strength and lower air permeability in CFP. All these results are expected to prepare CFP with superior formation, thereby improving other properties of CFP. [ABSTRACT FROM AUTHOR]

Influence of the ion irradiation at elevated temperatures on the novel preceramic paper-derived SiCf/SiC laminated composites fabricated by spark plasma sintering was investigated. The composites were subjected to high-dose simultaneous irradiation of silicon (Si) ions at 400 °C. Irradiation induces amorphization of the damaged area up to 30 dpa, and then recrystallization of amorphous regions with increasing dose occur. No evidence of cavities was found in SiCf/SiC composites irradiated by silicon ions up to 100 dpa. The irradiated composites pre-injected with 5000 appm He displays low swelling (~ 0.3%). The irradiation with Si ions may suppress the cavity nucleation and they growth in SiC layers. [ABSTRACT FROM AUTHOR]

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The December 2023 cover paper of the Journal of Materials Science features a study by Xie and Luo from Chongqing Jiaotong University in China. The paper, included in the "Computation & Theory" Topical Collection, focuses on the use of carbon fiber-reinforced polymer (CFRP) for construction projects. The authors aim to provide insights into the transport behavior of liquids in epoxy-modified C–S–H pores in cement-based materials, combining MD simulations with experimental measurements. Xie is currently pursuing a master's degree in civil engineering, while Prof. Luo is an associate professor at Chongqing Jiaotong University and a researcher at Aarhus University in Denmark, with a focus on reducing the carbon and energy footprint of civil engineering materials and infrastructure. The paper is published open access and can be widely shared with readers using the provided link. [Extracted from the article]

The June 2024 cover image of the Journal of Materials Science features a paper by Liss et al. titled "Recrystallization of bulk nanostructured magnesium alloy AZ31 after severe plastic deformation: an in situ diffraction study." The image is an artistic representation of nanostructured magnesium alloy AZ31 undergoing heating, showcasing the process of recrystallization in reciprocal space. The paper is part of a Special Issue on "Processing Bulk Nanostructured Materials," which includes a total of 28 articles covering various aspects of severe plastic deformation (SPD) in the processing of bulk nanostructured materials. The Special Issue aims to highlight the enduring significance and resilience of research in this field. Both the paper and the preface of the Special Issue have SharedIt links for easy sharing with readers. [Extracted from the article]

The May 2024 issue of the Journal of Materials Science features a cover paper titled "Role of stacking fault energy in confined layer slip in nanolaminated Cu" by Ji et al. The paper explores the deformation of metallic nanolaminates and acknowledges the contribution of Professor Hussein Zbib. The issue is dedicated to honoring Professor Zbib's memory and was conceived by Guest Editors Tariq Khraishi, Georges Ayoub, Sinisa Mesarovic, and Mutasem Shehadeh. The paper includes references to previous work but does not mention any measurements of the intrinsic stacking fault energy. The corresponding author is Professor Shuozhi Xu from the University of Oklahoma, and the last author is Professor I.J. Beyerlein, who has a background in research and was born in Los Alamos. The paper is freely accessible through the SharedIt link provided. [Extracted from the article]

The April 2024 issue of the Journal of Materials Science features a cover paper titled "Self-assembled NIPAM-PEG-NIPAM polymeric nanomicelles for the delivery of zinc protoporphyrin: a potential stimuli-triggered cancer treatment approach" by Bagheri-Meyabad et al. The paper, which is part of the "Materials for Life Sciences" Topical Collection, explores the use of nanomicelles for drug delivery. The corresponding author, Professor Rassoul Dinarvand, is based in Iran and has a strong research background in materials for life sciences. The paper is freely available online and includes supplementary information. [Extracted from the article]

