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Volatilization of hazardous hydrophobic organic compounds is often observed in many water, wastewater and soil treatment (bio)processes. Several models have been developed to quantify and predict gas-liquid pollutant transfer, being the proportionality coefficient model (PCM) one of the most commonly used, particularly in wastewater treatment. The PCM is based on the use of oxygen as a reference compound, which has a low resistance to the transfer in the gas phase. However, this resistance might be important for (semi-)volatile organic compounds - or (semi-)VOCs, which may render the use of the PCM model inaccurate. This study proposes an experimental methodology and a modeling approach for the use of the two-reference compound model (2RCM) that considers both the liquid-side and the gas-side resistances, by using water and oxygen as references. Results showed that the 2RCM predicts more accurately the overall mass transfer coefficients than the PCM for a VOC and two semi-VOCs tested in this study. In addition, the 2RCM was found to be a more robust method to estimate mass transfer coefficient of any compound and its use can be extrapolated to all substances. Finally, the relevance and limitations of both models was established., (Copyright © 2021 Elsevier B.V. All rights reserved.)

A lot of soil (particularly, former industrial and military sites) has been contaminated by various highly toxic contaminants such as petroleum hydrocarbons, polycyclic aromatic hydrocarbons (PAHs), polychlorobiphenyls (PCBs) or chlorinated solvents. Soil remediation is now required for their promotion into new industrial or real estate activities. Therefore, the soil washing (SW) process enhanced by the use of extracting agents (EAs) such as surfactants or cyclodextrins (CDs) has been developed for the removal of hydrophobic organic compounds (HOCs) from contaminated soils. The use of extracting agents allows improving the transfer of HOCs from the soil-sorbed fraction to the washing solution. However, using large amount of extracting agents is also a critical drawback for cost-effectiveness of the SW process. The aim of this review is to examine how extracting agents might be recovered from SW solutions for reuse. Various separation processes are able to recover large amounts of extracting agents according to the physicochemical characteristics of target pollutants and extracting agents. However, an additional treatment step is required for the degradation of recovered pollutants. SW solutions may also undergo degradation processes such as advanced oxidation processes (AOPs) with in situ production of oxidants. Partial recovery of extracting agents can be achieved according to operating conditions and reaction kinetics between organic compounds and oxidant species. The suitability of each process is discussed according to the various physicochemical characteristics of SW solutions. A particular attention is paid to the anodic oxidation process, which allows either a selective degradation of the target pollutants or a complete removal of the organic load depending on the operating conditions., (Copyright © 2020 Elsevier B.V. All rights reserved.)

Hydrophobic organic compound (HOC)-contaminated soils are a great environmental and public health concern nowadays. Further research is necessary to develop environmental friendly biotechnologies that allows public and private sectors to implement efficient and adaptable treatment approaches. Aerobic soil-slurry bioreactor technology has emerged as an effective and feasible technique with a high remediation potential, especially for silt and clay soil fractions, which often contain the highest pollutant concentration levels and are usually difficult to remove by implementing conventional methods. However, the mechanisms involved in the HOC removal in bioslurry reactor are still not completely understood. Gas-liquid and solid-liquid mass transfer, mass transport and biodegradation phenomena are the main known processes taking place in slurry bioreactors. This review compiles the most up-to-date information available about these phenomena and tries to link them, enlightening the possible interactions between parameters. It gathers the basic information needed to understand the complex bioremediation technology and raises awareness of some considerations that should be made., (Copyright © 2017. Published by Elsevier B.V.)

The release of hydrophobic organoxenobiotics such as polycyclic aromatic hydrocarbons, petroleum hydrocarbons or polychlorobiphenyls results in long-term contamination of soils and groundwaters. This constitutes a common concern as these compounds have high potential toxicological impact. Therefore, the development of cost-effective processes with high pollutant removal efficiency is a major challenge for researchers and soil remediation companies. Soil washing (SW) and soil flushing (SF) processes enhanced by the use of extracting agents (surfactants, biosurfactants, cyclodextrins etc.) are conceivable and efficient approaches. However, this generates high strength effluents containing large amount of extracting agent. For the treatment of these SW/SF solutions, the goal is to remove target pollutants and to recover extracting agents for further SW/SF steps. Heterogeneous photocatalysis, technologies based on Fenton reaction chemistry (including homogeneous photocatalysis such as photo-Fenton), ozonation, electrochemical processes and biological treatments have been investigated. Main advantages and drawbacks as well as target pollutant removal mechanisms are reviewed and compared. Promising integrated treatments, particularly the use of a selective adsorption step of target pollutants and the combination of advanced oxidation processes with biological treatments, are also discussed., (Copyright © 2015 Elsevier B.V. All rights reserved.)