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Understanding of characteristics and transport of perfluoroalkyl acids (PFAAs) in heterogeneous estuarine environments is limited. Furthermore, the role of suspended particles (SPS) in different layers remains unclear. This study explores the multiphase distribution process and mechanism of PFAAs controlled by SPS across surface and bottom layers in five small estuaries. Peaks in PFAA concentrations are consistently observed at strongly stratified sites. Concentrations of the PFAAs in both surface and bottom SPS decreased as the degree of mixing increased from strongly stratified levels to well-mixed levels. The water-SPS partitioning of some short-chain PFAAs (PFBS, PFHxA, and PFHpA) is influenced by environmental factors (pH, depth, temperature, and salinity) due to electrostatic interactions, while the sorption of some long-chain PFAAs (PFOA, PFOS, and PFNA) is controlled by SPS and dissolved organic carbon (OC), driven by hydrophobic interactions. Additionally, SPS dominates OC transport in estuarine systems, except in sandy sediment environments. SPS plays a dominant role in PFAA partitioning in both surface and bottom water-SPS systems (p < 0.05), and salinity only significantly affects PFBS in bottom layer (p < 0.01). These findings are critical for understanding the drivers of PFAA partitioning and the roles of SPS in different layers, underscoring the necessity of considering particle-associated PFAA fractions in future coastal environmental management., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Microplastics and nanoplastics are ubiquitous in rivers and undergo environmental aging. However, the molecular mechanisms of plastic aging and the in-depth effects of aging on ecological functions remain unclear in waters. The synergies of microplastics and nanoplastics (polystyrene as an example) with natural organic small molecules (e.g., natural hyaluronic acid and vitamin C related to biological tissue decomposition) are the key to producing radicals (•OH and •C). The radicals promote the formation of bubbles on plastic surfaces and generate derivatives of plastics such as monomer and dimer styrene. Nanoplastics are easier to age than microplastics. Pristine plastics inhibit the microbial Shannon diversity index and evenness, but the opposite results are observed for aging plastics. Pristine plastics curb pectin decomposition (an indicator of plant-originated refractory carbon), but aging plastics promote pectin decomposition. Microplastics and nanoplastics undergoing aging processes enhance the carbon biogeochemical cycle. For example, the increased carbohydrate active enzyme diversity, especially the related glycoside hydrolase and functional species Pseudomonas and Clostridium, contributes to refractory carbon decomposition. Different from the well-studied toxicity and aging of plastic pollutants, this study connects plastic pollutants with biological tissue decomposition, biodiversity and climate change together in rivers., Competing Interests: Declaration of Competing Interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: Xiangang Hu reports financial support was provided by the 111 Program. Xiangang Hu reports a relationship with the 111 Program that includes: funding grants. If there are other authors, they declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

In order to mitigate the hazards of water pollution in drinking water source areas (DWSAs), developing applicable models and proposing effective solutions is of paramount significance. The study developed the Heshangshan Drinking Water Source Area (HDWSA) Hydrodynamic Model, integrating Geographic Information System (GIS) into a two-dimensional hydrodynamic water quality model using FORTRAN. TECPLOT360 software (Software Tools for Numerical Simulation with Visualization) visualized contamination transportation and diffusion. The model's relative error is less than 6%, indicating its strong stability and high reliability. The HDWSA in the Three Gorges Reservoir Area (TGRA) was used as a case study, focusing on copper (Cu) as a pollutant. By regulating the flow downstream from the Xiangjiaba Reservoir, Scheduling Group 1 and Scheduling Group 2 respectively increased the flow by 4000 m 3 /s and 8000 m 3 /s. The study analyzed the spatio-temporal variations of Cu concentration following pollution accident and flow scheduling. Under accident conditions, it took 71, 61, 49, and 56 min for the Cu concentration in the study area to decrease to below the standard value (1 mg/L) during dry, falling, flood, and storage periods. Scheduling Groups 1 and 2 reduced the pollutant exceedance duration by 19-26 min and 12-18 min across the four water periods., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