The flame resistance of kraft paper was greatly modified by an eco-friendly, phosphorus-containing and reactive flame retardant, ammonium phosphite, which was grafted on kraft paper via pad-bake method. The results showed that the limiting oxygen index of treated kraft paper could increase from 19.1 to 48.2%. The results of vertical flammability tests imply that the char length of treated sample decreased from 210 to 45 mm. Thermogravimetry analysis showed that treated kraft paper had the lower initial decomposition temperature and more residues than control sample. Thermogravimetry analysis/infrared spectrometry indicated that the flammable volatile species of treated kraft paper reduced obviously compared with that of control sample. Fourier transform infrared spectroscopy suggested that ammonium phosphite was grafted on the cellulose molecules by P-O-C covalent bonds and the flame retardant is reactive in condensed phase. Scanning electron microscopy showed that the modification had little effect on the surface of kraft paper and the residual carbonized frame of treated kraft paper retained the fiber shape after combustion. EDX results showed that the flame retardant introduced a large amount of phosphorus and nitrogen into kraft paper. X-ray diffraction indicated that the modification did not significantly affect the crystal structure of kraft paper. And the strength of kraft papers slightly declined after the modification, but it still remained well. [ABSTRACT FROM AUTHOR]

We report on a corroborative study of the structural, morphological and electrical property alterations of free-standing graphene oxide (GO) papers subject to thermal reduction. Structural analysis performed using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) and Raman techniques prove that the onset of major structural changes, characterized by removal of oxygen functionalities, occur in the 200–300 °C temperature range. The results are corroborated with related morphological changes observed using Scanning electron microscopy (SEM) and Atomic force microscopy (AFM) imaging. Elemental analysis shows the GO paper reduced at 600 °C to contain an 85 wt. % carbon content and a remnant oxygen level of 13.31 wt. %. At the highest reduction temperatures, we see evidence of vacancy-type defects impeding the overall effectiveness of the reduction process. Detailed electrical resistance measurements and current–voltage (I-V) profiling conducted using four-point probe method reveals a several orders of magnitude drop in the sample resistance once the reduction temperature exceeds 200 °C, in good agreement with the structural and morphological changes. The fundamental insights revealed through these studies will be important for future applications where the electrical and mechanical properties of free-standing GO and reduced graphene oxide (rGO) are exploited in practical devices. [ABSTRACT FROM AUTHOR]

Excellent mechanical and electrical properties of graphene-based paper-like materials are essential for applications in flexible conductors, energy-storage devices, etc. The graphene oxide (GO) supernatant separated by centrifugation and ultrasonication has been used to prepare graphene oxide paper and reduced graphene oxide paper (rGOP) with high strength and conductivity. However, this method has cumbersome steps and low supernatant concentration, which greatly increases time and energy consumption, and is not suitable for rapid batch preparation of high-strength and high-thickness rGOP. Herein, a high-speed mechanical shearing method has been used to efficiently exfoliate graphite oxide suspension into high-concentration GO slurry with large lateral size, and rGOP has been further prepared by blade coating and HI acid chemical reduction. Compared with the product prepared by ultrasonic exfoliation method, the average area of GO sheets obtained via the mechanical shear exfoliation method can reach around 16.31 μm2. As a result, the mechanical properties and conductivity of the prepared rGOP have been increased by 30% and 23.5%, respectively, with the tensile strength and electrical conductivity of 478.2 MPa and 208.4 S/cm being obtained. The developed method is of great significance for the large-scale production and emerging applications of lightweight and high-performance rGOP. [ABSTRACT FROM AUTHOR]

It remains a challenge to prepare special engineering paper with excellent mechanical properties, high temperature resistance and chemical resistance. The emergence of high-performance fiber provides support for the technical progress of special engineering paper. Herein, a novel method to obtain a novel self-reinforced poly (ether ether ketone) (PEEK) composite paper (SR-DI-PEEK/paper) by vacuum filtration, impregnation and hot pressing. Specially, PEEK fibers were used as the skeleton fiber and a small amount of aramid pulp was added as the decanted fiber. By optimizing the process of SR-DI-PEEK/paper preparation, the best mechanical properties of SR-DI-PEEK/paper was presented. Compared with the composite paper prepared with Phenolic solution (PF-PEEK/paper) and Polyimide solution (PI-PEEK/paper), the mechanical properties of SR-DI-PEEK/paper was significantly improved. In particular, when the concentration of impregnation was 3 wt%, the tensile index of SR-DI-PEEK/paper reached 51.10 N m g−1 (tensile strength 47.16 kN m−1), which is 16.48 times than that of the un-impregnated PEEK/paper (2.86 kN m−1). SR-DI-PEEK/paper also exhibited excellent chemical resistance among acid, alkali, and polar solvents, while the tensile index maintained 96.3% after 40 wt% H2SO4 treatment. Besides, SR-DI-PEEK/paper showed superior thermal performance, while the temperatures corresponding to the weight loss of 5% were 574 °C. [ABSTRACT FROM AUTHOR]

