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Fluorescent carbon quantum dots (CQDs) were prepared by an economical, green, and single-step procedure with the assistance of microwave heating of urea with bagasse (SCB), cellulose (C), or carboxymethyl cellulose (CMC). The prepared CQDs were characterized using a series of spectroscopic techniques, and they had petite size, intense absorption in the UV, and excitation wavelength-dependent fluorescence. The prepared CQDs were used for Pb(II) adsorption from an aqueous solution. The removal efficiency percentages (R %) were 99.16, 96.36, and 98.48% for QCMC, QC, and QSCB, respectively. The findings validated the efficiency of CQDs synthesized from CMC, cellulose, and SCB as excellent materials for further utilization in the environmental fields of wastewater pollution detection, adsorption, and chemical sensing applications. The kinetics and isotherms studied found that all CQDs isotherms fit well with the Langmuir model than Freundlich and Temkin models. According to R 2 , the pseudo-second-order fits the adsorption of QCMC, while the first-order one fits with QC and QSCB., (© 2022. The Author(s).)

A practical fluorescent test dipstick for an efficient recognition of ammonia and amines vapors was developed. The prepared testing strip was based on a composite of molecularly imprinted chitosan nanoparticles, supported on cellulose paper assay, with artificial fluorescent receptor sites for ammonia/amines recognition in aqueous and gaseous phases. A modified chitosan nanoparticles containing fluorescein molecules, were successfully prepared and employed on cellulose paper strip creating fluorescent cellulose (FL-Cell) to act as "turn-on" fluorescent sensor for sensing and determining ammonia and organic amine vapor. We employed chitosan nanoparticles that had fluorescein incorporated as the fluorescent probe molecule, with a readout limit achieved for aqueous ammonia as low as 280 ppm at room temperature and atmospheric pressure. The sensor responded linearly relying on the aqueous ammonia concentration in the range of 0.13-280 ppm. The chromogenic fluorescent cellulose platform response depended on the acid-base characteristic effects of the fluorescein probe. The protonated form of fluorescein molecules immobilized within the chitosan nanoparticles were in a nanoenvironment demonstrating only weak fluorescence. When binding to ammonia/amine vapor, the fluorescein active sites were deprotonated and exhibited higher "turned-on" fluorescence as a result of exposure to those alkaline species. The simple fabrication and abovementioned characteristics of such fluorescent chitosan nanoparticles are such that they should be applicable for monitoring of ammonia/amines in either aqueous or vapor states. We studied the distribution of the fluorescent chitosan onto paper sheets fabricated from bleached bagasse pulp and coated with two different thicknesses of a fluorescent nanochitosan and blank nanochitosan solutions. A thin fluorescent nanochitosan layer was created on the surface of cellulose strips using an applicator. Its distribution was assessed by scanning electron microscopic (SEM) and transmission electron microscopic (TEM) analysis as well as Fourier-transform infrared spectroscopic (FT-IR) measurements. The mechanical properties were also tested. The exploitation of this "turn-on" fluorescence sensor invented platform should be amenable to different situations where determination of ammonia/amine vapor or aqueous solution is required.

A novel series of pyrazoline derivatives were synthesized and their spectral properties were characterized via FT-IR, 1 H, and 13 C NMR. The electronic transitions and fluorescence properties were tracked via UV-Vis and emission spectrometry. The density functional theory (DFT) calculations have been also computed to get spot onto the geometry, electronic transitions and spectroscopic properties theoretically that has been compared with the encountered experimental ones. Moreover, the dipole moment, optimized energy, HOMO - LUMO energies and band gaps were calculated for novel candidates pyrazoline derivatives with highly fluorescence quantum yield.

Diarylidenecyclopentanone compound namely, 2,5-bis[4-choloroacetyl-(thiophen-2-ylmethylene)]cyclopentanone (BCTCP) was firstly synthesized using the normal condition of Friedel-Crafts method by reacting 2,5-bis(thiophen-2-ylmethylene)cyclopentanone (BTCP) with chloroacetyl chloride in the presence of aluminum chloride anhydrous. The structure of this compound was confirmed by elemental and spectral analyses including FT-IR, 1 H-NMR, 13 C-NMR and mass spectrometry. The electronic absorption and emission properties of BCTCP were studied in different solvents. BCTCP displays a slight solvatochromic effect of the absorption and emission spectrum, indicating a small change in dipole moment of BCTCP upon excitation. BCTCP displayed photodecomposition in chlorinated solvents upon irradiating with 365 nm light. Ground and excited states electronic geometric optimizations were performed using density functional theory (DFT) and time-dependent density functional theory (TD-DFT), respectively. A DFT natural bond orbital (NBO) analysis complemented the intramolecular charge transfer (ICT). The simulated maximum absorption and emission wavelengths are in line the observed ones in trend, and were proportionally red-shifted with the increase of the solvent polarity. The stability, hardness and electrophilicity of BCTCP in different solvents were correlated with the polarity of the elected solvents.