Wastewater is among the main sources of antibiotic resistance genes (ARGs) in the environment, but effective methods to quickly assess ARGs on-site in wastewater are lacking. Here, using the typical ARG ermB as the target, we report a portable biosensor combining CRISPR/Cas12a and loop-mediated isothermal amplification (LAMP) for the detection of ARGs. Six primers of LAMP and the crRNA of CRISPR/Cas12a were first designed to be preamplification with LAMP and lead Cas12a to recognize the ermB via base pairing. Due to the trans-cleavage activity of CRISPR/Cas12a after amplicon recognition, ssDNA probes modified with reporter molecules were used to implement a visual assay with lateral flow test strips and fluorescence. After a simple nucleic acid extraction with magnetic beads, the constructed biosensor possesses excellent sensitivity and selectivity as low as 2.75 × 10 3 copies/μL using fluorescence and later flow strips in wastewater. We further evaluated the community-wide prevalence of ermB in wastewater influent and found high mass loads of ermB during different months. This user-friendly and low-cost biosensor is applicable for rapid on-site ARG detection, providing a potential point-of-use method for rapid assessments of ARG abundance in wastewater from large city areas with many wastewater treatment plants and in resource-limited rural areas., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

Arsenic is a ubiquitous environmental toxi substance that affects human health. Compared to inorganic arsenicals, reduced organoarsenicals are more toxic, and some of them are recognized as antibiotics, such as methylarsenite [MAs(III)] and arsinothricin (2-amino-4-(hydroxymethylarsinoyl)butanoate, or AST). To date, organoarsenicals such as MAs(V) and roxarsone [Rox(V)] are still used in agriculture and animal husbandry. How bacteria deal with both inorganic and organoarsenic species is unclear. Recently, we identified an environmental isolate Mucilaginibacter rubeus P2 that has adapted to high arsenic and antinomy levels by triplicating an arsR-mrarsU Bact -arsN-arsC-(arsRhp)-hp-acr3-mrme1 Bact -mrme2 Bact gene cluster. Heterologous expression of mrarsM Bact , mrarsU Bact , mrme1 Bact and mrme2 Bact , encoding putative arsenic resistance determinants, in the arsenic hypersensitive strain Escherichia coli AW3110 conferred resistance to As(III), As(V), MAs(III) or Rox(III). Our data suggest that metalloid exposure promotes plasticity in arsenic resistance systems, enhancing host organism adaptation to metalloid stress., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

Ecological restoration of heavily contaminated soils by multiple metal(loid)s in mining areas is very difficult. In this study, we provided an attractive measure of using silkworm excrement (SE) and its modified materials to restore the soil heavily contaminated by arsenic (As), antimony (Sb), cadmium (Cd), lead (Pb) and chromium (Cr). We investigated the adsorption capacities and the associated remediation mechanisms for antimonite [Sb(III)] and antimonate [Sb(V)] by raw SE, biochar-modified SE (BC700), iron-modified BC700 (MBC) and sulfhydryl-modified BC700 (SH). Then, we selected SE and SH to compare their outcomes to restore the vegetations and the soil bacterial communities in the investigated soil mentioned above. The results showed that SE displayed the best characteristics for metal(loid) physical adsorption. But SH conferred the strongest capacity to adsorb Sb (max 23.92 mg g -1 ), suggesting the process of chemical adsorption played a key role in adsorbing Sb via functional groups (-SH). SE and SH both significantly (1) promoted the growth of pakchoi (Brassica campestris L., New Zealand No.2), community abundance of soil bacteria (283-936 OTUs), and the quantity of bacterial genera correlated with resistance, plant growth promotion and specified carbon metabolism; (2) but reduced bacterial genera correlated with pathogenicity. In this study, we suggested an attractive recyclable measure to restore the disturbed ecological environment in mining areas, i.e, using mulberry to restore the vegetation→ using leaves of mulberry to rear silkworms→ using SE to immobilize metal(loid)s in soils growing mulberry or other plants., Competing Interests: Declaration of Competing Interest We declare that no conflict of interest exits in this manuscript, and manuscript is approved by all authors for publication. This manuscript was original and has not been published in whole or in part previously., (Copyright © 2023 Elsevier B.V. All rights reserved.)