Highly flexible electromagnetic interference (EMI) shielding material with excellent shielding performance is of great significance to practical applications in next-generation flexible devices. However, most EMI materials suffer from insufficient flexibility and complicated preparation methods. In this study, we propose a new scheme to fabricate a magnetic Ni particle/Ag matrix composite ultrathin film on a paper surface. For a ~ 2-µm-thick film on paper, the EMI shielding effectiveness (SE) was found to be 46.2 dB at 8.1 GHz after bending 200,000 times over a radius of ~ 2 mm. The sheet resistance (R□) remained lower than 2.30 Ω after bending 200,000 times. Contrary to the change in R□, the EMI SE of the film generally increased as the weight ratio of Ag–Ni increased, in accordance with the principle that EMI SE is positively related to an increase in electrical conductivity. Desirable EMI shielding ability, ultrahigh flexibility, and simple processing provide this material with excellent application prospects. [ABSTRACT FROM AUTHOR]

The use of cyclopropenone derivatives as latent photo-released strained cyclic alkynes is reported for the covalent printing of complex patterns on cellulose paper. Two different approaches using either a UV LED or a laser as light irradiation source are discussed. While the high intensity of the laser damages the grafted molecular layer, the use of a simple UV LED allows the printing in only 8 min at room temperature with a good resolution at the micrometer scale with negligible diffusion. The validity of this strategy is demonstrated through the sequential printing of a QR code and a logo on the same paper sheet. [ABSTRACT FROM AUTHOR]

We described a new concept, carbon paper-free membrane electrode assembly (MEA) fabricated from Nafion membrane and multi-walled carbon nanotubes-based electrocatalyst, in which platinum nanoparticles were deposited on carbon nanotubes after coating with pyridine-polybenzimidazole (PyPBI). Polymer-coated carbon nanotubes served as platinum nanoparticles support and current collector in carbon paper-free MEA. The fabricated carbon paper-free MEA was systematically studied by in situ cyclic voltammetry, SEM and fuel cell test. Pt utilization efficiency of carbon paper-free MEA improved with decreasing in Pt loading and reached 62% with 0.1 mg cm. Meanwhile, the mass power density reached 1.1 W mg, which was comparable to that of MEA with carbon paper. Fuel cell performance maintained 50% after 100000 startup-shutdown cycles, suggesting that carbon paper-free MEA was applicable in real fuel cell operation. To the best of our knowledge, this is the first study of carbon paper-free MEA in polymer electrolyte fuel cells. [ABSTRACT FROM AUTHOR]

Multiwalled carbon nanotubes (MWNT) were deposited via dropcasting and dried using vacuum filtration. Because of the slightly larger pore size (5–10 µm) of the paper substrate used as compared to the length of the nanotubes (0.5–2 µm), a variety of MWNT networks were formed both on the surface and through the thickness of the paper. Using a combination of impedance spectroscopy, equivalent circuit modeling, and microscopy techniques, it was possible to describe in detail how the electrical properties change as a function of how the MWNTs are distributed on the porous substrate by varying the number of deposited layers (1–20) as well as the dispersion concentration (0.1–5 mg/mL). In the in-plane, four different electrical responses were observed and modeled: (1) a substrate dominated spectrum representing unconnected MWNTs, (2) one that included bundle and junction responses as well as some inductances representing sparsely distributed MWNT networks, (3) followed by a parallel RL circuit for partially connected MWNT networks, and (4) finally a series RL circuit for fully connected MWNT networks. In the thru-plane, only two different electrical responses were observed and modeled. The results for the in-plane and thru-plane properties were used to generate percolation curves that show that electrical conductivity can change as much as 10 orders of magnitude for the same exact MWNTs. These results indicate that not only do the characteristics of the nanotubes themselves play a role but also the structure of the underlying substrate and the details of how the films are deposited. [ABSTRACT FROM AUTHOR]

