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A Very Low Frequency (VLF) wave detection system has been designed at Wuhan University (WHU) and recently deployed by the Polar Research Institute of China at the Chinese Great Wall station (GWS, 62.22°S, 58.96°W) in Antarctica. With a dynamic range of ∼110 dB and timing accuracy of ∼100 ns, this detection system can provide observational data with a resolution that can facilitate space physics and space weather studies. This paper presents the first results of the wave measurements by the WHU VLF wave detection system at GWS to verify the performance of the system. With the routine operation for 3 months, the system can acquire the dynamic changes of the wave amplitudes and phases of various ground‐based VLF transmitter signals emitted in both North America and Europe. A preliminary analysis indicates that the properties of the VLF transmitter signals observed at GWS during the X‐class solar flare events are consistent with previous studies. As the HWU‐GWS path crosses the South Atlantic Anomaly region, the observations also imply a good connection in space and time between the VLF wave disturbances and the lower ionosphere variation potentially caused by magnetospheric electron precipitation during the geomagnetic storm period. It is therefore well expected that the acquisition of VLF wave data at GWS, in combination with datasets from other instruments, can be beneficial for space weather studies related to the radiation belt dynamics, terrestrial lightning discharge, whistler wave propagation, and the lower ionosphere disturbance, etc., in the polar region. Plain Language Summary: Considering the good coverage and quiet electromagnetic environment, Antarctica is an ideal place for plasma wave measurements. Various stations have been established in Antarctica, of which Palmer station is particularly noteworthy and has historically provided valuable VLF data for atmospheric, ionospheric, and magnetospheric studies. An Extremely Low Frequency/Very Low Frequency (VLF) wave detection system has been designed by Wuhan University and recently set up at Great Wall station (GWS) in Antarctica. This device can effectively record VLF signals with frequencies of 1–50 kHz, including artificial transmitter signals and natural emissions. This paper gives the broadband spectrum of 1–50 kHz signals in the north‐south and east‐west directions recorded at GWS for the first time. VLF signatures from lightning discharges, environmental disturbances, and navy transmitters in North America and Europe can be clearly identified. The overall trend of amplitude and phase of transmitter signals is consistent with the X‐ray fluxes measured by the Geostationary Operational Environment Satellite satellite. Based on the GWS observations, it is expected to reveal some significant new phenomena reflected in VLF signals and further study the distribution and propagation characteristics of VLF waves. These are of great significance for physical research and application, especially in the unique geographical location of the South Pole. Key Points: A high‐sensitivity Very Low Frequency (VLF) wave detection system with a dynamic range of ∼110 dB and timing accuracy of ∼100 ns has been designedThis system has been recently deployed by the Polar Research Institute of China in Antarctica and operated routinely for 3 monthsThe VLF wave data collected by this system can be widely used to monitor and study space weather events in the polar region [ABSTRACT FROM AUTHOR]