Lead ion (Pb 2+ ) is one of the heavy metal contaminants within the environment, which can seriously affect biological health. Thus, it is very important to detect lead ions, especially exceeding the standard concentration (100 ng/mL). In this work, we have developed a photoelectrochemical (PEC) aptamer sensor with Z-scheme Fe 2 O 3 /g-C 3 N 4 heterojunction as a substrate material for sensitive detection of Pb 2+ . Specifically, Fe 2 O 3 /g-C 3 N 4 is employed as a substrate with a powerful and stable photocurrent response. Au and DNA-1 connected to the substrate material via the Au-S bond and increased the electron conduction. Marking DNA-2 with ZnO effectively reduced the light absorption intensity resulting in a lower photocurrent response. Surprisingly, the Pb 2+ PEC sensor showed good linearity in the detection range of 62 pg/mL to 1 μg/mL with a detection limit as low as 7.9 pg/mL (S/N = 3). The sensor showed stable recovery and low relative standard deviation in real sample detection. Additionally, the sensor exhibited excellent stability, selectivity, and reproducibility. The reproducibility of the electrodes was evaluated, and the accuracy of the individual electrode current values was calculated to range from 0.5% to 2.71% with an RSD of 1.74%. Such PEC sensor guarantees to supply a brand-new approach to the detection of Pb 2+ ., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

In this study, we investigated the effects of different natural organic acids (NOAs), L-ascorbic acid (AA) and (+)-catechin hydrate (CAT), on the activation of persulfate (PDS) for the oxidation of naproxen (NAP) in water and soil. We found that only AA-activated PDS process had a significant degradation efficiency of NAP in water. High AA concentration (500 μM) inhibited the degradation of NAP, whereas high levels of PDS (7.5 mM) and acidic conditions (pH=3-7) were beneficial for NAP degradation. In soil, both CAT and AA promoted PDS activation and NAP degradation. Low soil organic matter and high Fe/Mn-mineral contents were favorable for NAP degradation by AA-activated PDS. Column experiments confirmed that NAP was readily transported and degraded under porous medium conditions using AA-activated PDS. Moreover, we revealed that SO 4 •- and HO• were the dominant reactive species for NAP degradation by AA-activated PDS. Intermediate products of NAP in the AA-activated PDS process were analyzed and the reactive sites of NAP were predicted. E. coli growth tests verified that the intermediate products in the AA-activated PDS process were less toxic than NAP. Our results highlight the high potential of NOAs-activated PDS process for the remediation of NAP-contaminated water and soil., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

Arsenic (As) presents high toxicity and strong carcinogenicity, and its health risks are regulated by its oxidation state and speciation. As can form complexes with the surface of minerals or organic matter through adsorption, affecting its toxicity and bioavailability. However, the regulation effect of the interaction of coexisting minerals and organic matter on As fate remains largely unknown. Here, we discovered that minerals (e.g., pyrite) and organic matter (e.g., alanyl glutamine, AG) can form pyrite-AG complexes, promoting As(III) oxidation under simulated solar irradiation. The formation of pyrite-AG was explored in terms of the interaction of surface oxygen atoms, electron transfer and crystal surface changes. From the perspective of atoms and molecules, pyrite-AG showed more oxygen vacancies, stronger reactive oxygen species (ROS) and a higher electron transport capacity than pyrite alone. Compared with pyrite, pyrite-AG effectively promoted the conversion of highly toxic As(III) to less toxic As(V) due to the enhanced photochemical properties. Moreover, quantification and capture of ROS confirmed that hydroxyl radicals (•OH) played an important role in As(III) oxidation in the pyrite-AG and As(III) system. Our results provide previously unidentified perspectives on the effects and chemical mechanisms of highly active complexes of mineral and organic matter on As fate and provide new insights into the risk assessment and control of As pollution., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

