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The absorption air-conditioning system is a low-power-consumption and low-noise system and is also good at balancing the electricity peak-valley system. It can be driven by low-grade energy, such as solar energy and industrial exhaust heat. The nanofluids, which possess the superior thermophysical properties, exhibit a great potential in enhancing heat and mass transfer. In this paper, nanofluids of H2O/LiBr with Fe3O4 nanoparticles were introduced into absorption air conditioning system. The effects of critical parameters, such as the flow rate of H2O/LiBr nanofluids, nanoparticle size and mass fraction, on the falling film absorption were investigated. The H2O/LiBr nanofluids with Fe3O4 nanoparticle mass fractions of 0.01 wt %, 0.05 wt % and 0.1 wt %, and nanoparticle sizes of 20 nm, 50 nm and 100 nm were tested. The results imply that the vapor absorption rate could be improved by adding the nanoparticles to H2O/LiBr solution. The smaller the nanoparticle size, the greater the enhancement of the heat and mass transfer. The absorption enhancement ratio increases sharply at first by increasing the nanoparticle mass fraction within a range of relatively low mass fraction and then exhibits a slow growing even reducing trends with increasing the mass fraction further. For Fe3O4 nanoparticle mass fraction of 0.05 wt % and nanoparticle size of 20 nm, the maximum mass transfer enhancement ratio is achieved about 2.28 at the flow rate of 100 L h−1. Meanwhile, a fitting formula of mass transfer enhancement ratio for Fe3O4 nanofluids has been improved.

As a relatively new type of functional material, porous graphite foam exhibits unique thermophysical properties. It possesses the advantages of low density, high specific surface area, and high bulk thermal conductivity and could be used as the core component of compact, lightweight, and efficient heat exchangers. Effective thermal conductivity serves one of the key thermophysical properties of foam-based heat exchangers. The complex three-dimensional topology and interstitial fluids significantly affect the heat conduction in the porous structure, reflecting a topologically based effective thermal conductivity. This paper presents a novel geometric model for representing the microstructure of graphite foams with simplifications and modifications made on the realistic pore structure, where the complex surfaces and tortuous ligaments were converted into a simplified geometry with cylindrical ligaments connected between cuboid nodes. The multiple-layer method was used to divide the proposed geometry into solvable areas, and the series–parallel relation was used to derive the analytical model for the effective thermal conductivity. To explore heat conduction mechanisms at the pore scale, direct numerical simulation was also conducted on the realistic geometric model. Achieving good agreement with experimental data, the simplified geometric model was validated. The numerically simulated conductivity followed the simplified model prediction that the two geometries are equivalent from thermal aspect. It validates further that the simplified model is capable of reflecting the internal microstructure of graphite foam, which would benefit the understandings of the thermophysical mechanisms of pore-scaled heat conduction and microstructures of graphite foam.

Highly conductive porous media have recently been considered for enhanced cooling applications due to their large internal contact surface area, which promotes convection at the pore level. In this paper, graphite foams that possess high thermal conductivity but low permeability are investigated for convection heat transfer enhancement using air as coolant. Two novel heat sink structures are designed to reduce the fluid pressure drop. Both experimental and numerical approaches are adopted in the study. The experimental data show that the designed structures significantly reduce flow resistance in graphite foams while maintaining relatively good heat removal performance. The numerical results obtained based on the local thermal nonequilibrium model are validated by experimental data and show that the inlet air flow partially penetrates the structured foam walls, while the remaining air flows tortuously through slots in the structure. Flow mixing, which is absent in the block graphite foam, is observed in the freestream area inside the designed structure. It can be concluded that graphite foams with appropriately designed structures can be applied as air-cooled heat sinks in thermal management applications.