Sulfur quantum dots are promising alternatives for traditional heavy metal-containing quantum dots due to their benign chemical properties and low cytotoxicity. Herein, cysteine-decorated sulfur dots were prepared from facile modification of pristine sulfur dots and can be acted as a chemosensor for the fluorometric and colorimetric dual-channel detection of cobalt (Co2+) with high sensitivity and selectivity. Visual colors of the as-prepared chemosensor in the presence of Co2+ changed from blue to colorless under UV light and also can transform from colorless to yellow under sunlight based on the photoinduced electron transfer effect. The detection limit of cysteine-decorated sulfur dots toward Co2+ was determined as low as 0.16 μM with a wide detection range, which is lower than the permitted guideline level by Department of Environmental Protection for drinking water (1.7 μM). Furthermore, portable paper sensor-based cysteine-decorated sulfur dots were fabricated for Co2+ detection and showed superior detection ability. Aided by a common smartphone as detector, the rapid, on-site and accurate quantification of Co2+ in real water samples can be accomplished. Our research has provided a novel chemosensor based on sulfur dots for dual-channel detection of Co2+, which would expand applications of sulfur dots in environmental monitoring, diseases diagnosis, cell imaging, light-emitting diodes, etc. Cysteine-decorated sulfur dots were acted as a chemosensor for fluorometric and colorimetric dual channel detection of Co2+ based on the photoinduced electron transfer effect. [ABSTRACT FROM AUTHOR]

Three types of carbon nanotubes coated on paper-like sintered stainless steel fibers (PSSF) were synthesized and applied for continuous catalytic wet hydrogen peroxide oxidation (CWPO) of phenol. The novel metal-free nitrogen-doped carbon nanotube-coated PSSF catalyst (N-CNTs/PSSF) was designed by direct chemical vapor deposition using melamine as solid precursor for the first time, and CNTs/PSSF and Fe2O3-deposited CNTs/PSSF (Fe-CNTs/PSSF) catalysts were synthesized for comparison. Characterization results showed that all the catalysts exhibited three-dimensional networks structure, with nanotubes wrapping on the stainless steel fibers successfully, and the N-CNTs showed distinct irregular corrugated morphology with nitrogen-doping level about 5.18 at.%. CWPO of phenol revealed that the N-CNTs/PSSF catalyst achieved favorable catalytic activity and highest stability during 100-h reaction (phenol and TOC conversions reached about 90% and 50%, respectively), while phenol conversions of CNTs/PSSF and Fe-CNTs/PSSF catalysts decreased over time to 72% and 58%, respectively. The N-CNTs/PSSF catalyst also showed the lowest Fe weight loss ratio (about 2.44 wt%) among the three catalysts. The favorable catalytic results of N-CNTs/PSSF can be ascribed to the synergistic effects of the strong affinity toward polar molecules of N-CNTs, as well as the enhancement in contact efficiency associated with three-dimensional networks structure of the PSSF. [ABSTRACT FROM AUTHOR]

The February 2024 issue of the Journal of Materials Science features a cover paper titled "Enhancing the impact property of high-entropy alloys with graphene layers: a molecular dynamics study" by Qing-Xiang Pei et al. The paper explores the use of molecular dynamics simulations to study the impact of a projectile on a high-entropy alloy (HEA) containing layers of graphene. The authors highlight the broad interest in their research, as it appeals not only to the modeling community but also to other communities interested in the materials being modeled. The paper provides valuable insights into the behavior of composite materials and includes figures illustrating the preparation of the model material and the interaction between a projectile and the HEA. The article is freely accessible through the SharedIt link provided, and the corresponding authors can be contacted for access to the data. The publisher, Springer Nature, maintains a neutral stance on jurisdictional claims and institutional affiliations. [Extracted from the article]