Dissolved organic matter (DOM) exists widely in natural waters and plays an important role in river carbon cycles and greenhouse gas emissions through microbial interactions. However, information on DOM-microbe associations in response to environmental stress is limited. River environments are the main carriers of microplastic (MP) pollution, and global heat waves (HWs) are threatening river ecology. Here, through MP exposure and HW simulation experiments, we found that DOM molecular weight and aromaticity were closely related to initial microbial communities. Moreover, MP-derived DOM regulated microbial community abundance and diversity, influenced microorganism succession trajectories as deterministic factors, and competed with riverine DOM for microbial utilization. SimulatedHWs enhanced the MP-derived DOM competitive advantage and drove the microbial community to adopt a K-strategy for effective recalcitrant carbon utilization. Relative to single environmental stressor exposure, combined MP pollution and HWs led to a more unstable microbial network. This study addresses how MPs and HWs drive DOM-microbe interactions in rivers, contributes to an in-depth understanding of the fate of river DOM and microbial community succession processes, and narrows the knowledge gap in understanding carbon sinks in aquatic ecosystems influenced by human activities and climate change., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

Selenium (Se) can reduce cadmium (Cd) uptake/translocation via regulating pectins, hemicelluloses and lignins of plant root cell walls, but the detailed molecular mechanisms are not clear. In this study, six hydroponic experiments were set up to explore the relationships of uptake/translocation inhibition of Cd by selenite (Se(IV)) with cell wall component (CWC) synthesis and/or interactions. Cd and Se was supplied (alone or combinedly) at 1.0 mg L -1 and 0.5 mg L -1 , respectively, with the treatment without Cd and Se as the control. When compared to the Cd1 treatment, the Se0.5Cd1 treatment 1) significantly increased total sugar concentrations in pectins, hemicelluloses and callose, suggesting an enhanced capacity of binding Cd or blocking Cd translocation; 2) stimulated the deposition of Casparian strips (CS) in root endodermis and exodermis to block Cd translocation; 3) stimulated the release of C-O-C (-OH - or -O - ) and CO (carboxyl, carbonyl, or amide) to combine Cd; 4) regulated differential expression genes (DEGs) and metabolites (DMs) correlated with synthesis and/or interactions of CWSs to affect cell wall net structure to affect root cell division, subsequent root morphology and finally elemental uptake; and 5) stimulated de-methylesterification of pectins via reducing expression abundances of many DMs and DEGs in the Yang Cycle to reduce supply of methyls to homogalacturonan, and regulated gene expressions of pectin methylesterase to release carboxyls to combine Cd; and 6) down-regulated gene expressions associated with Cd uptake/translocation., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

