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Large amounts of process water with considerable concentrations of recalcitrant organic contaminants, such as polycyclic aromatic hydrocarbon (PAHs), phenolic compounds (PCs), and benzene, toluene, ethylbenzene, and xylene (BTEX), are generated by several segments of oil and gas industries. These segments include refineries, hydraulic fracturing (HF), and produced waters from the extraction of shale gas (SGPW), coalbed methane (CBMPW) and oil sands (OSPW). In fact, the concentration of PCs and PAHs in process water from refinery can reach 855 and 742 mg L−1, respectively. SGPW can contain BTEX at concentrations as high as 778 mg L−1. Adsorption can effectively target those organic compounds for the remediation of the process water by applying carbon-based adsorbents generated from organic feedstocks. Such organic feedstocks usually come from organic waste materials that would otherwise be conventionally disposed of. The objective of this review paper is to cover the scientific progress in the studies of carbon-based adsorbents from organic feedstocks that were successfully applied for the removal of organic contaminants PAHs, PCs, and BTEX. The contributions of this review paper include the important aspects of (i) production and characterization of carbon-based adsorbents to enhance the efficiency of organic contaminant adsorption, (ii) adsorption properties and mechanisms associated with the engineered adsorbent and expected for certain pollutants, and (iii) research gaps in the field, which could be a guidance for future studies. In terms of production and characterization of materials, standalone pyrolysis or hybrid procedures (pyrolysis associated with chemical activation methods) are the most applied techniques, yielding high surface area and other surface properties that are crucial to the adsorption of organic contaminants. The adsorption of organic compounds on carbonaceous materials performed well at wide range of pH and temperatures and this is desirable considering the pH of process waters. The mechanisms are frequently pore filling, hydrogen bonding, π−π, hydrophobic and electrostatic interactions, and same precursor material can present more than one adsorption mechanism, which can be beneficial to target more than one organic contaminant. Research gaps include the evaluation of engineered adsorbents in terms of competitive adsorption, application of adsorbents in oil and gas industry process water, adsorbent regeneration and reuse studies, and pilot or full-scale applications. [Display omitted] • Organic contaminants are a concern in process water (PW) from oil and gas operations. • Scientific progress in carbon-based adsorbents for organic contaminants is covered. • Adsorption efficiency is enhanced with production conditions of carbon-based material. • Future study must focus on real PW to assess adsorption efficiency and competitivity • Research gaps include regeneration/reuse and environmental impacts of spent adsorbent. [ABSTRACT FROM AUTHOR]

Basal aquifer water is deep groundwater found at the bottom of geological formations, underlying bitumen-saturated sands. Some of the concerns associated with basal aquifer water at the Athabasca oil sands are the high concentrations of hardness-causing compounds, alkalinity, and total dissolved solids. The objective of this pilot-scale study was to treat basal aquifer water to a quality suitable for its reuse in the production of synthetic oil. To achieve zero-liquid discharge (ZLD) conditions, the treatment train included chemical oxidation, polymeric ultrafiltration (UF), reverse osmosis (RO), and evaporation-crystallization technologies. The results indicated that the UF unit was effective in removing solids, with UF filtrate turbidity averaging 2.0 NTU and silt density index averaging 0.9. Membrane autopsies indicated that iron was the primary foulant on the UF and RO membranes. Laboratory and pilot-scale tests on RO reject were conducted to determine the feasibility of ZLD crystallization. Due to the high amounts of calcium, magnesium, and bicarbonate in the RO reject, softening of the feed was required to avoid scaling in the evaporator. Crystals produced throughout the testing were mainly sodium chloride. The results of this study indicated that the ZLD approach was effective in both producing freshwater and minimizing brine discharges. [ABSTRACT FROM AUTHOR]

Membrane filtration is an effective treatment method for oil sands tailings pond recycle water (RCW); however, membrane fouling and rapid decrease in permeate flux caused by colloids, organic matter, and bitumen residues present in the RCW hinder its successful application. This pilot-scale study investigated the impact of different pretreatment steps on the performance of a ceramic ultrafiltration (CUF) membrane used for the treatment of RCW. Two treatment trains were examined: treatment train 1 consisted of coagulant followed by a CUF system, while treatment train 2 included softening (Multiflo™ system) and coagulant addition, followed by a CUF system. The results indicated that minimum pretreatment (train 1) was required for almost complete solids removal. The addition of a softening step (train 2) provided an additional barrier to membrane fouling by reducing hardness-causing ions to negligible levels. More than 99% removal of turbidity and less than 20% removal of total organic carbon were achieved regardless of the treatment train used. Permeate fluxes normalized at 20 °C of 127–130 L/m 2 h and 111–118 L/m 2 h, with permeate recoveries of 90–93% and 90–94% were observed for the treatment trains 1 and 2, respectively. It was also found that materials deposited onto the membrane surface had an impact on trans-membrane pressure and influenced the required frequencies of chemically enhanced backwashes (CEBs) and clean-in-place (CIP) procedures. The CIP performed was successful in removing fouling and scaling materials such that the CUF performance was restored to baseline levels. The results also demonstrated that due to their low turbidity and silt density index values, permeates produced in this pilot study were suitable for further treatment by high pressure membrane processes. [ABSTRACT FROM AUTHOR]