The text is an editorial from the Journal of Materials Science discussing a cover paper titled "High-performance, water-resistant and ion-conducting gel used as underwater ECG electrodes" by Shi et al. The paper addresses the challenges of sensing underwater and describes the synthesis and characterization of a single-layer hydrogel electrode that is resistant to swelling in water. The paper is accessible to non-experts and includes photographs, curves, and electrocardiograms to support the findings. Although the article is not open access, it can be accessed through a SharedIt link provided by the publisher. [Extracted from the article]

The hydrogel in this paper is designed to do just that, by using controlled release from a hydrogel to deliver the drug quickly and at a relatively high concentration to the interior of cancer cells. The paper describes the synthesis and in-vitro testing of a hydrogel composite that is designed to maximize toxicity to cancer cells by both efficiently delivering the cancer drug doxorubicin (DOX) and overheating the cells with magnetically induced hyperthermia. This makes it highly desirable to develop a delivery system that can encapsulate the drug, bring the drug directly to the cancer cells then release the drug into the cancer tumor or cells. [Extracted from the article]

Paper-based packaging materials are generally assembled using adhesives formulated with oil-based polymers. These adhesives make the recyclability of the materials more complex and may be the source of material contamination by mineral oil. In view of developing an adhesive-free process, the potential of ultrasonic compression was investigated in this study. 100% lignocellulosic papers were assembled using an ultrasonic welder dedicated to thermoplastic polymers. For papers containing lignin, the measured peeling strengths were equivalent to those achieved by hot-melt gluing, provided that the water content of papers was well adjusted. At the interface between bonded papers, the fiber network was dense and rather continuous. SEM examinations, 3D X-ray microtomography images, and temperature measurements suggested that the development of adhesion originated to a large extent from a thermoplastic welding mechanism: wood fiber polymers passed their glass transition temperatures, creeped and formed a matrix that coated fibers. Thus, ultrasonic welding appears as an efficient adhesive-free technique for assembling papers that are used in a broad range of packaging applications. [ABSTRACT FROM AUTHOR]

As the development of dual-ion batteries (DIBs) is limited by the capacity of anions intercalation, we put forward an innovative design idea of DIB. Compared with the traditional graphite cathodes, few-layered reduced graphene oxide (rGO) has a large specific surface area and can greatly improve the utilization ratio of carbon layers for fast redox reaction process. In addition, the carbon paper current collector with porous network structure facilitates the uniform distribution of active materials, rapid penetration of electrolyte and fast migration of ions, and also relieves the volume strain caused by PF6− intercalation/de-intercalation. Under the effects of the above two aspects, the lithium-rGO DIB demonstrates significantly enhanced electrochemical performance compared with conventional DIBs. It possesses an ultra-high discharge capacity of 405 mA h g−1 with a coulombic efficiency of > 98% after 1000 cycles at 1 A g−1 in the voltage range of 3.0–5.0 V. The detailed mechanism of electrochemical performance enhancement is also discussed. [ABSTRACT FROM AUTHOR]

Herein, an eco-friendly and straightforward method was provided for the fabrication of superhydrophobic paper from native wood cellulose fibers via in situ hydrolysis of tetraethyl titanate(IV) without any chemical pretreatment. By simply adjusting the amount of acetic acid (HAc), the surface micro/nanomorphology could be well controlled. After papermaking and hexadecyltrimethoxysilane modification, superhydrophobic paper can be easily achieved with static water contact angle of 152.3° (± 1.3°). The paper also possessed good self-cleaning property against contamination and durability toward mechanical damages of finger wiping over 50 cycles as well as excellent oil/water separation, which expands its utility in various paper-based technologies. The whole procedure possesses the advantages of friendly raw material, mild reaction conditions and with no toxic modifier, which hold potential application in cellulose-based superhydrophobic material in large scale. [ABSTRACT FROM AUTHOR]