Bacterial adaptation to extreme environments is often mediated by horizontal gene transfer (HGT) via genetic mobile elements. Nevertheless, phage-mediated HGT conferring bacterial arsenic resistance determinants has rarely been investigated. In this study, a highly arsenite and antimonite resistant bacterium, Citrobacter portucalensis strain Sb-2, was isolated, and genome analysis showed that several putative arsenite and antimonite resistance determinants were flanked or embedded in prophages. Furthermore, an active bacteriophage carrying one of the ars clusters (arsRDABC arsR-yraQ/arsP) was obtained and sequenced. These genes encoding putative arsenic resistance determinants were induced by arsenic and antimony as demonstrated by RT-qPCR, and one gene arsP/yraQ of the ars cluster was shown to give resistance to MAs(III) and Rox(III), thereby showing function. Here, we were able to directly show that these phage-mediated arsenic and antimony resistances play a significant role in adapting to As- and Sb-contaminated environments. In addition, we demonstrate that this phage is responsible for conferring arsenic and antimony resistances to C. portucalensis strain Sb-2., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Rivers play a critical role in the global carbon cycle, but the processes can be affected by widespread microplastic (MP) pollution and the increasing frequency of heat waves (HWs) in a warming climate. However, little is known about the role of river microbes in regulating the carbon cycle under the combined action of MP pollution and HWs. Here, through seven-day MP exposure and three cycles of HW simulation experiments, we found that MPs inhibited the thermal adaptation of the microbial community, thus regulating carbon metabolism. The CO 2 release level increased, while the carbon degradation ability and the preference for stable carbon were inhibited. Metabonomic, 16 S rRNA and ITS gene analyses further revealed that the regulation of carbon metabolism was closely related to the microbial r-/K- strategy, community assembly and transformation of keystone taxa. The random forest model revealed that dissolved oxygen and ammonia-nitrogen were important variables influencing microbial carbon metabolism. The above findings regarding microbe-mediated carbon metabolism provide insights into the effect of climate-related HWs on the ecological risks of MPs., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Antimony (Sb) is a toxic metalloid, and excess Sb causes damage to the plant photosynthetic system. However, the underlying mechanisms of Sb toxicity in the plant photosynthetic system are not clear. Hydroponic culture experiments were conducted to illustrate the toxicity differences of antimonite [Sb(III)] and antimonate [Sb(V)] to the photosynthetic system in a rice plant (Yangdao No. 6). The results showed that Sb(III) showed a higher toxicity than Sb(V), judging from (1) lower shoot and root biomass, leaf water moisture content, water use efficiency, stomatal conductance, net photosynthetic rate, and transpiration rate; (2) higher water vapor deficit, soluble sugar content, starch content, and oligosaccharide content (sucrose, stachyose, and 1-kestose). To further analyze the direction of the photosynthetic products, we conducted a metabonomic analysis. More glycosyls were allocated to the synthesis pathways of oligosaccharides (sucrose, stachyose, and 1-kestose), anthocyanins, salicylic acid, flavones, flavonols, and lignin under Sb stress to quench excess oxygen free radicals (ROS), strengthen the cell wall structure, rebalance the cell membrane, and/or regulate cell permeability. This study provides a complete mechanism to elucidate the toxicity differences of Sb(III) and Sb(V) by exploring their effects on photosynthesis, saccharide synthesis, and the subsequent flow directions of glycosyls., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Carbon-based catalysts with heteroatom doping and hollow structures are desired for advanced oxidation processes (AOPs). Herein, dual-shelled Co, N, and S codoped hollow carbon nanocages were developed by wrapping zeolitic imidazolate framework-67 (ZIF-67) with trithiocyanuric acid (TCA) and performing subsequent carbonization. The optimal composite catalyst (Co-NC-CoS) exhibited excellent catalytic performance toward different organic pollutants. Almost complete removal of 4-NP (60 mg/L -1 ) was achieved within 20 min by 10 mg of catalyst and 0.2 g/L -1 peroxymonosulfate (PMS). Moreover, the catalyst showed good stability and reusability. The effects of catalyst and PMS dose, pollutant concentration, pH and common anions were investigated, and reactive oxygen species (ROS) were studied by scavenger experiments and electron paramagnetic resonance (EPR) tests. The results show that multidoped atoms S, Co and N all contributed to the degradation system. Several lines of evidence suggested that S could change the catalytic process from Co 3+ /Co 2+ to Co 3+ /Co 2+ /Co 0 reduction due to its low redox potential. Degradation was achieved through both radical and nonradical pathways, where sulfate radicals (SO 4 ·̶) , hydroxyl radicals ( · OH) and singlet oxygen ( 1 O 2 ) were primary reactive species. Overall, this work may suggest that the novel multi heteroatom-doped catalysts with complex structures can be developed for environmental remediation., (Copyright © 2021 Elsevier B.V. All rights reserved.)