Through sustainable water management, oil sands companies are working to reduce their reliance on fresh water by minimizing the amount of water required for their operations and by recycling water from tailings ponds. This study was the first pilot-scale testing of a hybrid technology consisting of froth flotation combined with filtration through precoated submerged stainless steel membranes used to treat recycle water from an oil sands facility. The results indicated that the most important factor affecting the performance of the hybrid system was the influent water quality. Any rise in the levels of suspended solids or total organic carbon of the feed water resulted in changes of chemical consumption rates, flux rates, and operating cycle durations. The selections of chemical type and dosing rates were critical in achieving optimal performance. In particular, the froth application rate heavily affected the overall recovery of the hybrid system as well as the performance of the flotation process. Optimum surfactant usage to generate froth (per liter of treated water) was 0.25 mL/L at approximately 2000 NTU of influent turbidity and 0.015 mL/L at approximately 200 NTU of influent turbidity. At the tested conditions, the optimal coagulant dose was 80 mg/L (as Al) at approximately 2000 NTU of influent turbidity and <40 mg/L (as Al) at approximately 200 NTU of influent turbidity. Precoat loading per unit membrane surface area tested during the pilot study was approximately 30 g/m 2 . The results of this study indicated that this hybrid technology can potentially be considered as a pre-treatment step for reverse osmosis treatment of recycle water. [ABSTRACT FROM AUTHOR]

Classical adsorbents such as activated carbon are inefficient to remove Cu(II)-EDTA in solution. Moreover, the heavy metals in the generated sludge can easily be dissolved back into solution. In this research, a novel strategy developed by coupling green rust adsorption and ferrite formation technology was proposed for Cu(II)-EDTA chelate removal. At the adsorption stage, green rust sulfate (GR ME (SO 4 2−)) showed a high adsorption efficiency of chelated copper, with a capacity of 126.41 mg g−1, compared to other classical adsorbents. During the ferrite formation stage, GR ME (SO 4 2−)-based precipitate with high moisture content and slow settling rate could be transformed into ferrite-based precipitate with low moisture content and rapid settling rate. The volume and moisture content of ferrite were 2.20 and 1.45 times lower than those of GR ME (SO 4 2−) and the sedimentation velocity of ferrite was also 1.23 times higher than that of GR ME (SO 4 2−), which strongly demonstrated the necessity of the ferrite formation process. Toxicity characteristic leaching procedure (TCLP) test results showed that the metallic copper of GR ME (SO 4 2−) sludge could be more easily dissolved back into solution than that of ferrite precipitate under weak-acid conditions, indicating the stability of ferrite. In addition, after the ferrite process, the generated sludge exhibited soft magnetism and could be quickly separated within few seconds using an external magnetic field. All these results showed that the combined green rust adsorption with ferrite formation method was an efficient, recyclable and eco-friendly method for the treatment of wastewater containing Cu(II)-EDTA. Image 1 • The Fe/C microelectrolysis effluent could be applied for green rust preparation. • Green rust was an efficient adsorbent for Cu(II)-EDTA removal. • Operational variables were optimized by response surface methodology. • The ferrite process improved the sludge stability. • The final sludge could be recycled as magnetic material. [ABSTRACT FROM AUTHOR]

The oil production generates large volumes of oil sands process-affected water (OSPW), referring to the water that has been in contact with oil sands or released from tailings deposits. There are concerns about the environmental impacts of the release of OSPW because of its toxicity. Zero valent iron alone (ZVI) and in combination with petroleum coke (CZVI) were investigated as environmentally friendly treatment processes for the removal of naphthenic acids (NAs), acid-extractable fraction (AEF), fluorophore organic compounds, and trace metals from OSPW. While the application of 25 g/L ZVI to OSPW resulted in 58.4% removal of NAs in the presence of oxygen, the addition of 25 g petroleum coke (PC) as an electron conductor enhanced the NAs removal up to 90.9%. The increase in ZVI concentration enhanced the removals of NAs, AEF, and fluorophore compounds from OSPW. It was suggested that the electrons generated from the oxidation of ZVI were transferred to oxygen, resulting in the production of hydroxyl radicals and oxidation of NAs. When OSPW was de-oxygenated, the NAs removal decreased to 17.5% and 65.4% during treatment with ZVI and CZVI, respectively. The removal of metals in ZVI samples was similar to that obtained during CZVI treatment. Although an increase in ZVI concentration did not enhance the removal of metals, their concentrations effectively decreased at all ZVI loadings. The Microtox® bioassay with Vibrio fischeri showed a decrease in the toxicity of ZVI- and CZVI-treated OSPW. The results obtained in this study showed that the application of ZVI in combination with PC is a promising technology for OSPW treatment. [Copyright &y& Elsevier]

The quality of heavy oil electric desalting wastewaters (HO-EDWs) affects the effectiveness of refinery wastewater treatment plants. In this study, an integrated coagulation-ozonation (ICO) process was used to pretreat HO-EDWs and the influences on the characteristics of dissolved organic pollutants (DOPs) were investigated. Coagulation using aluminum sulfate removed 39% of soluble chemical oxygen demand (SCOD), 21% of dissolved organic carbon (DOC), 57% of petroleum hydrocarbons and 38% of polar oils from Liaohe HO-EDWs and the biodegradability was greatly improved. Ozonation removed 33% of SCOD and 88% of polar oils from the coagulated HO-EDWs. Most species of aromatic compounds, phenols, aliphatic acids, anilines and naphthenic acids with high C numbers and ring numbers were degraded and the unsaturation degrees of DOPs significantly decreased under ozonation. As a result, the biodegradability was further improved and the acute toxicity towards Vibrio fischeri was substantially reduced. Some O x S 1 species and organic nitrogen compounds in HO-EDWs were penetrated through ozonation and caused the residual biotoxicity. The results demonstrate the potential of ICO pretreatment for improving the quality of refractory HO-EDWs. [Display omitted] • ICO pretreatment is effective in reducing pollutants contents in HO-EDWs. • ICO pretreatment improved the biodegradability of HO-EDWs. • Ozonation changed the compositions of coagulation-resistant DOPs. • Ozonation significantly decreased the acute toxicity of HO-EDWs towards V. fischeri. [ABSTRACT FROM AUTHOR]