Electromagnetic interference (EMI) shielding materials with high performance and low density are urgently needed with the rapid development of electronic communications. In this work, tuning solid–air interface of graphene paper was carried out to enhance multiple reflections of incident electromagnetic waves for high-performance EMI shielding. The large amount solid–air interface (57.8 m2 g−1) endowed the porous graphene paper with a high EMI shielding effectiveness (SE) of 31.0 dB, 50% enhancement from its counterpart of solid graphene paper. This porous graphene paper also showed an ultralow density of 0.02 g cm−3, an 18.5-fold decrease from its counterpart of solid graphene paper. Moreover, the EMI SE of obtained graphene papers exhibited proportional relationship with their specific surface area, further confirming the vital role of solid–air interface in the enhancement of EMI shielding. This work quantitatively demonstrates the significance of solid–air interface area for enhancing the EMI shielding performance and proposes an efficient guideline for the design of high-performance and low-density EMI shielding materials. [ABSTRACT FROM AUTHOR]

The disappearance of bibliographic heritage is one of the biggest problems facing libraries. One of the most common methods used to restore paper, lining, is to apply a reinforcing layer to the document. This study focuses on lining papers with bacterial cellulose (BC) sheets from Gluconacetobacter sucrofermentans. For this purpose, several model papers have been selected. They have been characterized before and after the lining with this BC and a specific Japanese paper (JP) to compare both materials. Taking into account the differences between bacterial and vegetal cellulose is expected that the results may be similar to other BC and JP. The samples have been characterized before and after an aging process. There are no significant differences in some of the characteristics studied. Nevertheless, BC-lined papers present higher gloss values and b* coordinate. The wettability decreases with both BC and JP. However, in papers lined with BC, the wettability decreases more markedly and independently of the model paper used. This is related to the sealing of the surface structure by BC, which also leads to a reduction of air permeability. When the lined papers go through an aging process, there are no significant changes in any characteristic, except in b* and L* color coordinates. Additionally, the wettability rate decreases in all cases. This study indicates that papers lined with BC are stable over time. Finally, the use of BC as reinforcing material may offer advantages for specific conservation treatments, being more suitable for certain types of paper than JP. [ABSTRACT FROM AUTHOR]

Professor Grimes summarizes the winning paper and the two runners-up:"Machine learning is certainly of great current interest to address the multivariable materials design challenge. 10.1007/s10853-022-07499-9 5 Wang Z, Lai A, Schuh CA, Radovitzky R. Phase transformation and incompatibility at grain boundaries in zirconia-based shape memory ceramics: a micromechanics-based simulation study. The winner of the 2022 Robert W. Cahn Best Paper award is "Machine learning guided alloy design of high-temperature NiTiHf shape memory alloys" by Udesh M.H.U. Kankanamge, Johannes Reiner, Xingjun Ma, Santiago Corujeira Gallo, and Wei Xu. [Extracted from the article]

Preservation of documentary heritage is one of the biggest challenges facing paper conservators today. The singular properties of bacterial cellulose (BC) lead us to propose to reinforce paper with BC sheets. In the first part of this study, the reinforcing capability of BC was tested on model papers of well-known fiber composition. The aim of the present study was to verify the suitability of rebuilding degraded old papers with BC. The degraded papers were characterized before and after the reinforcement. In addition, lined samples were characterized before and after an aging process in order to study the stability in time. The same methodology was used with Japanese paper (JP), a material commonly used by paper conservators, in order to compare both materials as reinforcement. Mechanical properties of paper lined with BC are as good as those obtained with JP. Papers lined with BC have more marked modifications on their optical properties than those restored with JP. Nevertheless, letters in books lined with BC are more legible. Moreover, only the papers restored with BC show high changes in porosity. The aging process leads to a slight decrement in burst index. Changes on tear index and optical properties with the aging process depend on the paper to be restored. This study suggests that BC improves deteriorated paper quality, without altering the information contained therein, and that this improvement is maintained over time. Hence, BC is a promising alternative material for the restoration of paper. [ABSTRACT FROM AUTHOR]

Of course, the paper complements the SEM imaging, which is intrinsic to the FIB, with imaging and diffraction in the TEM. The paper does also have a SharedIt link like all articles in JMS (https://rdcu.be/cWW0L) so it can be widely and immediately shared with readers; all papers published in JMS are free-to-read using the SharedIt link from the moment they appear online with their permanent DOI. The cover for the November 2022 issues of the Journal of Materials Science comes from the paper by Tunes et al. which appeared in issue #35 from September 2022 [[1]]. [Extracted from the article]

