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Water properties and formation processes of Alaskan Coastal Winter Water (ACWW) over the eastern Chukchi shelf along the Alaska coast, the so-called Barrow Canyon pathway, are examined using data from moorings, atmospheric reanalysis, satellite-derived sea-ice production (SIP), and a numerical tracer experiment. Along this pathway, Pacific Winter Water (PWW) can be modified to produce ACWW through SIP accompanied by production of cold, saline polynya water in the coastal polynyas, upwelling of warm Atlantic Water (AW), and mixing processes on the shelf. Three different types of ACWW are formed: (i) a mixture of AW and PWW, (ii) a mixture of AW and polynya water, and (iii) hypersaline polynya water. The northeasterly winds, correlated with the north-south atmospheric pressure gradient between Beaufort High and Aleutian Low, are common triggers of polynya SIP episodes and AW upwelling in the Barrow Coastal Polynya (BCP). Due to the dual impact of northeasterly winds, PWW modification processes in the BCP are more complicated than what occurs elsewhere in the Chukchi Polynya. The impact of AW upwelling on the ACWW formation is most prominent in the BCP, usually centered along the coast. All types of ACWW are thought to be basically transported westward or northwestward with the Chukchi slope current and/or Beaufort Gyre and finally contribute to maintenance of the lower halocline layer especially over the Chukchi Borderland, Northwind Ridge, and southern Canada Basin. Even in the Pacific sector of the Arctic Ocean, ACWW properties are strongly influenced by both Atlantic-origin and Pacific-origin waters.

Cracks are common and natural features of sea ice formed in the polar oceans. In this study, a sea ice crack in flooded, multiyear, land-fast Antarctic sea ice was examined to assess its influence on biological productivity and the transport of nutrients and microalgae into the upper layers of neighboring sea ice. The water inside the crack and the surrounding host ice were characterized by a strong discoloration (brown color), an indicator of a massive algal bloom. Salinity and oxygen isotopic ratio measurements indicated that 64-84% of the crack water consisted of snow meltwater supplied during the melt season. Measurements of nutrient and chlorophyll a concentrations within the slush layer pool (the flooded layer at the snow-ice interface) revealed the intrusion of water from the crack, likely forced by mixing with underlying seawater during the tidal cycle. Our results suggest that sea ice crack formation provides conditions favorable for algal blooms by directly exposing the crack water to sunlight and supplying nutrients from the under-ice water. Subsequently, constituents of the crack water modified by biological activity were transported into the upper layer of the flooded sea ice. They were then preserved in the multiyear ice column formed by upward growth of sea ice caused by snow ice formation in areas of significant snow accumulation. Plain Language Summary Formation of cracks in sea ice affects the environment associated with biological production and biogeochemical cycling in the surface ocean of sea ice systems. Because cracks are likely to form frequently within the sea ice during the season of ice melting and ice breaking, the contributions of cracks to biological production and biogeochemical cycling may be significant in ice-covered oceans. In the future, the melting of sea ice in polar oceans will strongly affect the output of biogeochemical parameters trapped within sea ice and their use in primary and secondary production within surface oceans. In the case of multiyear, land-fast ice, biogeochemical parameters that accumulate within the ice would be discharged abruptly to ocean surface waters when the multiyear ice breaks up.

The nature of the Barrow Coastal Polynya (BCP), which forms episodically off the Alaska coast in winter, is examined using mooring data, atmospheric reanalysis data, and satellite-derived sea-ice concentration and production data. We focus on oceanographic conditions such as water mass distribution and ocean current structure beneath the BCP. Two moorings were deployed off Barrow, Alaska in the northeastern Chukchi Sea from August 2009 to July 2010. For sea-ice season from December to May, a characteristic sequence of five events associated with the BCP has been identified; (1) dominant northeasterly wind parallel to the Barrow Canyon, with an offshore component off Barrow, (2) high sea-ice production, (3) upwelling of warm and saline Atlantic Water beneath the BCP, (4) strong up-canyon shear flow associated with displaced density surfaces due to the upwelling, and (5) sudden suppression of ice growth. A baroclinic current structure, established after the upwelling, caused enhanced vertical shear and corresponding vertical mixing. The mixing event and open water formation occurred simultaneously, once sea-ice production had stopped. Thus, mixing events accompanied by ocean heat flux from the upwelled warm water into the surface layer played an important role in formation/maintenance of the open water area (i.e., sensible heat polynya). The transition from a latent to a sensible heat polynya is well reproduced by a high-resolution pan-Arctic ice-ocean model. We propose that the BCP, previously considered to be a latent heat polynya, is a wind-driven hybrid latent and sensible heat polynya, with both features caused by the same northeasterly wind.

[1] In this study, we present evidence that Antarctic and Arctic sea ice act as sink for atmospheric CO2 during periods of snowmelt and surface flooding. The CO2 flux measured directly at the flooded sea ice surface (Fflood) constituted a net CO2 sink of −1.1 ± 0.9 mmol C m−2 d−1 (mean ± 1 SD), which was an order of magnitude higher than the flux measured at the snow-air surface (Fsnow) and bare ice surface (Fice). The Fsnow/Fflood ratio decreased with increasing water equivalent of snow and superimposed-ice, suggesting that the properties of snow and superimposed-ice formation affect the magnitude of the CO2 flux. The Fsnow/Fflood ratio ranged from 0.1 to 0.5, illustrating that 50–90% of the potential flux at the flooded surface was reduced due to the presence of snow/superimposed-ice. Hence, snow cover properties and superimposed-ice play an important role in the CO2 fluxes across the sea ice-snow-atmosphere interface.

[1] We present the first direct measurements of dimethylsulfide (DMS) emissions from Antarctic sea ice to the atmosphere during the seasonal warming period obtained using a chamber technique. Estimated DMS fluxes measured over the snow and superimposed ice (ice formed by the freezing of snow meltwater) were from 0.1 to 0.3 μmol m−2 d−1. The DMS fluxes measured directly over the sea-ice slush layer after removal of the snow and superimposed ice, ranged from 0.1 to 5.3 μmol m−2 d−1, were large compared to those measured over the snow and superimposed ice. The DMS concentrations in slush water ranged from 1.0 to 103.7 nM. The DMS fluxes increased with increasing DMS concentrations in slush water. Our results indicate that the potential DMS flux measured over the slush layer occurred originally from the slush layer, and was dependent on the DMS concentrations in slush water. However, snow accumulation and the formation of superimposed ice over the slush layer significantly blocks the diffusion of DMS to the atmosphere, with the result that DMS tends to accumulate in the slush layer although the removal process of DMS by photolysis reaction can modify the DMS flux from the slush layer. Hence, the slush layer has the potential to release the DMS to the atmosphere and ocean when the snow and superimposed ice melts.