1. Synergistic effect and mechanism of nZVI/LDH composites adsorption coupled reduction of nitrate in micro-polluted water.
- Author
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Pei, Yanyan, Cheng, Wei, Liu, Renyu, Di, Hongcheng, Jiang, Yachen, Zheng, Chaoqun, and Jiang, Zhuwu
- Subjects
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DENITRIFICATION , *LAYERED double hydroxides , *NITRITES , *ADSORPTION (Chemistry) , *CHEMICAL reduction , *IRON - Abstract
In this study, nZVI/LDH composites were prepared by loading nano zero-valent iron (nZVI) on layered double hydroxide (LDH) surface for adsorption coupled reduction of nitrate (NO 3 --N). The results showed that the removal of NO 3 --N and total nitrogen (TN) by the nZVI/LDH composites was 88.64% and 77.63%, respectively, with a selectivity of 55.21% for N 2 and only 1.86% for ammonia nitrogen (NH 4 +-N) within 180 min. The valence states of various N forms during the adsorption-reduction process were investigated. The mechanism of synergistic adsorption-reduction degradation of NO 3 --N was proposed by measuring the contents of NO 3 --N, nitrite (NO 2 --N), and NH 4 +-N in the aqueous and adsorbed phases in the reaction process, including rapid adsorption of initial NO 3 --N, chemical reduction of adsorbed NO 3 --N and resorption of the final product. The nZVI/LDH also maintained up to 82.56% NO 3 --N removal in natural water, with aging experiments proved that the composites maintained 60.48% NO 3 --N removal after 15 days. Therefore, the composites may have great application prospects for NO 3 --N removal in micro-polluted water. [Display omitted] • The nZVI/LDH composites was synthesized for removal of nitrate in micro-polluted water. • nZVI/LDH improved nitrogen selectivity and removed total nitrogen simultaneously. • The mechanism of synergistic adsorption-reduction removal of nitrate was proposed. • The nZVI/LDH composites showed stable and efficient performance in real water. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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