Based on surface science, adsorption of mineral oil, water, gas products (typified by CO2 and CH4), and acids (typified by formic acid) on meta-aramid insulation paper has been investigated by molecular dynamics simulations. When the adsorption process finishes, the free volume fraction in the crystalline region is very small owing to the stable molecular arrangement of fiber. In addition, the number of pores on the surface of the meta-aramid fiber and the pore size are small, and the stable configuration of hydrogen bonds plays an important role, so it is difficult for the mineral oil and aging products to enter the meta-aramid crystalline region. The irregular arrangement of molecules in the amorphous region means that it is easier for the mineral oil and aging products to enter the amorphous region than the crystalline region, and the influence of these substances on the amorphous region is greater than that on the crystalline region. The order of the adsorption strengths of the four types of aging products on meta-aramid fiber is formic acid > water > CO2 > CH4. Therefore, it is necessary to monitor the acid and water contents in transformers with meta-aramid insulation paper as the solid insulation material. [ABSTRACT FROM AUTHOR]

Flexible graphene-based paper is promising for wide applications due to its outstanding electrical and thermal conductivities. Graphene flakes with large size are usually known as the key factor for improved paper performance. However, we find that a combination of flakes with large and small sizes is more favorable for both electrical and thermal conductivities than pure large flakes. In this work, flexible paper with enhanced electrical and thermal properties was fabricated by mixing graphene flakes with various size distributions. Large-size graphene (LSG) flakes play the role of a backbone structure, whereas small-size graphene (SSG) flakes fill the voids in the paper without disturbing the high orientation. The physical properties of the as-prepared graphene papers with contents of SSG varying from 0 to 100% have been investigated. It is found that the electrical and thermal conductivities of the paper with 25 wt% SSG are both around 140% higher than that of pure LSG paper. Our results indicate that the lightweight and flexible graphene-based paper has great potential for lateral heat dissipation applications requiring heat movement in a particular direction. [ABSTRACT FROM AUTHOR]

We present a theory giving the standard roughness metrics R a and R q of stochastic fibrous materials in terms of their porosity and the thickness of the constituent fibres. Our treatment shows also that R a and R q are linearly dependent on each other with gradient depending on the skewness of the surface depth profile. Comparison of our theory with experiments on laboratory-formed paper samples and with data from the literature for industrially manufactured paper and carbon fibre nonwovens for use in fuel cells is excellent. The theory has applicability to generic families of stochastic fibrous materials and has relevance, for example, to printing of devices on paper. [ABSTRACT FROM AUTHOR]

Twinning is an important deformation mechanism for magnesium alloys, which has a significant impact on the texture evolution and mechanical properties. Pre-twinning deformation has been considered as an effective method for texture regulation. For each twinning mode, there are six crystallographically equivalent variants. Properly identifying the activated twin and understanding its variant selection criteria are essential for the development of high-performance magnesium alloys. As summarized in this paper, the observed twin variant by the commonly employed electron backscatter diffraction technique can be identified by several approaches, including misorientation analysis, trace analysis and matrix method. Schmid factor analysis was commonly performed to explain the selection of twin variants. To broaden the application scope under complex stress state, a generalized Schmid factor was derived by introducing a stress tensor. The efficiency of Schmid criteria to assess twin variant selection was confirmed to be influenced by the type of the applied stress. To consider the local effect on twin activation, in particular twin-twin transfer and slip-induced twinning, displacement gradient tensor calculation and geometrical compatibility factor analysis have been employed. It was demonstrated that local strain accommodation played a critical role in selecting the variants of cross-boundary twins in magnesium alloys. Assisted with crystal plasticity finite element modeling, the resolved shear stress on twinning and a composite Schmid factor combining the global Schmid factor and geometrical compatibility factor were obtained to better explain the activated twin variants in magnesium alloys. All the above-mentioned Schmid law based criteria and some energy based criteria as well are summarized in this paper. Their applications in evaluating twin variant selection in magnesium alloys are critically reviewed and discussed. [ABSTRACT FROM AUTHOR]