Polycyclic aromatic hydrocarbons are hazardous contaminants existing ubiquitously in polluted soil. In this study, using nanocellulose (CNC) fluid as an eco-friendly agent was proposed for the first time in the remediation of phenanthrene (PHE) contaminated soil. The effects of environmental factors on the mobilization of PHE in soil by CNC nanofluid was investigated using factorial analysis. The results showed that temperature and ionic strength had a significant influence on PHE removal, which were associated with the viscosity and zeta potential change in the nanofluid. The analysis based on two-dimensional correlation spectroscopy integrated with FTIR and synchrotron-based XRF imaging revealed that metals and minerals in soil played important roles in PHE detachment. The hydroxyl groups on CNC bonded with Fe-O, Si-O, and Mn-O in soil as time went on, and eventually achieved PHE mobilization through the interruption of PHE/SOM-metal/mineral linkages. The complexation and transport of PHE/SOM-metals/minerals from soil particles to the aqueous phase could be the primary PHE removal mechanism. Besides, the biotoxicity study displayed a detoxification effect of CNC nanofluid on PHE contaminants in soil. This study offers new insight into a cost-effective and biodegradable nanocellulose washing agent, which can be a good alternative to the available site remediation options., (Copyright © 2020 Elsevier B.V. All rights reserved.)

Since selenium (Se) was shown to be an essential element for humans in 1957, the biofortification of Se to crops via foliar spraying or soil fertilization has been performed for several decades to satisfy the daily nutritional need of humans. Appropriate doses of Se were found to counteract a number of abiotic and biotic stresses, such as exposure to heavy metals (metalloids) (HMs), via influencing the regulation of antioxidant systems, by stimulation of photosynthesis, by repair of damaged cell structures and functions, by regulating the metabolism of some substances and the rebalancing of essential elements in plant tissues. However, few concerns were paid on why and how Se could reduce the uptake of a variety of HMs. This review will mainly address the migration and transformation of HMs regulated by Se in the soil-plant system in order to present a hypothesis of why and how Se can reduce the uptake of HMs in plants. The following aspects will be examined in greater detail, including 1) how the soil characteristics influences the ability of Se to reduce the bioavailability of HMs in soils and their subsequent uptake by plants, which include soil Se speciation, pH, water regime, competing ions and microbes; 2) how the plant root system influenced by Se affects the uptake or the sequestration of HMs, such as root morphology, root iron plaques and root cell wall; 3) how Se combines with HMs and then sequesters them in plant cells; 4) how Se competes with arsenic (As) and thereby reduces As uptake in plants; 5) how Se regulates the expression of genes encoding functions involved in uptake, translocation and sequestration of HMs by Se in plants., (Copyright © 2020 Elsevier B.V. All rights reserved.)

An approved fire-protection method for in-flight freighter aircraft is aircraft depressurization. The objective of this study was to evaluate the influence of depressurization on the burning characteristics of typical combustibles based on large-scale corrugated cartons test data, which is believed to be valuable for aircraft fire safety engineering. The fuel mass loss, pressure, CO concentration, and axial temperature distribution were investigated in comparative tests conducted in a newly designed hypobaric chamber to simulate a depressurization process from 100 to 60 kPa with respective rates of decrease of 91, 182, and 328 Pa/s. The depressurization experimental results show that the fire plume temperature, burning rate and pressure have a good power function correlation. A theoretical analysis of the sub-atmospheric pressure dependence relationship on the burning rates was conducted to predict the burning behavior, showing good agreement with the experimental results. Two kinds of pressure effects on the burning control mechanism were proposed. For the convective heat feedback control, a 2/3 power law with pressure was formulated with experimental validation. For the radiation heat feedback influenced by soot emissivity and mean beam length, a 3/2 power law with pressure resulted., (Copyright © 2019 Elsevier B.V. All rights reserved.)

Technetium-99 ( 99 Tc) is a major contaminant at nuclear power plants and several US Department of Energy sites. Its most common aqueous species, pertechnetate (TcO 4 - ), is very mobile in the environment, and currently there are no effective technologies for its sequestration. In this work, a porous iron (pFe) material was investigated for TcO 4 - and perrhenate (ReO 4 - ) sequestration from artificial groundwater. The pFe was significantly more effective than granular iron for both TcO 4 - and ReO 4 - sequestration under oxic conditions. The Tc removal capacity was 27.5 mg Tc/g pFe at pH ˜6.8, while the Re removal capacity was 23.9 mg Re/g pFe at pH ˜10.6. Tc K-edge XANES and EXAFS analyses indicated that the removed Tc species was 70-80% Tc(IV) that was likely incorporated into Fe corrosion products (i.e., Fe(OOH), Fe 3 O 4 ) and 20-30% unreduced TcO 4 - . In contrast, the removed Re species was ReO 4 - only, without detectable Re(IV). In addition, the sequestered ReO 4 - was not extracted (<3%) by 0.1 M Na 2 SO 4 and 1 M KI solution, which indicated that ReO 4 - and by chemical analogy, unreduced TcO 4 - , was likely incorporated into Fe corrosion products. This inexpensive pFe material may be applied to the sequestration and stabilization of 99 TcO 4 - from contaminated environments and nuclear waste streams., (Copyright © 2019 Elsevier B.V. All rights reserved.)

To identify the key barrier parts and relevant elements during Cd/As transport into brown rice, 16 elements were measured in 14 different parts of 21 rice genotypes; moreover, transcriptomic of different nodes was analyzed. Cd/As contents in root and nodes were significantly higher than those other parts. Node I had the highest Cd content among nodes, leading an increase in gene expressions involved in glycolytic and Cd detoxification. The Cu/Zn/Co distribution and transport to various parts was similar to that of Cd, and Fe/Sb distribution and transport to various parts was similar to that of As. Moreover, Cu/Zn/Co/Mg was correlated with Cd in root and nodes, as well as Fe with As. Besides, the ionomic profile showed the different parts of an organ were closely related, and the spatial distribution of different organs was consistent with the growth morphology of rice. Therefore, root and nodes are two key barriers to Cd/As transport into brown rice. Moreover, Node I has the highest Cd accumulation capacities among nodes. The ionomic profile reflects relationships among plant parts and correlations between the elements, suggesting that nodes are hubs for element distribution, as well as the correlation between Cd with Zn/Cu/Co/Mg, between Fe with As., (Copyright © 2017. Published by Elsevier B.V.)

The treatment of bisphenol A (BPA)-contaminated water has attracted great interest recently. In this contribution, ultrasound (US) was applied to remove low-concentration BPA in aqueous solution at the frequency of 20 kHz, and the effects of ultrasonic intensity and ozone on BPA removal were evaluated for the first time. Considering the coexistence of halomethanes and BPA in chlorinated drinking water, BPA was degraded under US in the presence of CCl(4). In addition, the main intermediates resulting from BPA ultrasonic degradation were identified by gas chromatography-mass spectrometry. On the basis of these studies, OH radical induced oxidation was identified as the major destruction pathway during BPA sonolysis.

Based on the effects of various additives on ultrasonic degradation of 2,4-dinitrophenol (DNP) in aqueous solution, the degradation mechanisms and reaction kinetics of DNP in different processes were proposed. The results showed that some additives, such as CuO, CCl(4), O(3), NaCl and KI, were favorable for DNP sonochemical degradation. On the contrary, DNP degradation efficiency was restrained by Na(2)CO(3), indicating that OH radicals oxidation played an important role in DNP ultrasonic removal. The significant increases in DNP degradation in US/CuO/H(2)O(2), US/CCl(4) and US/O(3) systems were also related to the intermediates formed during the reactions, such as HO(2)/O(2)(-) radicals, chlorine-containing radicals and HClO. In addition, DNP ultrasonic removal was observed to behave as pseudo-first-order kinetics under different experimental conditions tested in the present work.